Showing papers by "Paul Scherrer Institute published in 1997"

Electrochemically Active Polymers for Rechargeable Batteries.

Abstract: Electrochemical energy storage systems (batteries) have a tremendous role in technical applications In this review the authors examine the prospects of electroactive polymers in view of the properties required for such batteries Conducting organic polymers are considered here in the light of their rugged chemical environment: organic solvents, acids, and alkalis The goal of the present article is to provide, first of all in tabular form, a survey of electroactive polymers in view of potential applications in rechargeable batteries It reviews the preparative methods and the electrochemical performance of polymers as rechargeable battery electrodes The theoretical values of specific charge of the polymers are comparable to those of metal oxide electrodes, but are not as high as those of most of the metal electrodes normally used in batteries Therefore, it is an advantage in conventional battery designs to use the conducting polymer as a positive electrode material in combination with a negative electrode such as Li, Na, Mg, Zn, MeH{sub x}, etc 504 refs

Reduced glucose metabolism in the frontal cortex and basal ganglia of multiple sclerosis patients with fatigue: a 18F-fluorodeoxyglucose positron emission tomography study.

Abstract: To investigate the pathophysiology of fatigue in MS, we assessed cerebral glucose metabolism (CMR-Glu) in 47 MS patients using PET and 18F-fluorodeoxyglucose. Applying the Fatigue Severity Scale (FSS), we first compared MS patients with severe fatigue (MS-FAT, n = 19, FSS > 4.9) and MS patients without fatigue (MS-NOF, n = 16, FSS < 3.7) on a pixel-by-pixel basis using Statistical Parametric Mapping (SPM95). Second, we compared FSS values of all 47 patients covering the whole range of this scale with CMRGlu using an analysis of covariance (SPM95). In addition, we determined global CMRGlu by region-of-interest analysis. Sixteen healthy subjects served as control subjects (CON). Global CMRGlu was significantly lower in both MS groups compared with CON (CON 43.3 +/- 6.9 mumol/100 mL/min, MS-FAT 34.7 +/- 4.4, MS-NOF 35.4 +/- 4.5) but was not related to fatigue severity. Comparing the two MS groups, SPM95 analysis revealed predominant CMRGlu reductions bilaterally in a prefrontal area involving the lateral and medial prefrontal cortex and adjacent white matter, in the premotor cortex, putamen, and in the right supplementary motor area of MS-FAT. In addition, there were CMRGlu reductions in the white matter extending from the rostral putamen toward the lateral head of the caudate nucleus. FSS values were inversely related to CMRGlu in the right prefrontal cortex. CMRGlu in the cerebellar vermis and anterior cingulate was relatively higher in MS-FAT than in MS-NOF patients. CMRGlu of both regions showed positive correlations with FSS values. Our data suggest that fatigue in MS is associated with frontal cortex and basal ganglia dysfunction that could result from demyelination of the frontal white matter.

Conformational identification of individual adsorbed molecules with the STM

Abstract: The structure and conformation of a molecule determine its chemical and physical properties. Molecular conformation at interfaces is of particular importance in organic thin films1: in organic optoelectronic devices2,3, for example, charge carrier injection is influenced by interfacial properties4. Here we present a real-space conformational analysis of individual porphyrin molecules using scanning tunnelling microscopy5,6. Porphyrins have been used as model systems to study charge transfer7 and in vivo photoactivation of drug precursors8, and have also been used in organic light-emitting diodes9. We find that changes in the porphyrins' conformation occur predominantly by rotations around the bonds to four tertiary butyl appendages, which differ on different metal substrates. On corrugated gold (110) surfaces, we identify two different conformations as the precursory (metastable) and final states of adsorption. This kind of conformational adaptation to a surface may be general for adsorbed organic molecules, and might have important consequences for the technological applications of organic thin films.

