Journal ArticleDOI
Enhanced activation of peroxymonosulfate by nitrogen doped porous carbon for effective removal of organic pollutants
TLDR
In this paper, three nitrogen-rich metal-organic frameworks (ZIF-8, NH2-MIL-53 and IRMOF-3) with nitrogen content of 24.7, 6.28 and 5.16 were chosen to prepare the nitrogen doped porous carbons (NPCs) with different nitrogen content.About:
This article is published in Carbon.The article was published on 2017-05-01. It has received 339 citations till now. The article focuses on the topics: Catalysis.read more
Citations
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Singlet oxygen-dominated non-radical oxidation process for efficient degradation of bisphenol A under high salinity condition.
Rui Luo,Li Miaoqing,Chaohai Wang,Ming Zhang,Muhammad Abdul Nasir Khan,Xiuyun Sun,Jinyou Shen,Weiqing Han,Lianjun Wang,Jiansheng Li +9 more
TL;DR: The results highlight leveraging the non-radical pathway dominated by singlet oxygen to conquer the inhibitory effect of anions in NGC700/PMS system, which represents a crucial step towards environmental remediation under high salinity condition.
Journal ArticleDOI
The Intrinsic Nature of Persulfate Activation and N-Doping in Carbocatalysis.
TL;DR: It is illustrated that the roles of nitrogen species in CNT-based persulfate systems are intrinsically different, which provides new insights into the intrinsic roles of heteroatom doping in nanocarbons for persulfates activation and unveils the principles for rational design of reaction-oriented carbocatalysts for pers fulfilment in advanced oxidation processes.
Journal ArticleDOI
A review of the innovations in metal- and carbon-based catalysts explored for heterogeneous peroxymonosulfate (PMS) activation, with focus on radical vs. non-radical degradation pathways of organic contaminants
TL;DR: In this paper, the authors summarize the rapid development of various heterogeneous catalysts developed for peroxymonosulfate (PMS) activation, destined for the degradation of organic contaminants.
Journal ArticleDOI
Recent advances on preparation and environmental applications of MOF-derived carbons in catalysis
TL;DR: The synthesis strategies of MOF-derived carbons with different physical and chemical properties, obtained through direct carbonization, co-pyrolysis and post-treatment are summarized.
Journal ArticleDOI
Non-radical-dominated catalytic degradation of bisphenol A by ZIF-67 derived nitrogen-doped carbon nanotubes frameworks in the presence of peroxymonosulfate
TL;DR: In this paper, a series of nitrogen-doped carbon nanotubes (NCNTFs) with distinguishable nitrogen content and graphitization degree have been successfully prepared through in situ transformation of ZIF-67 under N2/H2 atmosphere at different pyrolysis temperature.
References
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Journal ArticleDOI
Exceptional chemical and thermal stability of zeolitic imidazolate frameworks
Kyo Sung Park,Zheng Ni,Adrien P. Côté,Jae Yong Choi,Rudan Huang,Fernando J. Uribe-Romo,Hee K. Chae,Michael O'Keeffe,Omar M. Yaghi +8 more
TL;DR: Study of the gas adsorption and thermal and chemical stability of two prototypical members, ZIF-8 and -11, demonstrated their permanent porosity, high thermal stability, and remarkable chemical resistance to boiling alkaline water and organic solvents.
Journal ArticleDOI
Cobalt-catalyzed sulfate radical-based advanced oxidation: A review on heterogeneous catalysts and applications
Peidong Hu,Mingce Long +1 more
TL;DR: In this paper, the state-of-the-art progress on various heterogeneous cobalt-based catalysts for sulfate radical-based advanced oxidation processes (SR-AOPs) is reviewed.
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Metal-organic framework as a template for porous carbon synthesis
TL;DR: Porous carbon was synthesized by heating the precursor FA within the pores of MOF-5 to display a high specific surface area and important hydrogen uptake and excellent electrochemical properties as an electrode material for electrochemical double-layered capacitor (EDLC).
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Degradation of organic contaminants in water with sulfate radicals generated by the conjunction of peroxymonosulfate with cobalt.
TL;DR: The advantage of Co/PMS compared to the traditional Fenton Reagent is attributed primarily to the oxidizing strength of the radicals formed, since sulfate radicals are stronger oxidants than hydroxyl and the thermodynamics of the transition-metal-oxidant coupling.
Journal ArticleDOI
From Bimetallic Metal‐Organic Framework to Porous Carbon: High Surface Area and Multicomponent Active Dopants for Excellent Electrocatalysis
TL;DR: The optimized carbon with additional phosphorus dopant exhibits excellent electrocatalytic performance for the oxygen reduction reaction, which is much better than the benchmark Pt/C in alkaline media.