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Journal ArticleDOI

Stable alkali metal anodes enabled by crystallographic optimization-A review

TLDR
In this article, the authors summarize the recent advances in the crystallographic optimization for dendrite prevention and suppression and highlight the recent progress of crystallographic optimisation for a new generation of rechargeable batteries, including lithium metal batteries, sodium metal batteries and magnesium metal batteries.
Abstract
Alkali metal anodes have been regarded as an ideal candidate for next generation high-energy electrode couples due to their ultrahigh specific capacity and the lowest redox potential. However, their real-world application has been severely hampered by their highly uncontrollable chemical reactivity, which directly dictates metal dendrite growth behavior during cycling, low coulombic efficiency, and even safety concerns. Crystallographic optimization based on metal anode materials provides a fundamental solution for suppressing dendrite growth and enabling a stable metal anode, which has attracted extensive attention. In this perspective, we summarize the recent advances in the crystallographic optimization for dendrite prevention and suppression and highlight the recent progress of crystallographic optimization for a new generation of rechargeable batteries, including lithium metal batteries, sodium metal batteries, potassium metal batteries, zinc metal batteries and magnesium metal batteries. The challenges and prospects for the future development of crystallographic optimization are discussed to shed light on the future research of crystallographic optimization for boosting the performances of rechargeable batteries.

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Journal ArticleDOI

Porous Heteroatom-Doped Ti3C2Tx MXene Microspheres Enable Strong Adsorption of Sodium Polysulfides for Long-Life Room-Temperature Sodium-Sulfur Batteries.

TL;DR: In this article, a design strategy for encapsulation of sodium polysulfides using Ti3C2Tx MXene has been presented, which has a high reversible capacity (980 mAh g-1 at 0.5 C rate) and extended cycling stability.
Journal ArticleDOI

Element-Doped Mxenes: Mechanism, Synthesis, and Applications.

TL;DR: In this article , the authors comprehensively and critically discuss the syntheses, properties, and emerging applications of the growing family of heteroatom-doped MXenes materials, and present future opportunities and challenges for the study and application of multifunctional high-performance MXenes.
Journal ArticleDOI

Integrating a redox-coupled FeSe<sub>2</sub>/N–C photoelectrode into potassium ion hybrid capacitors for photoassisted charging

TL;DR: In this article , an energy-level-matched integrated photoelectrode with a 35.7% reduction in the reaction barrier based on electron-hole pair synergy under light irradiation was presented.
Journal ArticleDOI

Emerging Green Technologies for Recovery and Reuse of Spent Lithium-ion Batteries - A Review

TL;DR: In this article , the authors proposed rechargeable batteries, as one of the attractive energy storage technologies integrating renewable resources, as a solution to the growing global energy demand and environmental damage are driving the pursuit of sustainable energy and storage technologies.
Journal ArticleDOI

Integrated Photovoltaic Charging and Energy Storage Systems: Mechanism, Optimization, and Future.

TL;DR: In this article , a review of photo-electrochemical (PEC) and redox batteries for large-scale solar energy capture, conversion, and storage is presented, where the matching problem of high-performance dye sensitizers, strategies to improve the performance of photoelectrode PEC, and the working mechanism and structure design of multi-energy photoelectronic integrated devices are analyzed.
References
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Journal ArticleDOI

The Brønsted-Evans-Polanyi relation and the volcano plot for ammonia synthesis over transition metal catalysts

TL;DR: Using density functional calculations, the authors showed that there is an essentially linear relationship between the activation energy for N2 dissociation and the binding energy of atomic nitrogen on a range of transition metal surfaces.
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TL;DR: This work presents the largest database of calculated surface energies for elemental crystals to date, which contains the surface energies of more than 100 polymorphs of about 70 elements, up to a maximum Miller index of two and three for non-cubic and cubic crystals, respectively.
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The Three-Dimensional Dendrite-Free Zinc Anode on a Copper Mesh with a Zinc-Oriented Polyacrylamide Electrolyte Additive

TL;DR: In this article, a synergistic method that combines the Cu-Zn solid solution interface on a copper mesh skeleton with good zinc affinity and a polyacrylamide electrolyte additive to modify the zinc anode, which can greatly reduce the overpotential of the zinc nucleation and increase the stability of zinc deposition, is presented.
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Underpotential deposition of metals and work function differences

TL;DR: In this article, the potential difference between monolayer and bulk deposition is closely related to the difference in the work functions of substrate and deposit, causing a partial charge of the adatoms.
Journal ArticleDOI

Diffusion-controlled cluster formation in 2—6-dimensional space

TL;DR: In this article, the radius of gyration of the cluster is related to the number of particles in a diffusion-controlled cluster formation on lattices of dimensionality 2-6.
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