Birla Institute of Technology and Science

About: Birla Institute of Technology and Science is a education organization based out in Pilāni, Rajasthan, India. It is known for research contribution in the topics: Computer science & Population. The organization has 8897 authors who have published 13947 publications receiving 170008 citations.

Hole Transfer Dynamics from a CdSe/CdS Quantum Rod to a Tethered Ferrocene Derivative

Abstract: Hole transfer between a CdSe/CdS core/shell semiconductor nanorod and a surface-ligated alkyl ferrocene is investigated by a combination of ab initio quantum chemistry calculations and electrochemical and time-resolved photoluminescence measurements. The calculated driving force for hole transfer corresponds well with electrochemical measurements of nanorods partially ligated by 6-ferrocenylhexanethiolate. The calculations and the experiments suggest that single step hole transfer from the valence band to ferrocene is in the Marcus inverted region. Additionally, time-resolved photoluminescence data suggest that two-step hole transfer to ferrocene mediated by a deep trap state is unlikely. However, the calculations also suggest that shallow surface states of the CdS shell could play a significant role in mediating hole transfer as long as their energies are close enough to the nanorod highest occupied molecular orbital energy. Regardless of the detailed mechanism of hole transfer, our results suggest that ...

Shoreline shifting and its prediction using remote sensing and GIS techniques: a case study of Sagar Island, West Bengal (India)

Abstract: The shoreline position is difficult to predict but the trend of erosion or accretion can be determined by geospatial and statistical techniques which may help in reducing the loss of property. The study aims to assess the shoreline changes and prediction in Sagar Island, a delta of the Ganges, situated in West Bengal, India. Shorelines have been delineated by using Tasseled Cap Transformation techniques from the Landsat MSS (1975), Landsat TM (1989, 1991) and Landsat ETM+ (1999, 2002, 2005, 2008, and 2011) images. The uncertainty was calculated for every year for assessing the positional error related to shoreline extraction. Total shoreline change rate/year has also been calculated and the uncertainty of total shoreline change rate was found ±3.20 m/year. In the present study, End Point Rate (EPR) and Linear Regression (LR) methods have been used for shoreline change rate calculation and prediction of shoreline. Long term (1975–2002) and short term (2002–2011) erosion and accretion rates were calculated for the study area. Sagar is the biggest island of the Sundarban region; so, it was divided into three segments in order to analyze the change on a segment basis. It was observed that the most of erosion occurred in the Segment B (south Sagar). The rate of erosion was −7.91 and −7.01 m/year for the periods 1975–2002 and 2002–2011 respectively. The mean shoreline change rate was high in Segment B (South Sagar) with values of −6.46 m/year (1975–2002) but the rate was decreased into −5.25 m/year during the later period (2002–2011). The study reveals that most of the southern part of Sagar Island is vulnerable to high rate of shoreline erosion.

Shifting of research trends in islanding detection method - a comprehensive survey

Abstract: The augmentation in electricity demand, power system privatization as well as efficacy of renewable resources has paved the way for power system companies and researchers to exploit the field of grid connected distributed generation (DG) and its issues, islanding being a dominant one. Several research works have been conducted to mitigate the issues of islanding detection (ID). In context of this, the paper gives a comprehensive review of islanding issues, standard test systems, criteria and shifting of research trends in islanding detection methods (IDMs). The significant contributions pertain to categorization of IDMs, evaluation of non-detection zone (NDZ) for each test system, disquisition on evolution and advancement of IDMs and its comparisons based on criteria such as NDZ, run on time, nuisance tripping percentage, applicability in multi DG system and implementation cost to draw out the strength and shortcomings of individual methods that will come to aid to the companies or researchers for establishing the applicability and appropriateness of such method for their concerned domain.

Development Trends in Porous Adsorbents for Carbon Capture

Abstract: Accumulation of greenhouse gases especially CO2 in the atmosphere leading to global warming with undesirable climate changes has been a serious global concern. Major power generation in the world is from coal based power plants. Carbon capture through pre- and post- combustion technologies with various technical options like adsorption, absorption, membrane separations, and chemical looping combustion with and without oxygen uncoupling have received considerable attention of researchers, environmentalists and the stake holders. Carbon capture from flue gases can be achieved with micro and meso porous adsorbents. This review covers carbonaceous (organic and metal organic frameworks) and noncarbonaceous (inorganic) porous adsorbents for CO2 adsorption at different process conditions and pore sizes. Focus is also given to noncarbonaceous micro and meso porous adsorbents in chemical looping combustion involving insitu CO2 capture at high temperature (>400 °C). Adsorption mechanisms, material characteristics, and synthesis methods are discussed. Attention is given to isosteric heats and characterization techniques. The options to enhance the techno-economic viability of carbon capture techniques by integrating with CO2 utilization to produce industrially important chemicals like ammonia and urea are analyzed. From the reader's perspective, for different classes of materials, each section has been summarized in the form of tables or figures to get a quick glance of the developments.