Journal ArticleDOI
MoC/MAPbI3 hybrid composites for efficient photocatalytic hydrogen evolution.
TLDR
MoC/MAPbIglesias as discussed by the authors has shown excellent hydrogen evolution rate performance under visible light by using the non-precious metal promoter MoC to modify MAPbI3, and provides a new idea for the synthesis of efficient MAP bI3-based composite catalysts.Abstract:
Metal halide perovskites, such as iodine methylamine lead (MAPbI3), have received extensive attention in the field of photocatalytic decomposition of HI for hydrogen evolution, due to their excellent photoelectric properties. In this paper, a new MAPbI3-based composite, MoC/MAPbI3, was synthesized. The results show that 15 wt% MoC/MAPbI3 has the best hydrogen production performance (38.4 μmol h−1), which is approximately 24-times that of pure MAPbI3 (1.61 μmol h−1). With the extension of the catalytic time, the hydrogen production rate of MoC/MAPbI3 reached 165.3 μmol h−1 after 16 h due to the effective separation and transfer of charge carriers between MoC and MAPbI3, showing excellent hydrogen evolution rate performance under visible light. In addition, the cycling stability of MoC/MAPbI3 did not decrease in multiple 4 h cycle tests. This study used the non-precious metal promoter MoC to modify MAPbI3, and provides a new idea for the synthesis of efficient MAPbI3-based composite catalysts.read more
Citations
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Bismuthene as a versatile photocatalyst operating under variable conditions for the photoredox C H bond functionalization
TL;DR: In this article , the use of 2D bismuthene as a photocatalyst in a liquid-phase organic transformation was reported for the first time, and a density functional theory (DFT) study revealed mechanistic details that lie behind the catalytic activity.
Journal ArticleDOI
Bismuthene as a versatile photocatalyst operating under variable conditions for the photoredox CH bond functionalization
Melek Sermin Ozer,Önder Metin,Zafer Eroglu,Zafer Eroglu,Ahsen Sare Yalin,Murat Kılıç,Ursula Rothlisberger,Önder Metin +7 more
TL;DR: In this article, the use of 2D bismuthene as a photocatalyst in a liquid-phase organic transformation was reported for the first time, and a density functional theory (DFT) study revealed mechanistic details that lie behind the catalytic activity.
Journal ArticleDOI
Metal Carbide‐Based Cocatalysts for Photocatalytic Solar‐to‐Fuel Conversion
Ke-jing He,Eric F. Campbell,Zimo Huang,Ron Y. Shen,Qi Li,Shanqing Zhang,Yu Lin Zhong,Peng Zhang,Xin Li +8 more
TL;DR: In this paper , the authors highlight some recent crucial advances in active metal carbide-based cocatalysts for photocatalytic solar-to-fuel conversion and highlight some new options for rationally designing and developing novel and efficient metal carbides-based composites for highly active and selective photovoltaic solar to fuel conversion.
Journal ArticleDOI
Photocatalytic hydrogen evolution performance of metal ferrites /polypyrrole nanocomposites
Sanaz Chamani,E. Sadeghi,Naeimeh Sadat Peighambardoust,Fatmanur Doganay,Gizem Yanalak,Zafer Eroglu,Emre Aslan,E. Asghari,Oender Metin,Imren Hatay Patir,Umut Aydemir,M. Khatamian +11 more
TL;DR: In this paper , a photocatalytic hydrogen evolution (HER) amount for [email protected] was found to be 10.44 mmol g−1, far greater than any other composite catalysts in terms of photocatalysis.
Journal ArticleDOI
Expediting H2 Evolution over MAPbI3 with a Nonnoble Metal Cocatalyst Mo2C under Visible Light
Jinxing Yu,Xiaoxiang Xu +1 more
TL;DR: In this article , Mo2C nanoparticles have been anchored onto methylammonium lead iodide (MAPbI3) as a nonnoble metal cocatalyst to promote H2 evolution reactions.
References
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