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Small-Diameter Silicon Nanowire Surfaces

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TLDR
These hydrogen-terminated SiNW surfaces seem to be more oxidation-resistant than regular silicon wafer surfaces, because atomically resolved STM images of SiNWs were obtained in air after several days' exposure to the ambient environment.
Abstract
Small-diameter (1 to 7 nanometers) silicon nanowires (SiNWs) were prepared, and their surfaces were removed of oxide and terminated with hydrogen by a hydrofluoric acid dip. Scanning tunneling microscopy (STM) of these SiNWs, performed both in air and in ultrahigh vacuum, revealed atomically resolved images that can be interpreted as hydrogen-terminated Si (111)-(1 × 1) and Si (001)-(1 × 1) surfaces corresponding to SiH 3 on Si (111) and SiH 2 on Si (001), respectively. These hydrogen-terminated SiNW surfaces seem to be more oxidation-resistant than regular silicon wafer surfaces, because atomically resolved STM images of SiNWs were obtained in air after several days9 exposure to the ambient environment. Scanning tunneling spectroscopy measurements were performed on the oxide-removed SiNWs and were used to evaluate the electronic energy gaps. The energy gaps were found to increase with decreasing SiNW diameter from 1.1 electron volts for 7 nanometers to 3.5 electron volts for 1.3 nanometers, in agreement with previous theoretical predictions.

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Citations
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Investigation on the reflectance properties on silicon nanowires grown by electroless etching

TL;DR: In this paper, the reflectance of silicon nanowires (SiNWs) were fabricated at four different lengths of time and three etching solution concentrations at room temperature using the electroless etching technique in a silver nitrate (AgNO3) and hydrofluoric acid (HF) based solution.
Journal ArticleDOI

Atomistic simulations of the tensile and melting behavior of silicon nanowires

TL;DR: In this article, the tensile and melting behavior of single-crystalline silicon nanowires (SiNWs) were investigated using molecular dynamics simulations with Stillinger-Weber potential.
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Effect of Oxidation-Induced Tensile Strain on Gate-All-Around Silicon-Nanowire-Based Single-Electron Transistor Fabricated Using Deep-UV Lithography

TL;DR: In this paper, the electrical characteristics of gate-all-around silicon nanowires (SiNWs) based single-electron transistors (SETs) operating at room temperature were investigated.
Journal ArticleDOI

Cubic lattice nanosheets: Thickness-driven light emission

TL;DR: The group led by Heon-Jin Choi demonstrates the gas-phase dendritic growth of Si nanosheets, only 1 to 13 nm thick, which display strong thickness-dependent photoluminescence in a visible range with red, green, and blue emission each documented.
Journal ArticleDOI

Counterbalanced Effect of Surface Trap and Auger Recombination on the Transverse Terahertz Carrier Dynamics in Silicon Nanowires

TL;DR: In this article, using ultrafast optical-pump and terahertz-probe spectroscopy, the Auger scattering significantly reduces the trap-mediated decay process of nanowires.
References
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Journal ArticleDOI

Optical gain in silicon nanocrystals

TL;DR: It is demonstrated that light amplification is possible using silicon itself, in the form of quantum dots dispersed in a silicon dioxide matrix, which opens a route to the fabrication of a silicon laser.
Journal ArticleDOI

Control of Thickness and Orientation of Solution-Grown Silicon Nanowires

TL;DR: Bulk quantities of defect-free silicon nanowires with nearly uniform diameters were grown to a length of several micrometers with a supercritical fluid solution-phase approach, and visible photoluminescence due to quantum confinement effects was observed, as were discrete optical transitions in the ultraviolet-visible absorbance spectra.
Journal ArticleDOI

Ideal hydrogen termination of the Si (111) surface

TL;DR: In this article, the effect of varying the solution pH on the surface structure was studied by measuring the SiH stretch vibrations with infrared absorption spectroscopy, and the surface was found to be very homogeneous with low defect density (<0.5%) and narrow vibrational linewidth.
Journal ArticleDOI

Diameter-controlled synthesis of single-crystal silicon nanowires

TL;DR: In this article, the authors synthesize monodisperse silicon nanowires by exploiting well-defined gold nanoclusters as catalysts for one-dimensional growth via a vapor-liquid-solid mechanism.
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