Metal Thio- and Selenophosphates as Multifunctional van der Waals Layered Materials.
Michael A. Susner,Michael A. Susner,Marius Chyasnavichyus,Michael A. McGuire,Panchapakesan Ganesh,Petro Maksymovych +5 more
Reads0
Chats0
TLDR
A broad family of layered metal thio(seleno)phosphate materials that are moderate- to wide-bandgap semiconductors with incipient ionic conductivity and a host of ferroic properties are reviewed, arguing that this material class has the potential to merge the sought-after properties of complex oxides with electronic functions of 2D and quasi-2D electronic materials.Abstract:
Since the discovery of Dirac physics in graphene, research in 2D materials has exploded with the aim of finding new materials and harnessing their unique and tunable electronic and optical properties. The follow-on work on 2D dielectrics and semiconductors has led to the emergence and development of hexagonal boron nitride, black phosphorus, and transition metal disulfides. However, the spectrum of good insulating materials is still very narrow. Likewise, 2D materials exhibiting correlated phenomena such as superconductivity, magnetism, and ferroelectricity have yet to be developed or discovered. These properties will significantly enrich the spectrum of functional 2D materials, particularly in the case of high phase-transition temperatures. They will also advance a fascinating fundamental frontier of size and proximity effects on correlated ground states. Here, a broad family of layered metal thio(seleno)phosphate materials that are moderate- to wide-bandgap semiconductors with incipient ionic conductivity and a host of ferroic properties are reviewed. It is argued that this material class has the potential to merge the sought-after properties of complex oxides with electronic functions of 2D and quasi-2D electronic materials, as well as to create new avenues for both applied and fundamental materials research in structural and magnetic correlations.read more
Citations
More filters
Journal ArticleDOI
Two-dimensional magnetic crystals and emergent heterostructure devices
TL;DR: Recognizing that magnetic anisotropy can be used to induce stable magnetism in atomic monolayers, Gong and Zhang provide an overview of the materials available and the physical understanding of the effects and then discuss how these effects could be exploited for widespread practical applications.
Journal ArticleDOI
Suppression of magnetic ordering in XXZ-type antiferromagnetic monolayer NiPS 3
Kangwon Kim,Soo Yeon Lim,Jae-Ung Lee,Sungmin Lee,Tae Yun Kim,Kisoo Park,Gun Sang Jeon,Cheol-Hwan Park,Je-Geun Park,Hyeonsik Cheong +9 more
TL;DR: In this paper, it was shown that the XXZ-type antiferromagnetic order of a magnetic van der Waals material, NiPS3, behaves upon reducing the thickness and ultimately becomes unstable in the monolayer limit.
Journal ArticleDOI
Probing and controlling magnetic states in 2D layered magnetic materials
TL;DR: In this article, the authors survey the physical properties of the large class of layered magnetic materials, and discuss recent advances in the study of these materials in the 2D limit, including optical and electrical techniques used for probing 2D magnetic materials and mechanisms for reorienting and/or switching 2D magnets by electric fields.
Journal ArticleDOI
New Frontiers on van der Waals Layered Metal Phosphorous Trichalcogenides
Journal ArticleDOI
Emergent phenomena and proximity effects in two-dimensional magnets and heterostructures.
TL;DR: This Review summarizes recent progress in exploring the intrinsic magnetism of atomically thin van der Waals materials, manipulation of their magnetism by tuning the interlayer coupling, and device structures for spin- and valleytronic applications.
References
More filters
Journal ArticleDOI
Darstellung von quaternären Selenodiphosphaten(IV) aus Halogenidschmelzen: Die Kristallstruktur von CuAl[P2Se6]
Regine Pfeiff,Rüdiger Kniep +1 more
TL;DR: In this paper, the quaternary hexaselenodiphosphate CuAl[P₂Se₆] (trig. R 3 (No. 148); a = 627.95(2) pm; c = 1997.13(6) pm.
Journal ArticleDOI
Numerical-Basis-Set LCAO Method Using Gaussian-Fitting of Orbitals Potential
Noriyuki Kurita,Kenji Nakao +1 more
TL;DR: In this article, a new procedure is presented for the ab-initio self-consistent calculation of the band structure of complex crystals, based on the numerical-basis-set LCAO method and the norm-conserving pseudopotential in the local density functional formalism.
Journal ArticleDOI
Acoustic wave velocities and elastic properties of Sn2P2(Se0.28S0.72)6 solid solutions
TL;DR: An experimental study and analysis of the acoustic properties of Sn2P2(Se0.28S0.72)6 ferroelectric crystals was presented in this article. But the results were limited to the case of the slowest acoustic wave.
Journal ArticleDOI
Piezoelectric and Ultrasonic Studies of New Lamellar Crystals of CuInP2S6 Type
TL;DR: In this paper, the ultrasonic and piezoelectric investigations were performed in CuInP2S6 family layered crystals, where Cu, In, S were substituted by Ag, Bi and Se.