Operating Proton Exchange Membrane Fuel Cells Without External Humidification of the Reactant Gases Fundamental Aspects

Abstract: Operation of proton exchange membrane fuel cells (PEMFC) without external humidification of the reactant gases is advantageous for the PEMFC system, because it eliminates the need of a gas-humidification subsystem. The gas-humidification subsystem is a burden in the fuel cell system with respect to weight, complexity, cost, and parasitic power. A model for the operation of PEMFC with internal humidification of the gases is presented and the range of operating conditions for a PEMFC using dry H 2 /air was investigated. The model predicts that dry air, entering at the cathode, can be fully internally humidified by the water produced by the electrochemical reaction at temperatures up to 70°C. This model was experimentally verified for cell temperatures up to 60°C by long-term operation of a PEMFC with dry gases for up to 1800 h. The current densities, obtained at 0.6 V, were 20 to 40% lower than those measured when both gases were humidified. The water distribution in the cell, while operating with dry gases, was investigated by measuring the amount of product water on the anode and cathode sides. It was found that the back-diffusion of product water to the anode is the dominant process for water management in the cell over a wide range of operating conditions. The dominating water back-diffusion also allows internal humidification of the hydrogen reactant and prevents drying out of the anode.

The X-Ray Sun in Time: A Study of the Long-Term Evolution of Coronae of Solar-Type Stars

Abstract: We have used the ASCA and ROSAT X-ray satellites to probe the coronae of a sample of nine solar-like G stars. These stars are all ostensibly single with ages ranging from 70 Myr to 9 Gyr and have X-ray luminosities ranging from 1 to 500 times that of the quiet Sun. Specifically, we investigate the dependence of the coronal temperature and emission measure structure of these stars on age and rotation period. In the younger stars, a considerable portion of the volume emission measure resides at very high temperatures, reaching up to ~20-30 MK in EK Dra. Such temperatures are comparable to temperatures that are achieved on the Sun during short flaring episodes. In two-temperature fits to ROSAT data, the higher temperature decays rapidly within the first few 100 Myr; the decay may be described by an inverse power law, Thot age-0.3. We also find a power-law dependence between the total X-ray luminosity and the higher temperature LX${r X}$ --> T$4{r hot}$ -->. We interpret this as evidence of a decrease in the efficiency of high-temperature coronal heating as a solar-like star ages and its rotation slows down. A reconstruction of the coronal differential emission measure (DEM) distribution in three of the stars using ASCA data indicates a bimodal distribution in temperature, with the hotter plasma at 12-30 MK and the cooler plasma below 10 MK. We infer, for the first time, a consistent evolution of the DEM structure in a solar-type star. The emission measure of the hotter component rapidly decreases with age and becomes unimportant at ages beyond ~500 Myr. The emitted X-ray emission of the young Sun thus rapidly softened, which had important implications for the young planetary atmospheres. We suggest that the high-temperature component is the result of superimposed but temporally unresolved flaring events and support this picture by reconstructing the time-integrated (average) emission measure distribution of a typical solar X-ray flare. Radio observations of active stars fit well into this picture and suggest that the presence of nonthermal electrons in coronae is linked to the presence of hot ( > 10 MK) plasma, very much the same situation as in solar flares. We find, however, that radio emission saturates, if at all, at smaller rotation periods than does X-ray emission.

The H1 detector at HERA

Abstract: General aspects of the H1 detector at the electron-proton storage ring HERA as well as technical descriptions of the magnet, luminosity system, trigger, slow-control, data acquisition and off-line data handling are given. The three major components of the detector, the tracking, calorimeter and muon detectors, will be described in a forthcoming article. The present paper describes the detector that was used from 1992 to the end of 1994. After this a major upgrade of some components was undertaken. Some performance figures from luminosity runs at HERA during 1993 and 1994 are given.

Cross sections for the production of residual nuclides by low- and medium-energy protons from the target elements c, n, o, mg, al, si, ca, ti, v, mn, fe, co, ni, cu, sr, y, zr, nb, ba and au

Abstract: Cross sections for residual nuclide production by p-induced reactions were measured from thresholds up to 2.6 GeV using accelerators at CERN/Geneve, IPN/Orsay, KFA/Julich, LANL/Los Alamos, LNS/Saclay, PSI/Villigen, TSL/Uppsala, LUC/Louvain La Neuve. The target elements C, N, O, Mg, Al, Si, Ca, Ti, V, Mn, Fe, Co, Ni, Cu, Sr, Y, Zr, Nb, Ba and Au were investigated. Residual nuclides were measured by X- and γ-spectrometry and by Accelerator Mass Spectrometry (AMS). The measured cross sections were corrected for interfering secondary particles in experiments with primary proton energies above 200 MeV. Our consistent database covers presently ca 550 nuclear reactions and contains nearly 15000 individual cross sections of which about 10000 are reported here for the first time. They provide a basis for model calculations of the production of cosmogenic nuclides in extraterrestrial matter by solar and galactic cosmic ray protons. They are of importance for many other applications in which medium energy nuclear reactions have to be considered ranging from astrophysics over space and environmental sciences to accelerator technology and accelerator-based nuclear waste transmutation and energy amplification. The experimental data are compared with theoretical ones based on calculations using an INC/E model in form of the HETC/KFA2 code and on the hybrid model of preequilibrium reactions in form of the AREL code.

