Showing papers on "Phenocryst published in 1996"

Solidification fronts and magmatic evolution

Abstract: From G. F. Becker's and L. V. Pirsson's early enunciations linking the dynamics of magma chambers to the rock records of sills and plutons to this day, two features stand at the centre of nearly every magmatic process: solidification fronts and phenocrysts. The structure and behaviour of the envisioned solidification front, however, has been mostly that akin to non-silicate, non-multiply-saturated systems, which has led to confusion in appreciating its role in magmatic evolution. The common habit of intruding magmas to carry significant amounts of phenocrysts, which can lead to efficient fractionation, layering, and interstitial melt flow within extensive mush piles, when coupled with solidification fronts, allows a broad understanding of the processes leading to the rock records of sills and lava lakes. These same processes are fundamental to understanding all magmas. The spatial manifestation of the liquidus and solidus is the Solidification Front (SF); all magmas, stationary or in transit, are encased by SFs. In the ideal case of an initially crystal-free, cooling magma, crystallinity increases from nucleation on the leading liquidus edge to a holocrystalline rock at the trailing solidus. The package of SF isotherms advances inward, thickening with time and, depending on location — roof, floor, or walls — and the initial crystallinity of the magma, is instrumental in controlling magmatic evolution. Bimodal volcanism as well as much of the structure of the oceanic crust may arise from the behaviour of SFs. In mafic magmas, somewhere near a crystallinity (N) of 55% (vol), depending on the phase assemblage, the SF changes from a viscous fluid (suspension (0

Possible contribution of a metal-rich magmatic fluid to a sea-floor hydrothermal system

Abstract: THE source of the hydrothermal fluids vented in active volcanic areas on the sea floor1–3 has been a matter of some debate4–7; they may arise purely from the interaction of circulating sea water with the hot rocks through which it passes1,3,8, or there may be an admixture of a fluid escaping from magma at depth, as is seen in subaerial geothermal systems9 The answer to this question also bears on the origin of the sulphide ores deposited by sea-floor hydrothermal systems, and their ancient analogues8,10,11 preserved on land Here we present direct evidence for the presence of magmatic fluid in the lavas that host an actively forming massive sulphide deposit in the eastern Manus back-arc basin We find high concentrations of chlorides and sulphides of ore-forming metals such as copper, zinc and iron in CO2-rich gaseous bubbles found both in melt inclusions trapped in the phenocrysts of the volcanic rocks, and in the matrix glass We conclude that a metal-rich fluid was present in the magma before eruption, and probably exsolved as the pressure decreased This finding suggests the possibility for the contribution of large quantities of ore-forming metals to a sea-floor hydrothermal system

Quaternary minettes and associated volcanic rocks of Mascota, western Mexico: a consequence of plate extension above a subduction modified mantle wedge

Abstract: Pleistocene-Holocene volcanism in the Jalisco block of western Mexico is confined to two conspicuous grabens, where potassic eruptives range from absarokites (48–52% SiO2) and minettes (49–54% SiO2) through basaltic andesites (53–57% SiO2), the most voluminous type, to andesites and their lamprophyric equivalent spessartite (58–62% SiO2); there are no contemporary rhyolitic rocks. This suite has high concentrations of Mg, Cr (<550 ppm) and Ni (<450 ppm) accompanied by large concentrations of K, P, Ba (<4000 ppm) and Sr (<5000 ppm) and elements such as LREE and Zr (<600 ppm). No combination of crystal fractionation and/or crustal contamination can reproduce the compositional range of these magmas, which nevertheless are believed to be genetically related because of their proximity in time and space. Hydrous minerals in the lamprophyres and the typical absence of plagioclase phenocrysts in both basaltic andesites and andesites reflect the relatively high concentrations of water in the magmas, which suppressed the crystallisation of feldspar. Experimental verification of the minimal amounts of water required to reproduce the phenocryst assemblages in selected rocks range from 3.5 to 6%. During ascent in a volcanic conduit, andesitic magma may lose water and consequently precipitate plagioclase, or it may ascend more rapidly, retaining more of its initial water, which stabilises phenocrysts of hornblende at the expense of plagioclase. Our estimates of water concentrations, which are consistent with the various low pressure phenocryst assemblages, will be minimal for the magmas in their source regions, and the process of magmatic dewatering on ascent may be typical in well established volcanic conduits. In accord with the compositions of phenocrystic olivine in the basaltic andesites and the minettes, the values of FeO and Fe2O3 of the bulk lavas and scoriae are demonstrably pristine. As a consequence, there are two characteristic features of the Mascota suite: the high range of relative oxygen fugacities (ΔNNO=1–5) and the high Mg# (MgO/MgO+FeO) that ranges from 0.70 to 0.91 (with only one andesite as low as 0.66). From the evidence of phlogopite phenocrysts, a partial melt involving phlogopite would have a higher Mg# than one from olivine (Fo90) and pyroxene alone. As the Mascota series shows a correlation between K2O and Mg#, we conclude that it was generated by partial fusion of the mantle wedge, with a variable contribution of phlogopite and apatite from veins throughout the lherzolitic assemblage. In conformity with an origin by varying increments of partial fusion of a phlogopite-bearing mantle, all incompatible elements vary linearly with Ti (or K) as if phlogopite (+apatite) in the source dominated their contribution to the partial melts. Fluids from dehydration of the subducting slab presumably deposit hydrous and other minerals in veins in the mantle wedge and also increase its redox state. As the Mascota volcanism occurs in grabens closer to the trench than the main andesite arc, it is concluded that the eruption of these small volumes of hydrous magmas require the tectonically favored ascent paths offered by the extensional grabens to reach the surface from their mantle sources.

