Metal Thio- and Selenophosphates as Multifunctional van der Waals Layered Materials.
Michael A. Susner,Michael A. Susner,Marius Chyasnavichyus,Michael A. McGuire,Panchapakesan Ganesh,Petro Maksymovych +5 more
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TLDR
A broad family of layered metal thio(seleno)phosphate materials that are moderate- to wide-bandgap semiconductors with incipient ionic conductivity and a host of ferroic properties are reviewed, arguing that this material class has the potential to merge the sought-after properties of complex oxides with electronic functions of 2D and quasi-2D electronic materials.Abstract:
Since the discovery of Dirac physics in graphene, research in 2D materials has exploded with the aim of finding new materials and harnessing their unique and tunable electronic and optical properties. The follow-on work on 2D dielectrics and semiconductors has led to the emergence and development of hexagonal boron nitride, black phosphorus, and transition metal disulfides. However, the spectrum of good insulating materials is still very narrow. Likewise, 2D materials exhibiting correlated phenomena such as superconductivity, magnetism, and ferroelectricity have yet to be developed or discovered. These properties will significantly enrich the spectrum of functional 2D materials, particularly in the case of high phase-transition temperatures. They will also advance a fascinating fundamental frontier of size and proximity effects on correlated ground states. Here, a broad family of layered metal thio(seleno)phosphate materials that are moderate- to wide-bandgap semiconductors with incipient ionic conductivity and a host of ferroic properties are reviewed. It is argued that this material class has the potential to merge the sought-after properties of complex oxides with electronic functions of 2D and quasi-2D electronic materials, as well as to create new avenues for both applied and fundamental materials research in structural and magnetic correlations.read more
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References
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Journal ArticleDOI
Iron and nickel phosphorus trisulfides as electroactive materials for primary lithium batteries
TL;DR: In this article, the theoretical specific capacities of a family of layered compounds MPX3 (M = Fe, Co, Ni; X = S, Se) for current-producing reactions involving 1.5, 2, 6 and 9 lithium atoms per MPX 3 molecule have been estimated.
Journal ArticleDOI
Reflectance spectra of some FeP S 3 -type layer compounds in the vacuum ultraviolet
F. S. Khumalo,H. P. Hughes +1 more
Journal ArticleDOI
Infrared studies of lithium intercalation in the FePS3 and NiPS3 layer-type compounds
TL;DR: In this paper, the infrared spectra (700-30 cm-1) of several lithium intercalates (chemically prepared) LixMPS3, with M=Fe, Ni and 0
Journal ArticleDOI
Magnetic properties and specific heat of MPS3 (M=Mn, Fe, Zn)
TL;DR: In this paper, the magnetic properties and specific heat of MPS3 (M=Mn, Fe and Zn) have been investigated while ZnPS3 is non-magnetic, MnPS3 and FePS3 are antiferromagnets with the Neel temperature TN of 78 and 118 K, respectively.
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Electrical characteristics of MoS2 field-effect transistor with ferroelectric vinylidene fluoride-trifluoroethylene copolymer gate structure
TL;DR: In this article, the authors demonstrated fabrication and characterization of FeFET based on MoS2 channel with vinylidene fluoride (VDF)-trifluoroethylene (TrFE) copolymer as back-gate insulator.