Design and fabrication of double-chirped mirrors

Abstract: We present an analytic design method for the reproducible fabrication of double-chirped mirrors to achieve simultaneously a high reflectivity and dispersion compensation over an extended bandwidth compared with those of standard quarter-wave Bragg mirrors. The mirrors are fabricated by ion beam sputtering. Use of these mirrors in a Ti:sapphire laser leads to 6.5-fs pulses directly out of the laser. The method can also be applied to the design of chirped-fiber gratings and general optical filters.

Activation of the human brain by monetary reward

Abstract: WITH the purpose of studying neural activation associated with reward processing in humans, we measured regional cerebral blood flow in 10 right-handed healthy subjects performing a delayed go-no go task in two different reinforcement conditions. Correct responses were either rewarded by money or a simple 'ok' reinforcer. Behaviour rewarded by money, as compared with the 'ok' reinforcement, was most significantly associated with activation of dorsolateral and orbital frontal cortex and also involved the midbrain and thalamus. These results may reflect the processing of reward information, although arousal effects cannot be completely excluded. It is suggested that the observed foci are implicated in the assessment of consequences in goal-directed behaviour which agrees with research in non-human primates.

Molecular-Based Magnetism in Bimetallic Two-Dimensional Oxalate-Bridged Networks. An X-ray and Neutron Diffraction Study.

Abstract: Bimetallic, oxalate-bridged compounds with bi- and trivalent transition metals comprise a class of layered materials which express a large variety in their molecular-based magnetic behavior. Because of this, the availability of the corresponding single-crystal structural data is essential to the successful interpretation of the experimental magnetic results. We report in this paper the crystal structure and magnetic properties of the ferromagnetic compound {[N(n-C3H7)4][MnIICrIII(C2O4)3]}n (1), the crystal structure of the antiferromagnetic compound {[N(n-C4H9)4][MnIIFeIII(C2O4)3]}n (2), and the results of a neutron diffraction study of a polycrystalline sample of the ferromagnetic compound {[P(C6D5)4][MnIICrIII(C2O4)3]}n (3). Crystal data: 1, rhombohedral, R3c, a = 9.363(3) A, c = 49.207(27) A, Z = 6; 2, hexagonal, P63, a = 9.482(2) A, c = 17.827(8) A, Z = 2. The structures consist of anionic, two-dimensional, honeycomb networks formed by the oxalate-bridged metal ions, interleaved by the templating cations. Single-crystal field dependent magnetization measurements as well as elastic neutron scattering experiments on the manganese(II)−chromium(III) samples show the existence of long-range ferromagnetic ordering behavior below Tc = 6 K. The magnetic structure corresponds to an alignment of the spins perpendicular to the network layers. In contrast, the manganese(II)−iron(III) compound expresses a two-dimensional antiferromagnetic ordering.

Complementary PET studies of striatal neuronal function in the differential diagnosis between multiple system atrophy and Parkinson's disease

Abstract: We used PET with the tracers [18F]fluorodeoxyglucose (FDG), [18F]fluorodopa (FDOPA) and [11C]raclopride (RACLO) to study striatal glucose and dopa metabolism, and dopamine D2 receptor binding, respectively, in nine patients with multiple system atrophy. Ten patients with classical Parkinson's disease were investigated with the same three PET tracers' and three separate groups, each of 10 healthy subjects, served as control populations. We found that striatal FDOPA values separated all healthy subjects from patients with parkinsonism but they were not useful in distinguishing multiple system atrophy from Parkinson's disease. Conversely, striatal RACLO as well as FDG values discriminated all multiple system atrophy from Parkinson's disease patients as well as from healthy control subjects. Metabolic and receptor binding decrements in the putamen of multiple system atrophy patients were significantly correlated. Stepwise regression analysis revealed that a linear combination of putamen RACLO and FDOPA values accurately predicted clinical measures of disease severity in the multiple system atrophy group. Our findings suggest that striatal FDG and particularly RACLO are sensitive and effective measures of striatal function and may help characterizing patients with multiple system atrophy. In contrast, FDOPA measurements are accurate in detecting abnormalities of the nigrostriatal dopaminergic system but may not distinguish among different forms of parkinsonism.