Petrography and olivine and glass chemistry of lavas from the Hawaii Scientific Drilling Project

Abstract: Many of the lavas from the Hawaii Scientific Drilling Project (HSDP) are olivine-rich (>10 vol %) and weakly alteredJ The Maun. fi Loa lavas from the upper part of the HSDP hole are more olivine-rich and generally have oliviaes with higher forsterite contents than the underlying Mauna Kea lavas. Olivine-rich lavas from these volcanoes contain both euhedral, undeformed phenocrysts and kink-banded xenocrysts of olivines, unlike wha(was assumed for typical subaerial Hawaiian tholeiites. The forsterite content of both types of 01ivine ranges widely (80- 90%). Many of the HSDP lavas have olivines with forsterite Contents of ,89-90%, indicating that they grew in magmas with at least 15 wt % MgO. Most of these lavas contain even higher MgO contents (18 to 28 wt %), which are a result of accumulation of olivine phenocrysts and xenocrysts. The olivine xenocrysts in these lavas are inferred to be derived from disaggregation of deformed dunite cumulates, which are present in many of these lavas. Glasses from pahoehoe crusts on some of the HSDP flows have major element compositions that confinn the subdivision of the core based on whole rock compositions. The moderately evolved compositions of the HSDP glasses indicate quenching temperatures similar to those measured during the current Kilauea eruption.

Flow mechanism and viscosity in basaltic magma chambers

Abstract: Magmatic flow in the dense suspension of crystallizing gabbros below the free surface of basaltic magma chambers is considered from the point of view of flow mechanisms and rheology. Hyperdense suspensions (∼20% melt fraction) may arise if flat plagioclase crystals develop a strong preferred orientation induced by magmatic flow. With the help of Nomarski differential interference contrast and back scattered electron figures, we show that suspension flow is possible even for smaller melt fractions if impingements between moving crystals are reduced by chemical dissolution at their contact points. This dissolution process is rate controlling. With strain rates near 10−9 s−1 and viscosities near 1014–16 Pa.s, such crystalline mushes should be closer to plastically deforming solids than to the overlying basaltic suspension. If we characterize magma chambers by suspension flow, no matter how small the melt fraction, magma chambers below oceanic fast spreading centers should not be restricted to a perched melt lens, but should extend to the Moho and comprise the entire volume of observed strong seismic attenuation.

The Kula Volcanic Field, western Turkey: the development of a Holocene alkali basalt province and the adjacent normal-faulting graben

Abstract: The Kula province of Western Turkey provides an excellent example of an alkali basalt province in an area of active rifting. This paper establishes the relationship between the generation of the basalts and the extension of the region. The wide, shallow, terrestrial basin, formed by early extension, was subsequently cut through by narrow, fault-bounded grabens. The genesis of alkali basalt magmas began soon after the concentration of the extension into two grabens ˜2 Ma. The basalts, in the form of some 80 small cinder cones and associated lava flows and fields, have a total volume of 2.3 km3. This small volume reflects the small amount of extension in the region (β < 1.2 where β = final length of crust: initial length of crust).The intercalation of sediments and basalts in the Kula area enables the establishment of a relationship between the extensional activity and the generation of the basalts. This is demonstrable using radiometric and stratigraphic techniques, notably Ar-Ar dating of amphibole phenocrysts.

