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Open AccessJournal ArticleDOI

High-resolution monitoring of nutrients in groundwater and surface waters: process understanding, quantification of loads and concentrations, and management applications

TLDR
In this article, the authors present an overview of the current state of high-resolution monitoring of nutrients and present a new assessment of the objectives behind high-frequency monitoring as classified into three main groups: improved understanding of the underlying hydrological, chemical, and biological processes (PU); quantification of true nutrient concentrations and loads (Q); and operational management, including evaluation of the effects of mitigation measures (M).
Abstract
Four sessions on "Monitoring Strategies: temporal trends in groundwater and surface water quality and quantity" at the EGU conferences in 2012, 2013, 2014, and 2015 and a special issue of HESS form the background for this overview of the current state of high-resolution monitoring of nutrients. The overview includes a summary of technologies applied in high-frequency monitoring of nutrients in the special issue. Moreover, we present a new assessment of the objectives behind high-frequency monitoring as classified into three main groups: (i) improved understanding of the underlying hydrological, chemical, and biological processes (PU); (ii) quantification of true nutrient concentrations and loads (Q); and (iii) operational management, including evaluation of the effects of mitigation measures (M). The contributions in the special issue focus on the implementation of high-frequency monitoring within the broader context of policy making and management of water in Europe for support of EU directives such as the Water Framework Directive, the Groundwater Directive, and the Nitrates Directive. The overview presented enabled us to highlight the typical objectives encountered in the application of high-frequency monitoring and to reflect on future developments and research needs in this growing field of expertise. © Author(s) 2016.

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Seasonal variability of stream water quality response to storm events captured using high-frequency and multi-parameter data

TL;DR: In this article, an original four-year data set that combines high frequency records of stream flow, turbidity, nitrate and dissolved organic carbon concentrations, and piezometric levels was used to characterize storm responses in a headwater agricultural catchment.
Journal ArticleDOI

Nonlinear empirical modeling to estimate phosphorus exports using continuous records of turbidity and discharge

TL;DR: In this paper, an empirical modelling approach using relatively low-cost continuous records of turbidity and discharge as proxies to estimate phosphorus (P) concentrations at a sub-hourly time step for estimating loads.
Journal ArticleDOI

High-frequency monitoring reveals how hydrochemistry and dissolved carbon respond to rainstorms at a karstic critical zone, Southwestern China

TL;DR: Overall, biogeochemical processes, hydrogeological properties, storm intensity/magnitude and the timing of storms (antecedent conditions) are main factors influencing the response of hydrochemical variables and dissolved carbon to storm events.
Journal ArticleDOI

An evaluation of high frequency turbidity as a proxy for riverine total phosphorus concentrations.

TL;DR: High frequency data can be used to better understand catchment response to external pressures and gain insights into water quality that will be missed with grab sampling, and it is clear that credible water chemistryData can be obtained with current high frequency sensors.
References
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Journal ArticleDOI

The fine structure of water‐quality dynamics: the (high‐frequency) wave of the future

TL;DR: Kirchner et al. as mentioned in this paper argue that catchment hydrochemistry is on the verge of a major new advance, driven by automated, online continuous analysis for many chemical constituents in natural waters.
Journal ArticleDOI

Catchment residence and travel time distributions: The master equation

TL;DR: Botter et al. as mentioned in this paper analyzed theoretically the probability density functions (pdf's) of travel and residence times, which are key descriptors of the mechanisms through which catchments retain and release old and event water, transporting solutes to receiving water bodies.
Journal ArticleDOI

Limitations of instantaneous water quality sampling in surface-water catchments: Comparison with near-continuous phosphorus time-series data

TL;DR: In this article, a range of sampling methodologies and load estimation techniques are applied to phosphorus data from such a surface water dominated river system, instrumented at three sub-catchments with near-continuous monitoring stations.
Journal ArticleDOI

Characterising phosphorus transfers in rural catchments using a continuous bank-side analyser

TL;DR: In this paper, a six-month series of high-resolution synchronous stream discharge and total phosphorus (TP) concentration data is presented from a 5 km2 agricultural catchment in the Lough Neagh basin, Northern Ireland.
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