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Multicomponent isoreticular metal-organic frameworks: Principles, current status and challenges

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TLDR
The mixed-linker-based multivariate metal-organic frameworks are synthesized employing various systematic strategies which include Linker-Directed Vertex De-symmetrization, Random Mixed-Linker Distribution, covalent pre-and post-synthetic modification techniques, etc as discussed by the authors.
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This article is published in Coordination Chemistry Reviews.The article was published on 2021-10-15. It has received 164 citations till now.

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Current status and prospects of metal-organic frameworks for bone therapy and bone repair.

TL;DR: Metal organic frameworks (MOFs) are a new class of developed functional materials that have been widely used in the biomedical field during the recent years due to their porous nature, large specific surface area and diverse structures.
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A new magnetic adsorbent of eggshell-zeolitic imidazolate framework for highly efficient removal of norfloxacin.

TL;DR: In this paper, the magnetic biocomposite (eggshell-zeolitic imidazolate framework-8 (ZIF-8) particles were stabilized on the surface of magnetic eggshell (Fe3O4-ES).
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Metal Organic Framework as an Efficient Adsorbent for Drugs from Wastewater

TL;DR: In this paper , the utility of metal-organic frameworks (MOFs) to adsorption properties and related mechanism to remove drugs from wastewater are presented. But, due to their instability and difficulty in recycling in aqueous media, their application as an adsorbent is limited, and hence further investigation and syntheses of materials to overcome this shortcoming remains an arduous task.
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The extra-large calixarene-based MOFs-derived hierarchical composites for photocatalysis of dye: Facile syntheses and contribution of carbon species

TL;DR: In this paper , the photocatalytic optimizations of Cu/C composites were estimated by the disintegration of methyl violet (MV) dye by calcining the synthesized three calkylpyrogallol[4]arenes (PgCs) metal-organic nanocapsules (MONCs) precursors.
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A multimodal Metal-Organic framework based on unsaturated metal site for enhancing antitumor cytotoxicity through Chemo-Photodynamic therapy.

TL;DR: In this paper , a new multifunctional platform with the core-shell structure 5-ALA@UiO-66-NH-FAM@CP1 (ALA = 5aminolevulinic acid, CP1 = zirconium-pemetrexed (Zr-MTA)) has been performed.
References
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Journal ArticleDOI

Reticular synthesis and the design of new materials

TL;DR: This work has shown that highly porous frameworks held together by strong metal–oxygen–carbon bonds and with exceptionally large surface area and capacity for gas storage have been prepared and their pore metrics systematically varied and functionalized.
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Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage

TL;DR: Metal-organic framework (MOF-5), a prototype of a new class of porous materials and one that is constructed from octahedral Zn-O-C clusters and benzene links, was used to demonstrate that its three-dimensional porous system can be functionalized with the organic groups and can be expanded with the long molecular struts biphenyl, tetrahydropyrene, pyrene, and terphenyl.
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Ultrahigh Porosity in Metal-Organic Frameworks

TL;DR: The synthesis of a MOF in which zinc centers are bridged with long, highly conjugated organic linkers, but in which the overall symmetry of the networks created prevents formation of interpenetrating networks is described.
Journal ArticleDOI

Soft porous crystals

TL;DR: The concept of the cooperative integration of 'softness' and 'regularity' and the relationship between the structures and properties of these materials in view of their practical applications are discussed.
Journal ArticleDOI

Multiple Functional Groups of Varying Ratios in Metal-Organic Frameworks

TL;DR: It is shown that metal-organic frameworks (MOFs) can incorporate a large number of different functionalities on linking groups in a way that mixes the linker, rather than forming separate domains.
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