Open AccessJournal Article
MOF-5/n-Bu₄NBr: an efficient catalyst system for the synthesis of cyclic carbonates from epoxides and CO₂ under mild conditions
TLDR
In this article, the coupling reaction of CO₂ with propylene oxide (PO) to produce propylene carbonate (PC) catalyzed by MOF-5 (metal-organic frameworks) in the presence of quaternary ammonium salts (Me₄NCl, Me₆NBr, EtₘnBr, n-Pr₲NBr) was studied in different conditions.About:
This article is published in Green Chemistry.The article was published on 2009-01-01 and is currently open access. It has received 345 citations till now. The article focuses on the topics: Cycloaddition & Propylene oxide.read more
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Carbon capture and conversion using metal–organic frameworks and MOF-based materials
TL;DR: This review provides a comprehensive account of significant progress in the design and synthesis of MOF-based materials, including MOFs, MOF composites and MOF derivatives, and their application to carbon capture and conversion.
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Metal‐Organic Frameworks: A Rapidly Growing Class of Versatile Nanoporous Materials
TL;DR: This review covers advances in the MOF field from the past three years, focusing on applications, including gas separation, catalysis, drug delivery, optical and electronic applications, and sensing.
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The chemistry of metal–organic frameworks for CO 2 capture, regeneration and conversion
Christopher A. Trickett,Aasif Helal,Bassem A. Al-Maythalony,Zain H. Yamani,Kyle E. Cordova,Omar M. Yaghi +5 more
TL;DR: In this paper, structural and chemical features of state-of-the-art metal-organic frameworks for their application in the entire carbon cycle of capturing, purifying and transforming CO 2 into valuable products are described.
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Capture and conversion of CO2 at ambient conditions by a conjugated microporous polymer.
TL;DR: The cobalt-coordinated conjugated microporous polymers can also simultaneously function as heterogeneous catalysts for the reaction of CO2 and propylene oxide at atmospheric pressure and room temperature, wherein the polymers demonstrate better efficiency than a homogeneous salen-cobalt catalyst.
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Catalysis by Metal Organic Frameworks: Perspective and Suggestions for Future Research
Dong Yang,Bruce C. Gates +1 more
TL;DR: In this paper, the advantages and limitations of MOFs as catalysts are summarized and fundamental issues to be addressed about their potential applications, including shape-selective and bifunctional catalysis, and quantifying reaction/transport processes in MOFs, identifying catalytic sites, and determining intrinsic catalytic reaction rates.
References
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Functional porous coordination polymers.
TL;DR: The aim is to present the state of the art chemistry and physics of and in the micropores of porous coordination polymers, and the next generation of porous functions based on dynamic crystal transformations caused by guest molecules or physical stimuli.
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Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage
Mohamed Eddaoudi,Jaheon Kim,Nathaniel L. Rosi,David T. Vodak,Joseph Wachter,Michael O'Keeffe,Omar M. Yaghi +6 more
TL;DR: Metal-organic framework (MOF-5), a prototype of a new class of porous materials and one that is constructed from octahedral Zn-O-C clusters and benzene links, was used to demonstrate that its three-dimensional porous system can be functionalized with the organic groups and can be expanded with the long molecular struts biphenyl, tetrahydropyrene, pyrene, and terphenyl.
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Design and synthesis of an exceptionally stable and highly porous metal-organic framework
TL;DR: In this article, an organic dicarboxylate linker is used in a reaction that gives supertetrahedron clusters when capped with monocarboxyates.
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From molecules to crystal engineering: supramolecular isomerism and polymorphism in network solids.
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Transformation of carbon dioxide.
TL;DR: Reaction Mechanism, Synthesis of Urea and Urethane Derivatives, and Alcohol Homologation 2382 10.1.