Residual-liquid origin for a monzonitic intrusion in a mid-Proterozoic anorthosite complex: The Sybille intrusion, Laramie anorthosite complex, Wyoming

Abstract: The Sybille intrusion (≈100 km 2) is one of three large monzonitic intrusions in the 1.43 Ga Laramie anorthosite complex of southeastern Wyoming. The petrographic, geochemical, isotopic, and geophysical characteristics of Sybille monzonitic rocks are consistent with an origin by extensive crystallization of liquids residual to nearby anorthositic cumulates (ferrodiorites) and contamination by Archean wall rocks. The exposed part of the intrusion is composed mainly of coarse-grained monzosyenites with abundant alkali feldspar phenocrysts. The monzosyenites preserve mineralogical evidence for high crystallization temperatures (>1000 °C), mid-crustal emplacement pressures (≈3 kbar), relatively reduced crystallization conditions (2 log units below the fayalite + magnetite + quartz [FMQ] oxygen buffer), and they crystallized in the presence of a CO2-rich fluid phase (Fuhrman et al., 1988; Frost and Touret, 1989). The eastern monzosyenites, those adjacent to contemporaneous anorthosite, are distinguished by an anhydrous mineral assemblage (Fo16-Fo8 olivine, high-Ca pyroxene) lacking modal quartz, silica contents of 60 wt%, and smaller Eu anomalies (Eu/Eu* = 1.2 to 1.3). Abundant xenoliths of Archean wall rocks and anorthosite from the adjacent intrusions in all monzosyenites attest to a stoping emplacement mechanism near the roof of the chamber. We propose that the monzosyenites represent a relatively thin, 0.5-1.0-km-thick, roof to a magma chamber dominated by dense ferrodioritic cumulates at depth. Extensive, open-system fractionation of a ferrodioritic parent magma, residual after crystallization of anorthosite, produced Fe-enriched monzodioritic and/or monzonitic magma in the upper part of the chamber and complementary Fe- and Ti-rich cumulates in the lower levels. We have corroborated the production of monzonitic liquids from crystallization of ferrodiorite through a series of reconnaissance equilibrium-crystallization experiments. The presence of dense ferrodioritic cumulates at depth is consistent with the prominent positive gravity anomaly associated with the Sybille intrusion (Hodge et al., 1973). In the upper parts of the chamber, the fractionated monzodioritic and/or monzonitic magmas eventually became saturated in alkali feldspar. Owing to density contrasts, the alkali feldspar phenocrysts floated to the roof of the chamber, thus producing the exposed porphyritic monzosyenites. In addition, the roof of the chamber was the site of significant melting of Archean gneiss and, locally, metapelite. The Sr and Nd isotopic compositions of the monzosyenites, with Sr isotopic ratios becoming increasingly radiogenic from east ( I Sr = 0.7059 and initial ϵNd = −2.5) to west ( I Sr = 0.7092 and initial ϵNd = −2.6), are consistent with a 5% to 15% addition of Archean orthogneiss to a ferrodioritic parent magma that had isotopic characteristics similar to adjacent anorthositic rocks. The stratigraphic and compositional similarity of the Sybille monzosyenites to mangerites in the Bjerkreim-Sokndal intrusion of the Rogaland anorthosite complex, southern Norway, indicates that similar open-system magmatic processes are capable of having produced high-temperature, K-rich monzonitic rocks in other Proterozoic anorthosite complexes.

Magma evolution recorded in plagioclase zoning in 1991 Pinatubo eruption products

Abstract: Plagioclase, the most abundant phenocryst at Mount Pinatubo, displays varying textures and compositions within the 1991 eruption products. In June 7-14 dome-forming andesite, plagioclase phenocrysts show prominent rims with higher MgO (0.04-0.06 wt°jo), Fe20j (0.6-0.8 wt°/o), and K20 at given An than the interiors. The compositions of the rims are identical to those of microlites, which are abundant in the groundmass glass. White dacitic pumice, the most voluminous product of the June 15 eruption, contains partly corroded plagioclase phenocrysts but no prominent rims and no microlites. The interiors of phenocrysts from the dacitic pumice and the dome-forming andesite are remarkably similar in terms of textures and compositions. They show oscillatory zoning (mostly An35-6o),low MgO «0.02 wtOjo) and Fe20j (0.10-0.30 wt°jo), and similar K20 at given An. This similarity indicates that the two types of plagioclase phenocrysts formed in the same rhyolitic melt. The oscillatory zoning likely formed by temperature fluctuations in the convecting magma and incorporation and degassing of external fluids. A portion of the felsic magma ("-800°C) mixed with a mafic melt ("-1000-1100 °C) to become an andesitic magma that extruded to form the June 7-14 dome. All plagioclase phenocrysts in the andesite were derived from the felsic magma. The mixing caused destabilization of phenocrysts, forming sieve textures, dusty zones, and partial resorption. Extrusion of the mixed magma resulted in overgrowths on once-resorbed phenocrysts and the nucleation of plagioclase microlites in the groundmass glass. In the unmixed, remaining portion of the felsic magma, some plagioclase underwent partial resorption but did not develop overgrowths. This lack of overgrowths and the absence of micro lites in the groundmass glass of the June 15 dacitic pumice indicate rapid magma ascent during the eruption and a short time span between the injection of a mafic melt and the cataclysmic eruption, supporting the linkage between the two.

