University of Potsdam

About: University of Potsdam is a education organization based out in Potsdam, Germany. It is known for research contribution in the topics: Population & Computer science. The organization has 9629 authors who have published 26740 publications receiving 759745 citations. The organization is also known as: Universität Potsdam.

Internal and external green-blue agricultural water footprints of nations, and related water and land savings through trade

Abstract: . The need to increase food production for a growing world population makes an assessment of global agricultural water productivities and virtual water flows important. Using the hydrology and agro-biosphere model LPJmL, we quantify at 0.5° resolution the amount of blue and green water (irrigation and precipitation water) needed to produce one unit of crop yield, for 11 of the world's major crop types. Based on these, we also quantify the agricultural water footprints (WFP) of all countries, for the period 1998–2002, distinguishing internal and external WFP (virtual water imported from other countries) and their blue and green components, respectively. Moreover, we calculate water savings and losses, and for the first time also land savings and losses, through international trade with these products. The consistent separation of blue and green water flows and footprints shows that green water globally dominates both the internal and external WFP (84 % of the global WFP and 94 % of the external WFP rely on green water). While no country ranks among the top ten with respect to all water footprints calculated here, Pakistan and Iran demonstrate high absolute and per capita blue WFP, and the US and India demonstrate high absolute green and blue WFPs. The external WFPs are relatively small (6 % of the total global blue WFP, 16 % of the total global green WFP). Nevertheless, current trade of the products considered here saves significant water volumes and land areas (~263 km3 and ~41 Mha, respectively, equivalent to 5 % of the sowing area of the considered crops and 3.5 % of the annual precipitation on this area). Relating the proportions of external to internal blue/green WFP to the per capita WFPs allows recognizing that only a few countries consume more water from abroad than from their own territory and have at the same time above-average WFPs. Thus, countries with high per capita water consumption affect mainly the water availability in their own country. Finally, this study finds that flows/savings of both virtual water and virtual land need to be analysed together, since they are intrinsically related.

Polymer translocation: the first two decades and the recent diversification

Abstract: Probably no other field of statistical physics at the borderline of soft matter and biological physics has caused such a flurry of papers as polymer translocation since the 1994 landmark paper by Bezrukov, Vodyanoy, and Parsegian and the study of Kasianowicz in 1996. Experiments, simulations, and theoretical approaches are still contributing novel insights to date, while no universal consensus on the statistical understanding of polymer translocation has been reached. We here collect the published results, in particular, the famous–infamous debate on the scaling exponents governing the translocation process. We put these results into perspective and discuss where the field is going. In particular, we argue that the phenomenon of polymer translocation is non-universal and highly sensitive to the exact specifications of the models and experiments used towards its analysis.

Why Triple Bonds Protect Acenes from Oxidation and Decomposition

Abstract: An experimental and computational study on the impact of functional groups on the oxidation stability of higher acenes is presented. We synthesized anthracenes, tetracenes, and pentacenes with various substituents at the periphery, identified their photooxygenation products, and measured the kinetics. Furthermore, the products obtained from thermolysis and the kinetics of the thermolysis are investigated. Density functional theory is applied in order to predict reaction energies, frontier molecular orbital interactions, and radical stabilization energies. The combined results allow us to describe the mechanisms of the oxidations and the subsequent thermolysis. We found that the alkynyl group not only enhances the oxidation stability of acenes but also protects the resulting endoperoxides from thermal decomposition. Additionally, such substituents increase the regioselectivity of the photooxygenation of tetracenes and pentacenes. For the first time, we oxidized alkynylpentacenes by using chemically generat...

The evolution of faint AGN between z ' 1 and z ' 5 from the COMBO-17 survey

Abstract: We present a determination of the optical/UV AGN luminosity function and its evolution, based on a large sample of faint (R< 24) QSOs identified in the COMBO-17 survey. Using multi-band photometry in 17 filters within 350 nm < obs < 930 nm, we could simultaneously determine photometric redshifts with an accuracy of z < 0:03 and obtain spectral energy distributions. The redshift range covered by the sample is 1:2 < z < 4:8, which implies that even at z' 3, the sample reaches below luminosities corresponding to MB= 23, conventionally employed to distinguish between Seyfert galaxies and quasars. We clearly detect a broad plateau-like maximum of quasar activity around z ' 2 and map out the smooth turnover between z' 1a ndz' 4. The shape of the LF is characterised by some mild curvature, but no sharp "break" is present within the range of luminosities covered. Using only the COMBO-17 data, the evolving LF can be adequately described by either a pure density evolution (PDE) or a pure luminosity evolution (PLE) model. However, the absence of a strong L-like feature in the shape of the LF inhibits a robust distinction between these modes. We present a robust estimate for the integrated UV luminosity generation by AGN as a function of redshift. We find that the LF continues to rise even at the lowest luminosities probed by our survey, but that the slope is suciently shallow that the contribution of low-luminosity AGN to the UV luminosity density is negligible. Although our sample reaches much fainter flux levels than previous data sets, our results on space densities and LF slopes are completely consistent with extrapolations from recent major surveys such as SDSS and 2QZ.