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Role of initiator‐transfer agent‐terminator (iniferter) in radical polymerizations: Polymer design by organic disulfides as iniferters
Takayuki Otsu,Masatoshi Yoshida +1 more
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This article is published in Die Makromolekulare Chemie, Rapid Communications.The article was published on 1982-02-16. It has received 647 citations till now. The article focuses on the topics: Transfer agent.read more
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Advances in design and biomedical application of hierarchical polymer brushes
Ran Yang,Ran Yang,Xiaodan Wang,Xiaodan Wang,Shunjie Yan,Alideertu Dong,Shifang Luan,Shifang Luan,Jinghua Yin +8 more
TL;DR: This review systematically summarizes the recent developments in the construction and biological application of hierarchical polymer brushes, highlighting the rational design of numerous platforms to address various aspects of complex biological scenarios.
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Laboratory-scale mass production of a multi-micropatterned grafted surface with different polymer regions.
TL;DR: In this article, the authors demonstrate laboratory-scale mass production of a regionally precise multi-micropatterned surface photo-graft-copolymerized with three water-soluble monomers based on the photochemistry of an iniferter.
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Photo-induced living/controlled surface radical grafting polymerization and its application in fabricating 3-D micro-architectures on the surface of flat/particulate organic substrates
TL;DR: In this article, the fundamental chemistry and applications of photo-induced living surface grafting polymerization are discussed, and two technologies, i.e., 1-step and 2-step processes, their features and applications in fabricating polymer brushes with precisely controlled patterns, desired functions, branched and block grafting chains on planar substrates, and polymer lamination are presented.
The application of ionizing radiation in reversible addition fragmentation chain transfer (RAFT) polymerization: Renaissance of a key synthetic and kinetic tool
TL;DR: Ionizing radiation has been used in polymer chemistry as a means of initiating polymerization, crosslinking gels and decomposing particular polymer components as discussed by the authors, which is useful in applications where elevated temperature is likely to be detrimental to the system, such as protein-polymer conjugates.
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Living Radical Polymerization of Styrene with Diphenyl Diselenide as a Photoiniferter. Synthesis of Polystyrene with Carbon-Carbon Double Bonds at Both Chain Ends
TL;DR: In this article, a linear relationship was found for a plot of Mn for polystyrene versus polymer yield, and it was shown that this polymerization proceeds through a living radical mechanism.