Journal ArticleDOI
Metal-free carbocatalysis in advanced oxidation reactions
TLDR
This Account showcases the recent contributions to metal-free catalysis in advanced oxidation, including design of nanocarbon catalysts, exploration of intrinsic active sites, and identification of reactive species and reaction pathways, and offers perspectives on carbocatalysis for future environmental applications.Abstract:
ConspectusCatalytic processes have remarkably boosted the rapid industrializations in chemical production, energy conversion, and environmental remediation. As one of the emerging applications of carbocatalysis, metal-free nanocarbons have demonstrated promise as catalysts for green remediation technologies to overcome the poor stability and undesirable metal leaching in metal-based advanced oxidation processes (AOPs). Since our reports of heterogeneous activation of persulfates with low-dimensional nanocarbons, the novel oxidative system has raised tremendous interest for degradation of organic contaminants in wastewater without secondary contamination. In this Account, we showcase our recent contributions to metal-free catalysis in advanced oxidation, including design of nanocarbon catalysts, exploration of intrinsic active sites, and identification of reactive species and reaction pathways, and we offer perspectives on carbocatalysis for future environmental applications.The journey starts with the dis...read more
Citations
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Recent progress on carbon nanomaterials for the electrochemical detection and removal of environmental pollutants
TL;DR: Various carbon nanomaterials including carbon nanotubes, graphene, mesoporous carbon, carbon dots, and boron-doped diamond have been extensively utilized and further proven to be ideal candidates for resolving environmental problems, emerging as adsorbents, electrochemical sensors and electrodes.
Journal ArticleDOI
Insights into the mechanism of non-radical activation of persulfate via activated carbon for the degradation of p-chloroaniline
TL;DR: In this article, the degradation of p-chloroaniline (PCA) by persulfate (PS) activated with activated carbon (AC) was examined and the effects of initial pH and dosage of AC were also investigated.
Journal ArticleDOI
Degradation of thiacloprid via unactivated peroxymonosulfate: The overlooked singlet oxygen oxidation
TL;DR: In this paper, the authors investigated the role of singlet oxygen (1O2) in the degradation of thiacloprid (THIA) by peroxymonosulfate (PMS) without explicit activation.
Journal ArticleDOI
Metal-based catalysts for persulfate and peroxymonosulfate activation in heterogeneous ways: A review
TL;DR: In this paper , the up-to-date research progresses on various heterogeneous metal-based catalysts for persulfate and peroxymonosulfate (PMS) activation, including single metal and mixed metal catalysts.
Journal ArticleDOI
Metal-free graphene-based catalytic membrane for degradation of organic contaminants by persulfate activation
TL;DR: In this article, a metal-free catalytic membrane was used as the single activator of persulfate (PS) in water treatment and it was applied in filtration experiments for the degradation of phenol and oxalic acid.
References
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Journal ArticleDOI
Sulfur and Nitrogen Dual-Doped Mesoporous Graphene Electrocatalyst for Oxygen Reduction with Synergistically Enhanced Performance†
TL;DR: In this paper, Mesoporous graphene doped with both N and S atoms (N-S-G) was prepared in one step and studied as an electrochemical catalyst for the oxygen reduction reaction (ORR).
Journal ArticleDOI
Generation of sulfate radical through heterogeneous catalysis for organic contaminants removal: Current development, challenges and prospects
TL;DR: In this paper, the authors provide a state-of-the-art review on the development in heterogeneous catalysts including single metal, mixed metal, and nonmetal carbon catalysts for organic contaminants removal, with particular focus on peroxymonosulfate (PMS) activation.
Journal ArticleDOI
Environmental applications of carbon-based nanomaterials.
TL;DR: This review critically assesses the contributions of carbon-based nanomaterials to a broad range of environmental applications: sorbents, high-flux membranes, depth filters, antimicrobial agents, environmental sensors, renewable energy technologies, and pollution prevention strategies.
Journal ArticleDOI
Iron Encapsulated within Pod‐like Carbon Nanotubes for Oxygen Reduction Reaction
Dehui Deng,Liang Yu,Xiaoqi Chen,Guoxiong Wang,Li Jin,Xiulian Pan,Jiao Deng,Gongquan Sun,Xinhe Bao +8 more
TL;DR: Chainmail for catalysts: a catalyst with iron nanoparticles confined inside pea-pod-like carbon nanotubes exhibits a high activity and remarkable stability as a cathode catalyst in polymer electrolyte membrane fuel cells (PEMFC), even in presence of SO(2).
Journal ArticleDOI
Nanocarbons for the Development of Advanced Catalysts
TL;DR: This poster presents a probabilistic procedure to evaluate the response of the H2O/O2 mixture to various pyrolysis conditions and shows promising results in both the horizontal and the vertical domain.
Related Papers (5)
Generation of sulfate radical through heterogeneous catalysis for organic contaminants removal: Current development, challenges and prospects
Activation of persulfate (PS) and peroxymonosulfate (PMS) and application for the degradation of emerging contaminants
Jianlong Wang,Shizong Wang +1 more