Journal ArticleDOI
Fe-g-C3N4-Catalyzed Oxidation of Benzene to Phenol Using Hydrogen Peroxide and Visible Light
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TLDR
A bioinspired iron-based catalyst with semiconductor photocatalytic functions in combination with a high surface area holds promise for synthetic chemistry via combining photocatalysis with organosynthesis through using g-C(3)N(4) nanoparticles.Abstract:
A bioinspired iron-based catalyst with semiconductor photocatalytic functions in combination with a high surface area holds promise for synthetic chemistry via combining photocatalysis with organosynthesis. Here exemplified for phenol synthesis, Fe-g-C3N4/SBA-15 is able to oxidize benzene to phenol with H2O2 even without the aid of strong acids or alkaline promoters. By taking advantage of both catalysis and photocatalyisis functions of g-C3N4 nanoparticles, the yield of the phenol can be markedly promoted.read more
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Direct hydroxylation of benzene to phenol by supported vanadium substitution polyoxometalates using H 2 O 2 as oxidant
Yingwei Yang,Ruiren Tang +1 more
TL;DR: In this article, a method for the direct hydroxylation of benzene to phenol catalyzed by supported vanadium-substituted polyoxometalates using H2O2 as an oxidant is described.
Journal ArticleDOI
Enhanced Hydroxylation of Benzene to Phenol with Hydrogen Peroxide over g-C3N4 Quantum Dots-Modified Fe-SBA-15 Catalysts: Synergistic Effect Among Fe Species, g-C3N4 QDs, and Porous Structure
Journal ArticleDOI
Restricted binding of a model protein on C3N4 nanosheets suggests an adequate biocompatibility of the nanomaterial
TL;DR: It is found that the C3N4 nanosheet has a limited influence on the structure of the λ-repressor protein, which substantiates the outstanding biocompatibility of the nanomaterial and suggests its potential usage as a protein drug delivery platform.
Journal ArticleDOI
A hierarchical zeolite-Y hampered metallo-ligand complexes for selective oxidation: A mechanistic point of view
TL;DR: In this paper, a series of Ni 2+ and Mn 2+ complexes with ligands derived from the condensation of 1-(2-hydroxyphenyl)ethan-1-one and/or 1-(5-chloro-2-hexyl)hexyl-hexanone with ethane-1,2-diamine have been synthesized as neat and zeolite Y enslaved complexes.
References
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TL;DR: The slow pace of hazardous waste remediation at military installations around the world is causing a serious delay in conversion of many of these facilities to civilian uses as discussed by the authors, which is a serious problem.
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A metal-free polymeric photocatalyst for hydrogen production from water under visible light
Xinchen Wang,Kazuhiko Maeda,Arne Thomas,Kazuhiro Takanabe,Gang Xin,Johan M. Carlsson,Kazunari Domen,Markus Antonietti +7 more
TL;DR: It is shown that an abundant material, polymeric carbon nitride, can produce hydrogen from water under visible-light irradiation in the presence of a sacrificial donor.
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Polymer semiconductors for artificial photosynthesis: hydrogen evolution by mesoporous graphitic carbon nitride with visible light.
Xinchen Wang,Kazuhiko Maeda,Xiufang Chen,Kazuhiro Takanabe,Kazunari Domen,Yidong Hou,Xianzhi Fu,Markus Antonietti +7 more
TL;DR: It is shown that the efficiency of hydrogen production by photochemical water reduction can be improved by approximately 1 order of magnitude by introducing the right type of mesoporosity into polymeric C(3)N(4).
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Metal‐Containing Carbon Nitride Compounds: A New Functional Organic–Metal Hybrid Material
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