Journal ArticleDOI
Suzuki–Miyaura cross coupling reaction: recent advancements in catalysis and organic synthesis
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TLDR
The advancements (within the last 4 years) in catalysis related to SMCR that would be beneficial for researchers in designing synthetic protocols for the preparation of pharmacophores as well as drug molecules are discussed.About:
This article is published in Catalysis Science & Technology.The article was published on 2021-03-02. It has received 68 citations till now. The article focuses on the topics: Organic synthesis.read more
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DFT mechanistic studies of boron-silicon exchange reactions between silyl-substituted arenes and boron bromides.
TL;DR: In this paper , density functional theory (DFT) calculations were performed to map out the reaction pathways for a range of boron-silicon exchange reactions between Boron tribromide (BBr3) and trimethylsilyl-substituted arenes (TMSAr).
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Bimetallic (AuAg, AuPd and AgPd) nanoparticles supported on cellulose-based hydrogel for reusable catalysis.
Xiong Liu,Fangfei Liu +1 more
TL;DR: In this paper , a cellulose-based hydrogel is designed to load bimetallic (AuAg, AuPd and AgPd) nanoparticles for 4-Nitrophenol reduction and Suzuki-Miyaura coupling reactions.
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Carbonylative Suzuki Coupling Catalyzed by Pd Complexes Based on [N,P]‐Pyrrole Ligands: Direct Access to 2‐Hydroxybenzophenones
Salvador Cortés‐Mendoza,Dorian Adamczyk,J I Badillo-Gómez,Martine Urrutigoïty,M. Carmen Ortega-Alfaro,José G. López-Cortés +5 more
TL;DR: In this article , the Suzuki-Miyaura cross-coupling is used to build C−C bonds, but the use of hydroxyaryl halides to direct access hydroxy-byaryls still remains a challenge.
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Chemoenzymatic Cascades Combining Biocatalysis and Transition Metal Catalysis for Asymmetric Synthesis
Isabelle Mehawej,Gilles Séraphin +1 more
TL;DR: In this paper , a minireview is organized based on the action of the metal species (Pd, Ru, Au, Ir, Fe…) in combination with different enzymes, and special attention is paid to the design of sequential processes and concurrent cascades.
Journal ArticleDOI
Force-Modulated C–C Reductive Elimination from Nickel Bis(polyfluorophenyl) Complexes
TL;DR: In this article , the authors analyzed the rate of reductive elimination from nickel(II) bis(2,4,6-trifluorophenyl) complexes (P-P)Ni(2.4, 6-C6H2F3)2 containing either MeOBiPhep (3a) or a macrocyclic bisphosphine ligand (3b-3e) as a function of force applied to the biaryl backbone of these ligands through intramolecular tension generated by a molecular force probe.
References
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Journal ArticleDOI
Palladium-catalyzed cross-coupling reactions of organoboron compounds
Norio Miyaura,Akira Suzuki +1 more
TL;DR: In this paper, a cross-coupling reaction is proposed for coupling 1 -Alkenylboron Derivatives: Synthesis of Conjugated Dienes 6.
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Magnetic nanoparticles: Synthesis, protection, functionalization, and application
TL;DR: This review focuses on the synthesis, protection, functionalization, and application of magnetic nanoparticles, as well as the magnetic properties of nanostructured systems.
Journal ArticleDOI
Palladium(II)-catalyzed C-H activation/C-C cross-coupling reactions: versatility and practicality.
TL;DR: A review of palladium-catalyzed coupling of CH bonds with organometallic reagents through a PdII/Pd0 catalytic cycle can be found in this paper.
Journal ArticleDOI
A new stereospecific cross-coupling by the palladium-catalyzed reaction of 1-alkenylboranes with 1-alkenyl or 1-alkynyl halides
TL;DR: In this article, the representative (E)-1-alkenyldisiamylboranes and 1-alkenyl-1,3,2-benzodioxaboroles readily obtainable via hydroboration of 1 -alkynes react with (1) halides or (1)-alkynyl halides in the presence of a catalytic amount of tetrakis(triphenylphosphine)palladium and base to give corresponding conjugated (E-dienes or (E-)enynes with high regio-and
Journal ArticleDOI
Magnetic nanoparticles: design and characterization, toxicity and biocompatibility, pharmaceutical and biomedical applications.
TL;DR: Biocompatibility, Pharmaceutical and Biomedical Applications L. Harivardhan Reddy,‡ Jose ́ L. Arias, Julien Nicolas,† and Patrick Couvreur*,†.
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The B‐Alkyl Suzuki—Miyaura Cross‐Coupling Reaction: Development, Mechanistic Study, and Applications in Natural Product Synthesis
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