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Metal Acetylacetonate Series in Interface Engineering for Full Low-Temperature-Processed, High-Performance, and Stable Planar Perovskite Solar Cells with Conversion Efficiency over 16% on 1 cm2 Scale

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TLDR
A series of metal acetylacetonates produced by a full low-temperature (below 100 °C) process are successfully employed to obtain both "multistable" and high-performance planar-inverted perovskite solar cells.
Abstract
A series of metal acetylacetonates produced by a full low-temperature (below 100 °C) process are successfully employed to obtain both "multistable" and high-performance planar-inverted perovskite solar cells. All the three kinds of champion cells in small area exhibit over 18% in conversion-efficiency with negligible hysteresis, along with a conversion efficiency above 16% for planar PSCs in an aperture area of over 1 cm2 .

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Citations
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Boron nitride-incorporated NiOx as a hole transport material for high-performance p-i-n planar perovskite solar cells

TL;DR: The NiO:BN hole transport layer (HTLTL) has a deep energy level of highest occupied molecular orbital (HOMO) and smooth surface compared to pristine NiOx, which provide the better energy level alignment and better interface contact between NiO-BN HTL and perovskite, improving charge extraction and transportation and inhibiting recombination of charge as mentioned in this paper.
Journal ArticleDOI

Efficient Inverted Perovskite Solar Cells Enabled by Dopant-Free Hole-Transporting Materials Based on Dibenzofulvene-Bridged Indacenodithiophene Core Attaching Varying Alkyl Chains

TL;DR: In this article, two rationally designed hole-transporting material (HTM) with butterfly-shaped triarylamine groups based on dibenzo-fulvene-bridged indacenodithiophene (IDT) core (attaching hexyl and octyl chains) have been synthesized, namely, IT-C6 and IT-c8, respectively.
References
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Journal ArticleDOI

Organometal Halide Perovskites as Visible-Light Sensitizers for Photovoltaic Cells

TL;DR: Two organolead halide perovskite nanocrystals were found to efficiently sensitize TiO(2) for visible-light conversion in photoelectrochemical cells, which exhibit strong band-gap absorptions as semiconductors.
Journal ArticleDOI

Efficient Hybrid Solar Cells Based on Meso-Superstructured Organometal Halide Perovskites

TL;DR: A low-cost, solution-processable solar cell, based on a highly crystalline perovskite absorber with intense visible to near-infrared absorptivity, that has a power conversion efficiency of 10.9% in a single-junction device under simulated full sunlight is reported.
Journal ArticleDOI

Electron-hole diffusion lengths exceeding 1 micrometer in an organometal trihalide perovskite absorber.

TL;DR: In this article, transient absorption and photoluminescence-quenching measurements were performed to determine the electron-hole diffusion lengths, diffusion constants, and lifetimes in mixed halide and triiodide perovskite absorbers.
Journal ArticleDOI

Efficient planar heterojunction perovskite solar cells by vapour deposition

TL;DR: It is shown that perovskite absorbers can function at the highest efficiencies in simplified device architectures, without the need for complex nanostructures.
Journal Article

Electron-Hole Diffusion Lengths Exceeding 1 Micrometer in an Organometal Trihalide Perovskite Absorber

TL;DR: In this paper, transient absorption and photoluminescence-quenching measurements were performed to determine the electron-hole diffusion lengths, diffusion constants, and lifetimes in mixed halide and triiodide perovskite absorbers.
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