Correlating δ13C and δ18O in cellulose of trees

Abstract: We measured the carbon and oxygen isotopic composition of stem cellulose of Pinus sylvestris, Picea abies, Fagus sylvatica and Fraxinus excelsior. Several sites along a transect of a small valley in Switzerland were selected which differ in soil moisture conditions. At every site, six trees per species were sampled, and a sample representing a mean value for the period from 1940 to 1990 was analysed. For all species, the mean site δ13C and δ18O of stem cellulose are related to the soil moisture availability, whereby higher isotope ratios are found at drier sites. This result is consistent with isotope fractionation models when assuming enhanced stomatal resistance (thus higher δ13C of incorporated carbon) and increased oxygen isotope enrichment in the leaf water (thus higher δ18O) at the dry sites. δ18 O-δ13C plots reveal a linear relationship between the carbon and oxygen isotopes in cellulose. To interpret this relationship we developed an equation which combines the above-mentioned fractionation models. An important new parameter is the degree to which the leaf water enrichment is reflected in the stem cellulose. In the combined model the slope of the δ18O-δ13C plot is related to the sensitivity of the pi/pa of a plant to changing relative humidity.

Heavy-fermion systems studied by μSR technique

Abstract: The author attempts to give a comprehensive discussion of studies performed with the positive-muon spin rotation and relaxation technique (also known as the {mu}SR technique) on heavy-fermion compounds. The subtle competition between the demagnetizing Kondo interaction and the intersite Ruderman-Kittel-Kasuya-Yosida exchange interaction is believed to be the primary ingredient for the wealth of different ground states observed for this class of rare-earth{endash} and actinide-containing intermetallic compounds. Due to its microscopic character, its sensitivity to extremely small internal fields, and its capacity to detect spatially inhomogeneous magnetic features, the {mu}SR technique has been extensively utilized to investigate the peculiar magnetic properties of these ground states and improve our knowledge of heavy-fermion phenomena. In addition to providing a short introduction to {mu}SR, where the intrinsic difficulties of the method are clearly stated, this article reviews the main results obtained by this technique on the best-known heavy-fermion compounds (superconductors, band magnets, local-moment magnets, non-Fermi-liquid systems, and Kondo insulators). Special emphasis is placed on the particular information obtainable by monitoring the implanted muon. {copyright} {ital 1997} {ital The American Physical Society}

The tracking calorimeter and muon detectors of the H1 experiment at Hera

Abstract: Technical aspects of the three major components of the H1 detector at the electron-proton storage ring HERA are described. This paper covers the detector status up to the end of 1994 when a major upgrading of some of its elements was undertaken. A description of the other elements of the detector and some performance figures from luminosity runs at HERA during 1993 and 1994 are given in a paper previously published in this journal.

Stable carbon isotopes in tree rings of beech : climatic versus site-related influences

Abstract: Stable carbon isotopes in tree rings are a promising tool in palaeoclimate research, provided attempts are made to disentangle climatic from local effects (e.g. soil properties, competition, light). The 13C/12C variations in cellulose of tree rings of beech (Fagus sylvatica) were determined at several sites in the Swiss Central Plateau covering the last 50 years. We chose sites which differ in moisture conditions and sampled cores from four to six trees per site. The mean 13C/12C series from the different dry sites (distant by up to 40 km) are closely interrelated suggesting a common external cause. Correlation analysis with climate data proved the total precipitation in the months May, June and July to have the strongest effect on the carbon isotopes (r = – 0.73). This result is in agreement with the commonly used model which relates the isotope discrimination to the water use efficiency. On the other hand, the isotope series of the wet sites are not as well correlated to the climate. At two of the sites (a dry and a humid) tree ring width suddenly increased. We used this effect as a test-case to study the influence of local growth conditions on the climate-isotope relationship.