Petrology and sulfur and chlorine emissions of the 1963 eruption of Gunung Agung, Bali, Indonesia

Abstract: The 1963 eruption of Gunung Agung produced 0.95 km3 dense rock equivalent (DRE) of olivine±hornblende-bearing, weakly phyric, basaltic andesite tephra and lava. Evidence for magma mixing in the eruptive products includes whole-rock compatible and incompatible trace element trends, reverse and complex compositional zoning of mineral phases, disequilibrium mineral assemblages, sieve-textured plagioclase phenocrysts, and augite rims on reversely zoned orthopyroxene. Basalt magma mixed with pre-existing andesite magma shortly before eruption to yield basaltic andesite with a temperature of 1040–1100 °C at an assumed pressure of 2 kb, f O2>NNO, and an average melt volatile content (H2O±CO2) of 4.3 wt.%. Magma-mixing end members may have provided some of the S and Cl emitted in the eruption. Glass inclusions in phenocrysts contain an average of 650 ppm S and 3130 ppm Cl as compared with 70 ppm and 2220 ppm, respectively, in the matrix glass. Maximum S and Cl contents of glass inclusions approach 1800 and 5000 ppm, respectively. Application of the petrologic method to products of the 1963 eruption for estimating volatile release yields of 2.5×1012 g (Mt) of SO2 and 3.4 Mt of Cl released from the 0.65 km3 of juvenile tephra which contributed to stratospheric injection of H2SO4 aerosols on 17 March and 16 May, when eruption column heights exceeded 20 km above sea level. An independent estimate of SO2 release from atmospheric aerosol loading (11–12 Mt) suggests that approximately 7 Mt of SO2 was injected into the stratosphere. The difference between the two estimates can be most readily accounted for by the partitioning of S, as well as some Cl, from the magma into a water-rich vapor phase which was released upon eruption. For other recent high-S-release eruptions of more evolved and oxidized magmas (El Chichon, Pinatubo), the petrologic method gives values two orders of magnitude less than independent estimates of SO2 emissions. Results from this study of the Agung 1963 magma and its volatile emissions, and from related studies on eruptions of more mafic magmas, suggest that SO2 emissions from eruptions of higher-S-solubility magma may be more reliably estimated by the petrologic method than may those from more-evolved magma eruptions.

Petrology of a 2.41 Ga remarkably fresh komatiitic basalt lava lake in Lion Hills, central Vetreny Belt, Baltic Shield

Abstract: In the central Vetreny Belt, southeastern Baltic Shield, an areally extensive 110 m deep lava lake is exposed consisting of remarkably fresh differentiated komatiitic basalt. During eruption, the liquid had a temperature of 1380–1400 °C and contained ∼15% MgO. The lava ponded in a large topographic depression soon after eruption. The differentiation of the lava lake was controlled by settling of transported olivine and chromite phenocrysts and caused the origin of prominent internal layering. The last portions of the trapped liquid crystallized at temperatures of 1250– 1070 °C. A Sm-Nd isochron of 2410±34 Ma for whole rock samples, olivine, augite and pigeonite separates from the lava lake provides a reliable estimate for the time of formation of the uppermost sequences in the Vetreny Belt. This age is in good agreement with the Sm-Nd and Pb-Pb isochron ages of 2449±35 and 2424±178 Ma for the volcanic rocks from the same stratigraphic level in the northwestern Vetreny Belt. Modeling of Nd-isotopes and major and trace elements shows that the komatiitic basalts at Lion Hills may have had a komatiite parent depleted in highly incompatible elements. It can be shown that this initial liquid was contaminated by 7–9% of Archaean upper crustal material from the adjacent Vodla and Belomorian Blocks en route to the surface thus acquiring the observed geochemical and isotope signatures including relative enrichment in Zr, Ba, and LREE, negative Nb- and Ti-anomalies and ɛNd(T) of −1.

