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Journal ArticleDOI

Simple Way to Engineer Metal-Semiconductor Interface for Enhanced Performance of Perovskite Organic Lead Iodide Solar Cells

TLDR
A thin wide band gap organic semiconductor N,N,N',N'-tetraphenyl-benzidine layer has been introduced by spin-coating to engineer the metal-semiconductor interface in the hole-conductor-free perovskite solar cells and it is revealed that this modification can increase interfacial resistance of CH3NH3PbI3/Au interface and retard electron recombination process in the metal -semiconductors interface.
Abstract
A thin wide band gap organic semiconductor N,N,N′,N′-tetraphenyl-benzidine layer has been introduced by spin-coating to engineer the metal–semiconductor interface in the hole-conductor-free perovskite solar cells. The average cell power conversion efficiency (PCE) has been enhanced from 5.26% to 6.26% after the modification and a highest PCE of 6.71% has been achieved. By the aid of electrochemical impedance spectroscopy and dark current analysis, it is revealed that this modification can increase interfacial resistance of CH3NH3PbI3/Au interface and retard electron recombination process in the metal–semiconductor interface.

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Journal ArticleDOI

Organic–inorganic hybrid lead halide perovskites for optoelectronic and electronic applications

TL;DR: Recent progress on hybrid perovskites is reviewed including basic chemical and crystal structures, chemical synthesis of bulk/nanocrystals and thin films with their chemical and physical properties, device configurations, operation principles for various optoelectronic applications (with a focus on solar cells), and photophysics of charge-carrier dynamics.
Journal ArticleDOI

Under the spotlight: The organic–inorganic hybrid halide perovskite for optoelectronic applications

TL;DR: In this paper, the authors review the organic-inorganic hybrid halide perovskite and delve into its recent progress and relevant applications, highlighting its exceptional attributes including high carrier mobility, an adjustable spectral absorption range, long diffusion lengths, and the simplicity and affordability of fabrication.
Journal ArticleDOI

Inkjet Printing and Instant Chemical Transformation of a CH3NH3PbI3/Nanocarbon Electrode and Interface for Planar Perovskite Solar Cells

TL;DR: A planar perovskite solar cell that incorporates a nanocarbon hole-extraction layer is demonstrated for the first time by an inkjet printing technique with a precisely controlled pattern and interface.
Journal ArticleDOI

Triarylamine: Versatile Platform for Organic, Dye-Sensitized, and Perovskite Solar Cells.

TL;DR: This review focuses on the structure-property relationship of the TAA-based materials in OSCs, DSSCs, and PSCs in order to shed light on the solutions to the challenges in the field of organic and hybrid photovoltaics.
References
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Journal ArticleDOI

Efficient Hybrid Solar Cells Based on Meso-Superstructured Organometal Halide Perovskites

TL;DR: A low-cost, solution-processable solar cell, based on a highly crystalline perovskite absorber with intense visible to near-infrared absorptivity, that has a power conversion efficiency of 10.9% in a single-junction device under simulated full sunlight is reported.
Journal ArticleDOI

Sequential deposition as a route to high-performance perovskite-sensitized solar cells

TL;DR: A sequential deposition method for the formation of the perovskite pigment within the porous metal oxide film that greatly increases the reproducibility of their performance and allows the fabrication of solid-state mesoscopic solar cells with unprecedented power conversion efficiencies and high stability.
Journal ArticleDOI

Electron-hole diffusion lengths exceeding 1 micrometer in an organometal trihalide perovskite absorber.

TL;DR: In this article, transient absorption and photoluminescence-quenching measurements were performed to determine the electron-hole diffusion lengths, diffusion constants, and lifetimes in mixed halide and triiodide perovskite absorbers.
Journal ArticleDOI

Efficient planar heterojunction perovskite solar cells by vapour deposition

TL;DR: It is shown that perovskite absorbers can function at the highest efficiencies in simplified device architectures, without the need for complex nanostructures.
Journal Article

Electron-Hole Diffusion Lengths Exceeding 1 Micrometer in an Organometal Trihalide Perovskite Absorber

TL;DR: In this paper, transient absorption and photoluminescence-quenching measurements were performed to determine the electron-hole diffusion lengths, diffusion constants, and lifetimes in mixed halide and triiodide perovskite absorbers.
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