Journal ArticleDOI
Role of initiator‐transfer agent‐terminator (iniferter) in radical polymerizations: Polymer design by organic disulfides as iniferters
Takayuki Otsu,Masatoshi Yoshida +1 more
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This article is published in Die Makromolekulare Chemie, Rapid Communications.The article was published on 1982-02-16. It has received 647 citations till now. The article focuses on the topics: Transfer agent.read more
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Synthesis of polyurethane-g-poly(ethylene glycol) copolymers by macroiniferter and their protein resistance
TL;DR: In this article, a polyurethane (PU)-g-poly(ethylene glycol) (PEG) copolymers for protein resistance were synthesized by using a macroiniferter consisting of 1,1,2,2-tetraphenyl-1, 2-ethanediol and isocyanate-terminated prepolymer with poly(tetramethylene gels) segments.
Book ChapterDOI
Telomerisation Reactions of fluorinated alkenes
Bruno Ameduri,Bernard Boutevin +1 more
TL;DR: The synthesis of fluorinated oligomers by radical telomerization of fluoroalkenes is discussed in this article, with a brief presentation of the various parameters which direct this reaction and the kinetic laws.
Journal ArticleDOI
Investigation into the mechanism of photo-mediated RAFT polymerization involving the reversible photolysis of the chain-transfer agent
TL;DR: In this paper, a new dithiocarbamate with a N-carbazole Z group is synthesized and investigated as a chain-transfer agent (CTA) in a photo-mediated RAFT polymerization mechanism involving its partial and reversible photolysis.
Journal ArticleDOI
Kinetic Behavior of Atom Transfer Radical Polymerization of Dimethacrylates
TL;DR: In this article, the reaction behavior and kinetics of the atom transfer radical polymerization (ATRP) of poly(ethylene glycol) dimethacrylates (PEGDMA) were studied with respect to polymerization rate, vinyl conversion and the development of a crosslinked network.
& Heterogeneous Catalysis Synthesis, Solid-State NMR Characterization, and Application for Hydrogenation Reactions of a Novel Wilkinson's-Type Immobilized Catalyst
Safaa Abdulhussain,Hergen Breitzke,Tomasz Ratajczyk,Anna Grnberg,Mohamad Srour,Danjela Arnaut,Heiko Weidler,Ulrike Kunz,Hans-Joachim Kleebe,Ute Bommerich,Johannes Bernarding,Torsten Gutmann,Gerd Buntkowsky +12 more
TL;DR: First applications of this catalyst in hydrogenation reactions employing para-enriched hydrogen gas (PHIP experiments) and an assessment of its leaching properties are presented.