Trace Element and Isotope Geochemistry of the Volcanic Rocks of Bequia, Grenadine Islands, Lesser Antilles Arc: a Study of Subduction Enrichment and Intra-crustal Contamination

Abstract: (~5-5 in clinopyroxene). The isotopically diverse suite (IDS) is characterized by much wider ranges of radiogenic isotopes ,87Sr/86Sr Q-7048-0-7077, Nd/Nd 0-5128-0-5123 and ho6pb/2O4pb 19.7-20-2), in which all of the Sr and Pb ratios are higher and Nd ratios are lower than those of the IHS. The IDS is also characterized by high d0 values, up to 7-6 in clinopyroxene. The Sr and Pb isotope ratios are too high, and the Nd isotope ratios are too low in the IDS for any of these lavas to be derived from unmodified depleted mantle. Both suites are petrologically very similar and their major element compositions and phenocryst contents suggest that they were formed largely by fractional crystallization of a hydrous tholeiitic melt at pressures <3 kbar. The isotopic ratios and enrichments in large ion lithophile elements (LILE), and to some extent light rare earth elements (LREE), as compared with mid-ocean ridge basalts (MORB), of the IHS lavas suggest that they were derived from a depleted mantle source which had been re-enriched by the addition of1-4% of a subduction component. This component probably comprised a mixture of dehydration fluids, and perhaps minor siliceous melts, released from subducting sediments and mafic crust. The extreme isotopic ranges, large enrichments in incompatible elements, more fractionated LREE patterns and higher 5O values of the IDS lavas are interpreted as resulting from ~ 10-55% assimilation—fractional crystallization of sediments, derived from the Guyana Shield, which are present in the arc crust, by IHS type melts.

Crystal size distributions and other quantitative textural measurements in lavas and tuff from Egmont volcano (Mt. Taranaki), New Zealand

Abstract: The size, shape and orientation of plagioclase crystals have been quantified in a tuff and series of andesite lavas from the active Egmont volcano (Mt. Taranaki), New Zealand. Linear crystal size distributions (CSDs) show that if the magma had several components, then only one provided the crystals. The slope of the CSD indicates that the earliest lavas measured had a residence time of ∼50 years in the magma chamber for a growth rate of 10–11cm/s. Subsequent lavas had slightly longer residence times (50–75 years), but the following series returned to 50-year residence times. The youngest magmas, from both Egmont summit and the parasitic Fantham's Peak, have the shortest residence times of ∼30 years. Variations in residence time may reflect changes in the magma chamber shape or depth, or the temperature of the surrounding rocks. Crystal shapes and zonation suggest that crystallization occurred in a bottle-shape magma chamber, and not in a narrow conduit. If future eruptions use the same magma chamber as the most recent eruptions, then a delay of approximately 30 years can be expected between refilling and eruption.

The Mt. Vulture volcanic complex (Italy): evidence for distinct parental magmas and for residual melts with melilite

Abstract: New data of mineral compositions, whole-rock major and trace element contents are presented for lava flows and dykes of Mt. Vulture volcano (southeastern Roman Magmatic Province). The dominant rock series ranges from basanite, through tephrite and foidite, to phonolite. Diopsidic to Fe-salitic (hedenbergitic) clinopyroxene is the major phenocryst phase, and shows a very strong Ti- and Al-enrichment trend (up to 5 wt% TiO2 and 12 wt% Al2O3). Phonolites have Fe-rich pyroxenes low in Ti and Al, as a consequence of fractionation of Ti-magnetite and/or melanite garnet. Feldspar ranges in composition from bytownite to Ba- and Sr-rich anorthoclase (up to 7 wt % BaO and 4 wt % SrO); the latter is present in the groundmass of mafic and intermediate rocks. Phonolites are characterized by anorthoclase and sanidine with Ba-rich cores, and with Ba-depleted rims. Subordinate melilite-bearing rocks are also present, and are characterized by melilite with a very large compositional variation, Ca-rich nepheline (up to 8 wt% CaO) and lack of feldspar and amphibole. Some of them also show calcite-rich ocellar structures, possibly due to liquid immiscibility. They have also major and trace element contents different from those of the feldspar-bearing rocks. This all indicates distinct parental magmas for feldspar-bearing and melilite-bearing rocks. These latter were likely generated by differentiation processes starting from olivine- and melilite-bearing ultramafic parental magmas. Mineral compositions and suitable phase diagrams indicate that the Melfi hauynophyre, which is the most MgO-poor melilite-bearing rock of Mt. Vulture, is close to a residual melt analogous to phonolite, but in petrogenetic systems with melilite and without feldspar. The high- to very high-titanium content of most of the ferromagnesian phases, despite a relatively low TiO2 of primitive Mt. Vulture rocks, is absent in other rocks of similar degree of evolution in the Roman Province. It resembles that found in anorogenic magmas and gives further indications for a within-plate signature in this particular volcanic complex.

