Journal ArticleDOI
Role of initiator‐transfer agent‐terminator (iniferter) in radical polymerizations: Polymer design by organic disulfides as iniferters
Takayuki Otsu,Masatoshi Yoshida +1 more
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This article is published in Die Makromolekulare Chemie, Rapid Communications.The article was published on 1982-02-16. It has received 647 citations till now. The article focuses on the topics: Transfer agent.read more
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Book ChapterDOI
Other Initiating Systems
TL;DR: A purely thermal polymerization is one in which a monomer is converted to polymer by thermal energy alone as mentioned in this paper, where the identity of the initiating radicals and the mechanisms by which they are formed remain obscure.
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Synthesis and characterization of novel polystyrene‐block‐polyurethane‐block‐polystyrene tri‐block copolymers through atom transfer radical polymerization
TL;DR: In this paper, the authors describe the method of synthesizing tri-block copolymers using Atom Transfer Radical Polymerization (ATRP) for polystyrene-block-polyurethane-blockpolystyrene.
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Living radical polymerization of diisopropyl fumarate to obtain block copolymers containing rigid poly(substituted methylene) and flexible polyacrylate segments
TL;DR: In this paper, a living radical polymerization of diisopropyl fumarate (DiPF) is carried out to synthesize poly(diisopric fumetric) (PDiPF) as a rigid poly(substituted methylene) and its block copolymers combined with a flexible polyacrylate segment.
Journal ArticleDOI
Block Copolymers by Mechanistic Transformation from PROAD to Iniferter Process
TL;DR: A facile strategy for synthesizing block copolymers by the combination of two different living polymerization techniques, namely, photoinduced radical oxidation/addition/deactivation (PROAD) and iniferter processes is described.