Journal ArticleDOI
Fe-g-C3N4-Catalyzed Oxidation of Benzene to Phenol Using Hydrogen Peroxide and Visible Light
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TLDR
A bioinspired iron-based catalyst with semiconductor photocatalytic functions in combination with a high surface area holds promise for synthetic chemistry via combining photocatalysis with organosynthesis through using g-C(3)N(4) nanoparticles.Abstract:
A bioinspired iron-based catalyst with semiconductor photocatalytic functions in combination with a high surface area holds promise for synthetic chemistry via combining photocatalysis with organosynthesis. Here exemplified for phenol synthesis, Fe-g-C3N4/SBA-15 is able to oxidize benzene to phenol with H2O2 even without the aid of strong acids or alkaline promoters. By taking advantage of both catalysis and photocatalyisis functions of g-C3N4 nanoparticles, the yield of the phenol can be markedly promoted.read more
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Enhancement of Hydrogen Evolution Reaction Performance of Graphitic Carbon Nitride with Incorporated Nickel Boride
TL;DR: Li et al. as mentioned in this paper incorporated nickel boride (Ni2B) nanoparticles into bulk graphitic carbon nitride (g-C3N4) to enlarge the specific surface area, exfoliate the layers, and improve the electronic conductivity.
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Light-Induced Efficient Hydroxylation of Benzene to Phenol by Quinolinium and Polyoxovanadate-Based Supramolecular Catalysts.
TL;DR: It is demonstrated that polyoxoalkoxovanadates can serve as efficient catalysts which can not only stabilize quinolinium radicals but also reuse H 2 O 2 produced by quinolium ions under light irradiation to obtain excellent synergistic effect.
Journal ArticleDOI
Synthesis of g-C3N4/Bi4O5Br2 via reactable ionic liquid and its cooperation effect for the enhanced photocatalytic behavior towards ciprofloxacin degradation
TL;DR: In this article, a visible-light-driven g-C 3 N 4 /Bi 4 O 5 Br 2 composite material has been prepared via an ionic liquid 1-hexadecyl-3-methylimidazolium bromide ([C 16 mim]Br) assisted solvothermal method.
Journal ArticleDOI
Controlled synthesis of ordered mesoporous g-C3N4 with a confined space effect on its photocatalytic activity
Jinyuan Liu,Jia Yan,Haiyan Ji,Yuanguo Xu,Liying Huang,Yeping Li,Yanhua Song,Qi Zhang,Hui Xu,Huaming Li +9 more
TL;DR: In this article, an ordered mesoporous g-C3N4 photocatalyst was synthesized successfully using silica material SBA-15 as the hard template via an impregnation method at different calcinations temperatures.
Journal ArticleDOI
Multiple Doped Carbon Nitrides with Accelerated Interfacial Charge/Mass Transportation for Boosting Photocatalytic Hydrogen Evolution.
TL;DR: An in situ multiple heteroelement (sodium, oxygen, and iodide) doping strategy based on a molten salt-assisted route to prepare a green-colored carbon nitride (GCN) that shows an increased degradation activity of rhodamine B and highlights the importance of surface modulation through multiple earth-abundant element incorporation for designing of advanced and practical photocatalysts.
References
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A metal-free polymeric photocatalyst for hydrogen production from water under visible light
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TL;DR: It is shown that an abundant material, polymeric carbon nitride, can produce hydrogen from water under visible-light irradiation in the presence of a sacrificial donor.
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Polymer semiconductors for artificial photosynthesis: hydrogen evolution by mesoporous graphitic carbon nitride with visible light.
Xinchen Wang,Kazuhiko Maeda,Xiufang Chen,Kazuhiro Takanabe,Kazunari Domen,Yidong Hou,Xianzhi Fu,Markus Antonietti +7 more
TL;DR: It is shown that the efficiency of hydrogen production by photochemical water reduction can be improved by approximately 1 order of magnitude by introducing the right type of mesoporosity into polymeric C(3)N(4).
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Metal‐Containing Carbon Nitride Compounds: A New Functional Organic–Metal Hybrid Material
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