Journal ArticleDOI
The Role of Oxygen during Thermal Reduction of Graphene Oxide Studied by Infrared Absorption Spectroscopy
Muge Acik,Geunsik Lee,Cecilia Mattevi,Adam Pirkle,Robert M. Wallace,Manish Chhowalla,Kyeongjae Cho,Yves J. Chabal +7 more
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TLDR
In this article, the role of trapped water and the evolution of oxygen during annealing of reduced graphene oxide (GO) is investigated, and the interactions between randomly arranged nearby oxygen species are found to affect the spectral response (red and blue shifts) and the overall chemistry during the reduction process.Abstract:
Understanding the thermal reduction of graphene oxide (GO) is important for graphene exfoliation, and chemical and morphological modifications. In this process, the role of trapped water and the evolution of oxygen during annealing are still not well-understood. To unravel the complex mechanisms leading to the removal of oxygen in reduced GO, we have performed in situ transmission infrared absorption spectroscopy measurements of GO films upon thermal annealing at 60–850 °C in vacuum (10–3–10–4 Torr). Using cluster-based first-principles calculations, epoxides, ethers (pyrans and furans), hydroxyls, carboxyls, lactols, and various types of ketones and their possible derivatives have been identified from the spectroscopic data. Furthermore, the interactions between randomly arranged nearby oxygen species are found to affect the spectral response (red and blue shifts) and the overall chemistry during annealing. For instance, the initial composition of oxygen species (relative amounts and types of species, su...read more
Citations
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Graphene oxide: preparation, functionalization, and electrochemical applications.
Da Chen,Hongbin Feng,Jinghong Li +2 more
Journal ArticleDOI
Adsorption of divalent metal ions from aqueous solutions using graphene oxide
Rafal Sitko,Edyta Turek,Beata Zawisza,Ewa Malicka,Ewa Talik,J. Heimann,Anna Gagor,Barbara Feist,Roman Wrzalik +8 more
TL;DR: Potential application of GO in analytical chemistry as a solid sorbent for preconcentration of trace elements and in heavy metal ion pollution cleanup results from its maximum adsorption capacities that are much higher than those of any of the currently reported sorbents.
Journal ArticleDOI
Harnessing the chemistry of graphene oxide
TL;DR: An overview of some of the most recent and significant developments in the field of graphene oxide, and an outlook of potential areas where GO, its derivatives, and related materials may be expected to find utility or opportunity for further growth and study.
Journal ArticleDOI
Efficient hydrogen peroxide generation using reduced graphene oxide-based oxygen reduction electrocatalysts
Hyo Won Kim,Hyo Won Kim,Michael B. Ross,Nikolay Kornienko,Liang Zhang,Jinghua Guo,Jinghua Guo,Peidong Yang,Peidong Yang,Bryan D. McCloskey,Bryan D. McCloskey +10 more
TL;DR: In this paper, a mild thermal reduction of graphene oxide was used to form hydrogen peroxide from oxygen, achieving state-of-the-art performance at low overpotentials.
Journal ArticleDOI
Carbocatalysis by Graphene-Based Materials
Sergio Navalon,Amarajothi Dhakshinamoorthy,Mercedes Alvaro,Hermenegildo García,Hermenegildo García +4 more
TL;DR: This paper aims to demonstrate the efforts towards in-situ applicability of EMMARM, as to provide real-time information about concrete mechanical properties such as E-modulus, compressive strength, and other properties related to E-commerce.
References
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Projector augmented-wave method
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Efficiency of ab-initio total energy calculations for metals and semiconductors using a plane-wave basis set
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TL;DR: A detailed description and comparison of algorithms for performing ab-initio quantum-mechanical calculations using pseudopotentials and a plane-wave basis set is presented in this article. But this is not a comparison of our algorithm with the one presented in this paper.
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Processable aqueous dispersions of graphene nanosheets
TL;DR: It is reported that chemically converted graphene sheets obtained from graphite can readily form stable aqueous colloids through electrostatic stabilization, making it possible to process graphene materials using low-cost solution processing techniques, opening up enormous opportunities to use this unique carbon nanostructure for many technological applications.
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Chemically Derived, Ultrasmooth Graphene Nanoribbon Semiconductors
TL;DR: A chemical route to produce graphene nanoribbons with width below 10 nanometers was developed, as well as single ribbons with varying widths along their lengths or containing lattice-defined graphene junctions for potential molecular electronics.