Petrography and petrology of the Hawaii Scientific Drilling Project lavas: Inferences from olivine phenocryst abundances and compositions

Abstract: The Mauna Loa (ML) and Mauna Kea (MK) lavas recovered by the Hawaii Scientific Drilling Project (HSDP) include aphyric to highly olivine-phyric basalts. The average olivine phenocryst abundance in the reference suite of ML flows is 14.5 vol % (vesicle-free and weighted by the flow thickness), while the average abundances of olivine in the reference suites of the MK alkalic and tholeiitic basalts are 1.1 and 14.0 vol %, respectively. Plagioclase and augite phenocrysts are rare in the ML and MK tholeiites, but the MK alkalic basalts can have up to 4 vol % plagioclase phenocrysts. Strained olivine grains, thought to represent disaggregated dunite xenoliths from the cumulate pile within the magma chamber(s), are ubiquitous in the drill core lavas. These deformed grains can comprise up to 50 % of the modal olivine in a given rock. Olivine core compositions in the lavas span forsterite contents of 80.4–90.7 (median 88.8, ML tholeiites), 75.8–86.6 (median 85.8, MK alkalic basalts), and 76.3–90.5 (median 88.0 mol %, MK tholeiites). Olivines with core compositions in the range Fo_(89–90.5) are present in tholeiitic lavas with a wide range of whole-rock MgO contents (9–30 wt %). Strained and unstrained olivines completely overlap in composition as do the compositions of spinels (100*Cr/(Cr+Al) ∼59–72; Mg# = 100*Mg/(Mg+Fe^(2+)) ∼40–66) present as inclusions in the olivine phenocrysts. The presence of Fo_(90.5) olivine in the HSDP lavas requires magmas with ∼16 wt % MgO in the ML and MK plumbing systems. Rare dunite xenoliths are also present in the drill core lavas. While compositionally homogeneous within a given xenolith, the six xenoliths contain olivines that span a wide range of forsterite contents (78.3–89.2 mol %). Spinels in these xenoliths are chrome-rich, have Mg# between 31 and 66, and define two populations on the basis of TiO_2 contents. Whole-rock compositions for the ML and MK tholeiites define olivine control lines on MgO-oxide diagrams, and the relationship between whole-rock MgO and olivine phenocryst abundance in these lavas suggests that the lavas with >12 wt % MgO have accumulated olivine. Comparing the weighted bulk composition of all of the MK tholeiites in the drill core with a calculated parental magma suggests that, on average, the MK tholeiites entrained most of the olivine phenocrysts that crystallized from their parental liquids. Although deformed olivines in Hawaiian lavas are widely thought to represent disaggregated dunite xenoliths, none of the majoror minor-element data on the strained or unstrained olivine phenocrysts suggest that the strained olivines in the HSDP lavas are exotic. We suggest that most of the olivine phenocrysts in a given flow, whether strained or unstrained, are closely related to the evolved liquid that now forms the groundmass. This is consistent with observed correlations between isotopic systems measured on olivine separates (e.g., O, He) and isotopic systems dominated by groundmass (e.g., Nd, Pb).

Crystallization of the Shap Granite: evidence from zoned K-feldspar megacrysts

Abstract: Textural, chemical and Sr isotopic studies of feldspars from the subsolvus Shap granite, northern England, demonstrate that a number of magma mixing events have dominated the evolution of this pluton. K-feldspar megacrysts are phenocrysts formed in the magma chamber. They contain a number of Ba-rich zones that developed during periods of slight dissolution and regrowth linked to the hybridization of the granite by the intrusion of basic magmas. Diorite enclaves represent the relicts of these magmas and these also contain K-feldspar megacrysts, which show evidence of major dissolution. They are xenocrysts picked up from the host granite and incorporated in the basic magma. Increasing H 2 O contents during fractional crystallization caused a late switch from growth of megacrysts to finer-grained K-feldspars in the matrix. The chemically and isotopically zoned K-feldspar megacrysts preserve an exceptional record of the evolution of the magma, and the zones also had a significant influence on the development of exsolution microtextures during cooling.

Exsolved magmatic fluid and its role in the formation of comb-layered quartz at the Cretaceous Logtung W-Mo deposit, Yukon Territory, Canada

