Journal ArticleDOI
Imprinting chemical and responsive micropatterns into metal-organic frameworks.
Shuangbing Han,Yanhu Wei,Cory Valente,Ross S. Forgan,Jeremiah J. Gassensmith,Ronald A. Smaldone,Hideyuki Nakanishi,Ali Coskun,J. Fraser Stoddart,Bartosz A. Grzybowski +9 more
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TLDR
Wet stamping allows metal–organic framework (MOF) crystals to be imprinted with micropatterns of various organic chemicals which change their appearance upon contact with specific chemicals, thus reporting the environmental “status” of the crystal.Abstract:
Wet stamping allows metal–organic framework (MOF) crystals to be imprinted with micropatterns of various organic chemicals. Printing the MOFs with photochromic molecules and pH indicators generates stimuli-responsive micropatterns which change their appearance upon contact with specific chemicals (see picture), thus reporting the environmental “status” of the crystal.read more
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Postsynthetic methods for the functionalization of metal-organic frameworks.
Journal ArticleDOI
MOF positioning technology and device fabrication
TL;DR: In this review, the current technologies that enable the precise positioning of MOFs onto different platforms are presented and examples of devices in which the control of MOF position and functionalisation will play a major technological role are presented.
Journal ArticleDOI
Surveying macrocyclic chemistry: from flexible crown ethers to rigid cyclophanes
TL;DR: This Review surveys the recent developments of the chemistry of naturally occurring cyclodextrins, along with a variety of synthetic flexible and rigid macrocycles that have drawn their inspiration from Pedersen's ground-breaking discovery of crown ethers in the mid-1960s.
Journal ArticleDOI
Strong and reversible binding of carbon dioxide in a green metal-organic framework.
Jeremiah J. Gassensmith,Hiroyasu Furukawa,Ronald A. Smaldone,Ross S. Forgan,Youssry Y. Botros,Youssry Y. Botros,Omar M. Yaghi,Omar M. Yaghi,J. Fraser Stoddart +8 more
TL;DR: The highly selective adsorption of CO(2) by CD-MOF-2, a recently described green MOF consisting of the renewable cyclic oligosaccharide γ-cyclodextrin and RbOH, by what is believed to be reversible carbon fixation involving carbonate formation and decomposition at room temperature is reported.
Journal ArticleDOI
Nanoporous Carbohydrate Metal–Organic Frameworks
Ross S. Forgan,Ronald A. Smaldone,Jeremiah J. Gassensmith,Hiroyasu Furukawa,David B. Cordes,Qiaowei Li,Christopher E. Wilmer,Youssry Y. Botros,Youssry Y. Botros,Randall Q. Snurr,Alexandra M. Z. Slawin,J. Fraser Stoddart +11 more
TL;DR: These new MOFs demonstrate that the CDs can indeed function as ligands for alkali and alkaline earth metal cations in a manner similar to that found with crown ethers, which make them realistic candidates for commercial development.
References
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Functional porous coordination polymers.
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Journal ArticleDOI
Plasmonics for improved photovoltaic devices
Harry A. Atwater,Albert Polman +1 more
TL;DR: Recent advances at the intersection of plasmonics and photovoltaics are surveyed and an outlook on the future of solar cells based on these principles is offered.
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Reticular synthesis and the design of new materials
Omar M. Yaghi,Michael O'Keeffe,Nathan W. Ockwig,Hee K. Chae,Hee K. Chae,Mohamed Eddaoudi,Jaheon Kim +6 more
TL;DR: This work has shown that highly porous frameworks held together by strong metal–oxygen–carbon bonds and with exceptionally large surface area and capacity for gas storage have been prepared and their pore metrics systematically varied and functionalized.
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Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage
Mohamed Eddaoudi,Jaheon Kim,Nathaniel L. Rosi,David T. Vodak,Joseph Wachter,Michael O'Keeffe,Omar M. Yaghi +6 more
TL;DR: Metal-organic framework (MOF-5), a prototype of a new class of porous materials and one that is constructed from octahedral Zn-O-C clusters and benzene links, was used to demonstrate that its three-dimensional porous system can be functionalized with the organic groups and can be expanded with the long molecular struts biphenyl, tetrahydropyrene, pyrene, and terphenyl.
Journal ArticleDOI
Design and synthesis of an exceptionally stable and highly porous metal-organic framework
TL;DR: In this article, an organic dicarboxylate linker is used in a reaction that gives supertetrahedron clusters when capped with monocarboxyates.