Journal ArticleDOI
Role of initiator‐transfer agent‐terminator (iniferter) in radical polymerizations: Polymer design by organic disulfides as iniferters
Takayuki Otsu,Masatoshi Yoshida +1 more
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This article is published in Die Makromolekulare Chemie, Rapid Communications.The article was published on 1982-02-16. It has received 647 citations till now. The article focuses on the topics: Transfer agent.read more
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Metal-Containing initiator Systems. XXXVI. Synthesis of Block Copolymer of Methyl Acrylate and α-Methylbenzyl Methacrylate with Binary Initiator System of Cobaltocene and Bis(ethyl acetoacetato)copper(II)
TL;DR: In this paper, a block copolymer was obtained in 90% yield in the polymerization of MBMA with a polymer radical which prepared from MA with this system for 1 day.
Reference EntryDOI
Living Radical Polymerization
Mitsuo Sawamoto,Masami Kamigaito +1 more
TL;DR: In this paper, the authors discuss living or controlled radical polymerization involving covalent dormant species.The sections in this article are==================672============Initiation of Free Radical Polymerization============
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A reactive polystyrene- block -polyisoprene star copolymer as a toughening agent in an epoxy thermoset
TL;DR: A polystyrene block polyisoprene ((PS-b-PI)3) was synthesized by photochemical reversible addition fragmentation chain transfer (RAFT) polymerization as discussed by the authors.
Journal ArticleDOI
Supramolecular Polymerization of a Photo-Fluttering Chiral Monomer: A Temporarily Suspendable Chain Growth by Light.
TL;DR: Using a photochemically fluttering thiophene-fused cyclooctatetraene derivative (COT) as a nonplanar chiral monomer, the authors has succeeded in remotely suspending the supramolecular polymerization in a temporal manner by a completely new strategy.