Abstract: Comb-layered quartz is a type of unidirectional solidification texture found at the roofs of shallow silicic intrusions that are often associated spatially with Mo and W mineralisation. The texture consists of multiple layers of euhedral, prismatic quartz crystals (Type I) that have grown on subplanar aplite substrates. The layers are separated by porphyritic aplite containing equant phenocrysts of quartz (Type II), which resemble quartz typical of volcanic rocks and porphyry intrusions. At Logtung, Type I quartz within comb layers is zoned with respect to a number of trace elements, including Al and K. Concentrations of these elements as well as Mn, Ti, Ge, Rb and H are anomalous and much higher than found in Type II quartz from Logtung or in igneous quartz reported elsewhere. The two populations appear to have formed under different conditions. The Type II quartz phenocrysts almost certainly grew from a high-silica melt between 600 and 800°C (as β-quartz); in contrast, the morphology of Type I quartz is consistent with precipitation from a hydrothermal solution, possibly as α-quartz grown below 600°C. The bulk compositions of comb-layered rocks, as well as the aplite interlayers, are consistent with the hypothesis that these textures did not precipitate solely from a crystallising silicate melt. Instead, Type I quartz may have grown from pockets of exsolved magmatic fluid located between the magma and its crystallised border. The Type II quartz represents pre-existing phenocrysts in the underlying magma; this magma was quenched to aplite during fracturing/degassing events. Renewed and repeated formation and disruption of the pockets of exsolved aqueous fluid accounts for the rhythmic banding of the rocks.

Plagioclase zonation styles in hornblende gabbro inclusions from Little Glass Mountain, Medicine Lake volcano, California: implications for fractionation mechanisms and the formation of composition gaps

Abstract: The rhyolite of Little Glass Mountain (73–74% SiO2) is a single eruptive unit that contains inclusions of quenched andesite liquid (54–61% SiO2) and partially crystalline cumulate hornblende gabbro (53–55% SiO2). Based on previous studies, the quenched andesite inclusions and host rhyolite lava are related to one another through fractional crystallization and represent an example of a fractionation-generated composition gap. The hornblende gabbros represent the cumulate residue associated with the rhyolite-producing and composition gap-forming fractionation event. This study combines textural (Nomarski Differential Interference Contrast, NDIC, imaging), major element (An content) and trace element (Mg, Fe, Sr, K, Ti, Ba) data on the style of zonation of plagioclase crystals from representative andesite and gabbro inclusions, to assess the physical environment in which the fractionation event and composition gap formation took place. The andesite inclusions (54–61% SiO2) are sparsely phyric with phenocrysts of plagioclase, augite and Fe-oxide±olivine, +/–orthopyroxene, +/–hornblende set within a glassy to crystalline matrix. The gabbro cumulates (53–55% SiO2) consist of an interconnected framework of plagioclase, augite, olivine, orthopyroxene, hornblende and Fe-oxide along with highly vesicular interstitial glass (70–74% SiO2). The gabbros record a two-stage crystallization history of plagioclase+olivine+augite (Stage I) followed by plagioclase+orthopyroxene+ hornblende+Fe-oxide (Stage II). Texturally, the plagioclase crystals in the andesite inclusions are characterized by complex, fine-scale oscillatory zonation and abundant dissolution surfaces. Compositionally (An content) the crystals are essentially unzoned from core-to-rim. These features indicate growth within a dynamic (convecting?), reservoir of andesite magma. In contrast, the plagioclase crystals in the gabbros are texturally smooth and featureless with strong normal zonation from An74 at the core to around An30. K, and Ba abundances increase and Mg abundances decrease steadily towards the rim. Ti, Fe, and Sr abundances increase and then decrease towards the rim. The trace element variations are fully consistent with the two-stage crystallization sequence inferred from the gabbro mineralogy. These results indicate progressive closed-system in situ crystallization in a quiescent magmatic boundary layer environment located along the margins of the andesite magma body. The fractional crystallization that generated the host rhyolite lava is one of inward solidification of a crystallizing boundary layer followed by melt extraction and accumulation of highly evolved interstitial liquid. This mechanism explains the formation of the composition gap between parental andesite and rhyolite magma compositions.

Gas saturation and evolution of volatile and light lithophile elements in the Bandelier magma chamber between two caldera‐forming eruptions