Chemical properties of element 106 (seaborgium)

Abstract: The synthesis, via nuclear fusion reactions, of elements heavier than the actinides, allows one to probe the limits of the periodic table as a means of classifying the elements. In particular, deviations in the periodicity of chemical properties for the heaviest elements are predicted as a consequence of increasingly strong relativistic effects on the electronic shell structure1,2,3,4,5,6,7. The transactinide elements have now been extended up to element 112 (ref. 8), but the chemical properties have been investigated only for the first two of the transactinide elements, 104 and 105 (refs 9,10,11,12,13,14,15,16,17,18,19). Those studies showed that relativistic effect render these two elements chemically different from their lighter homologues in the same columns of the periodic table (Fig. 1). Here we report the chemical separation of element 106 (seaborgium, Sg) and investigations of its chemical behaviour in the gas phase and in aqueous solution. The methods that we use are able to probe the reactivity of individual atoms, and based on the detection of just seven atoms of seaborgium we find that it exhibits properties characteristic of the group 6 homologues molybdenum and tungsten. Thus seaborgium appears to restore the trends of the periodic table disrupted by relativistic effects in elements 104 and 105.

Status report of the PSI/ETH AMS facility

Abstract: The technical and operational details of the Zurich AMS system are discussed and an overview of new developments which have improved efficiency, sensitivity and accuracy of the measurements is given. The numerous applications associated with these measurements will not be covered.

Miniature integrated optical modules for chemical and biochemical sensing.

Abstract: An overview is given on the principal ideas, new concepts and practical issues for accomplishing complete miniature sensor modules for chemical and biochemical applications, which are at the same time small, highly sensitive and stable The novelty of the approach is mainly based on using different types of smart planar optical transducer (SPOT) chips, which not only carry out the task of conventional integrated optical transducers, but also perform additional functions for which peripheral equipment is otherwise needed The emphasis is on pointing out and discussing the most important aspects for refractometric modules Different approaches and sensor types are compared with respect to fulfilling the requirements for practical applications New results concerning the use of multilayer waveguides and the implementation of novel modules are also presented Key issues discussed are the importance of a proper theoretical modelling of the sensor chips and the (bio-) chemical sensing layers; the availability of micro- and nanofabrication technologies suitable for realizing sensors based on a variety of substrate materials, such as glasses, polymers and semiconductors; the possibility of mass-producing low-cost SPOT chips; using standardized waveguides for the implementation of miniature integrated optical chemical benches; employing planar micro-optical elements for accomplishing illumination and detection sub-modules; the advantages of surface-emitting chip configurations with respect to miniaturization and adaptation to different applications; schemes for single-chip multicomponent analysis based on sensor-pad arrays; and the significance of using on-chip measuring variables and true differential on-chip referencing for achieving both high sensitivity and stability

200-Year Record of Metals in Lake Sediments and Natural Background Concentrations

Abstract: Lake sediments conserve important information about past conditions of a lake and its environments. We present analyses of calcium, manganese, iron, copper, zinc, cadmium, mercury, and lead in dated (210Pb, 137Cs, varve-chronology) sediment cores from Zurichsee (Lake Zurich), Switzerland, covering a time span of the last 200 years and an additional time interval between 13 500 and 15 000 years before the present time. The concentrations of these elements varied very little in pre-anthropogenic sediments and represent geochemical background concentrations. With the beginning of industrialization in the early 19th century and the corresponding growth of population, significant changes occurred in the concentrations of the investigated metals. Copper, zinc, and cadmium increased until about 1960 and decreased sharply afterwards. The increase correlates to the growth of local industrial productivity (and population growth), whereas the decrease after about 1960 was caused by (i) the introduction of sewage tre...

Premartensitic phenomena in the ferro- and paramagnetic phases of Ni 2 MnGa

Abstract: Low-energy phonons were studied in the ferromagnetic and paramagnetic phases of the Heusler alloy ${\mathrm{Ni}}_{2}\mathrm{MnGa}.$ The investigated sample shows a martensitic phase transformation with a transition temperature ${T}_{M}\ensuremath{\approx}284\mathrm{K},$ only about 80 K below the Curie temperature. Therefore, premartensitic phenomena could be studied in the ferromagnetic as well as in the paramagnetic state. The (\ensuremath{\xi} \ensuremath{\xi} 0) ${\mathrm{TA}}_{2}$-phonon branch shows a strong but incomplete softening at $\ensuremath{\xi}\ensuremath{\approx}1/3$ in the premartensitic phase when the temperature approaches ${T}_{M}.$ The temperature dependence of this softening changes at the Curie temperature which can be explained by an additional contribution of the magnetization to the Landau free energy. At the wave vector of the strongest phonon softening a central peak occurs. A second elastic peak, with the same temperature behavior, appears at $\ensuremath{\xi}\ensuremath{\approx}0.17.$ The relation of these elastic precursors to the low-temperature structure is discussed.