Abstract: We have studied the distribution of light and volatile elements (Li, Be, B, H2O, F, Cl) in matrix glasses and melt inclusions in quartz and sanidine phenocrysts from tephras of the Cerro Toledo Rhyolite, which were erupted from the Bandelier magma chamber between two caldera-forming eruptions at 1.608 Ma and 1.225 Ma. Since the small-volume tephras of the Cerro Toledo Rhyolite record chemical evolution of the upper parts of the magma chamber during this 383-kyr period, we can track volatile evolution in the magma during its differentiation, specifically, the development of a separate fluid phase from the magma, the partitioning of volatile and light elements between this fluid and the magma, and the timing of the second caldera eruption at 1.225 Ma. The melt inclusion data reveal that Li, Be, and B were progressively enriched with time at the top of the magma chamber, showing a similar three fold enrichment. By contrast, F, Cl, and F2O show more variable behavior. F was enriched 3.6 times in the magma and Cl increased 2.5 times, while water concentrations remained constant. Evidence for a separate fluid phase includes (1) comparatively small magmatic enrichment factors for Cl and H2O, elements which are known to partition into fluid, (2) decline of the Cl/Be and Cl/B ratios in melt inclusions with time, indicating preferential loss of Cl, and (3) maximum Cl contents of 2900–3000 ppm in melt inclusions, which are concentrations at or close to the saturation limit for Cl in a two-phase gas-saturated magma. The lack of temporal H2O enrichment in the magma suggests that it became gas saturated at an early stage. The Cl fluid-magma partition coefficient was initially low, due to the presence of a low-salinity single-phase vapor. The fluid is calculated to have increased its salinity from 0.76 wt % equivalent NaCl to 3.1 wt % NaCl by crystallization and Cl enrichment in the magma. Consequently, the fluid was transformed to two immiscible phases. As a result, the Cl partition coefficient increased, and the Cl content in the magma was buffered at 2900–3000 ppm. Overpressures in the magma chamber have been modeled as a function of crystallization, total pressure and depth, H2O solubility in rhyolite, resurgence, crystallization contraction, and initial fluid mass. For the large amounts of crystallization (40–70%) required by the geochemical relations, unrealistically large overpressures (>75 MPa) are indicated, unless (1) the magma existed as a foam or (2) the chamber was able to degas passively, and thus buffer the buildup of pressure. To maintain realistic overpressures in the magma chamber (<50 MPa), an equilibrium was required between gas buildup by crystallization and volatile loss by passive degassing. The change from a one-phase vapor to a two-phase immiscible fluid before the Upper Bandelier Tuff eruption may have promoted partial or complete sealing of the magmatic-hydrothermal system, permitting significant overpressures to develop. The result could have been a cataclysmic caldera-forming eruption.

Diopside phenocrysts from nephelinite lavas, Napak Volcano, eastern Uganda; evidence for magma mixing

Abstract: Samples of olivine nephelinite from Napakvolcano,eastern Uganda, containtwo populations of clinopyroxenephenocrysts, one chromian and the othertitanium-bearing aluminian diopside. The chromian diopsidecrystalsareamongthe most magnesian to occur in nephelinite. The diopside phenocrysts show normal, reverse and oscillatory zoning, and some have an embayed texture suggestiveof resorption. Disequilibrium in Nd, Pb,andSr isotopicratios forboth populations ofclinopyroxeneand their host rocks is interpreted in terms of crystallization in an open system. Populations of chromian and Ti-bearing aluminian diopside from the same lavas have distinct isotopic ratios, indicativeof derivation and crystallization from different melts. We attribute the zoning, tcxtural features, and bimodality of the Napak diopsides to the mixing of at least two nephclinitic magmas at a shallow crust.il level.

Evolution of parental magmas of Miocene shield basalts of Gran Canaria (Canary Islands): constraints from crystal, melt and fluid inclusions in minerals

Abstract: Picritic units of the Miocene shield volcanics on Gran Canaria, Canary Islands, contain olivine and clinopyroxene phenocrysts with abundant primary melt, crystal and fluid inclusions. Composition and crystallization conditions of primary magmas in equilibrium with olivine Fo90-92 were inferred from high-temperature microthermometric quench experiments, low-temperature microthermometry of fluid inclusions and simulation of the reverse path of olivine fractional crystallization based on major element composition of melt inclusions. Primary magmas parental for the Miocene shield basalts range from transitional to alkaline picrites (14.7–19.3 wt% MgO, 43.2–45.7 wt% SiO2). Crystallization of these primary magmas is believed to have occurred over the temperature range 1490–1150° C at pressures ≈5 kbar producing olivine of Fo80.6-90.2, high-Ti chrome spinel [Mg/ (Mg+Fe2+)=0.32–0.56, Cr/(Cr+Al)=0.50–0.78, 2.52–8.58 wt% TiO2], and clinopyroxene [Mg/(Mg+Fe)=0.79–0.88, Wo44.1-45.3, En43.9-48.0, Fs6.8-11.0] which appeared on the liquidus together with olivine≈Fo86. Redox conditions evolved from intermediate between the QFM and WM buffers to late-stage conditions of NNO+1 to NNO+2. The primary magmas crystallized in the presence of an essentially pure CO2 fluid. The primary magmas originated at pressures >30 kbar and temperatures of 1500–1600° C, assuming equilibrium with mantle peridotite. This implies melting of the mantle source at a depth of ≈100 km within the garnet stability field followed by migration of melts into magma reservoirs located at the boundary between the upper mantle and lower crust. The temperatures and pressures of primary magma generation suggest that the Canarian plume originated in the lower mantle at depth ≈900 km that supports the plume concept of origin of the Canary Islands.