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Hole density and acceptor-type defects in MBE-grown GaSb1-x Bix

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TLDR
In this article, acceptor-type defects in GaSb1−xBix grown by molecular beam epitaxy were studied and it was shown that both Ga vacancies and Ga antisites contribute to the hole density and the proportion of the two acceptor type defects vary in the layers.
Abstract
We study acceptor-type defects in GaSb1−xBix grown by molecular beam epitaxy. The hole density of the GaSb1−xBix layers, from capacitance-voltage measurements of Schottky diodes, is higher than that of the binary alloys and increases linearly up to 1019 − cm 3 with the Bi content. Positron annihilation spectroscopy and ab initio calculations show that both Ga vacancies and Ga antisites contribute to the hole density and that the proportion of the two acceptor-type defects vary in the layers. The modification of the band gap due to Bi incorporation as well as the growth parameters are suggested to affect the concentrations of acceptor-type defects.

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Journal Article

New Semiconductor Alloy GaAs_ Bi_x Grown by Metal Organic Vapor Phase Epitaxy

TL;DR: In this paper, a new semiconductor alloy material, GaAs1-xBix, was created by metal organic vapor phase epitaxial (MOVPE) growth, and X-ray diffraction measurements of alloy layers reveal that the diffraction patterns are satisfactory.
Journal ArticleDOI

Type I GaSb 1-x Bi x /GaSb quantum wells dedicated for mid infrared laser applications: Photoreflectance studies of bandgap alignment

TL;DR: In this paper, a set of GaSb1-xBix/GaSb quantum wells (QWs) of various widths and contents were grown by molecular beam epitaxy and investigated by photoreflectance (PR) spectroscopy.
Journal Article

Defect identification in semiconductors with positron annihilation: experiment and theory

TL;DR: Positron annihilation spectroscopy is particularly suitable for studying vacancy-type defects in semiconductors and combining state-of-the-art experimental and theoretical methods allows for detailed identification of the defects and their chemical surroundings as mentioned in this paper.
Book ChapterDOI

Dilute bismide and nitride alloys for mid-IR optoelectronic devices

TL;DR: In this paper, a review of theoretical simulations, epitaxial growth, material characterizations, and devices of dilute bismides and dilute nitrides is presented.
Journal ArticleDOI

Raman spectroscopy of GaSb1−xBix alloys with high Bi content

TL;DR: In this article, the crystal morphology and Raman scattering features of high structural quality GaSb1−xBix alloys grown by molecular beam epitaxy with a high Bi content (x up to ∼0.10).
References
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Journal ArticleDOI

Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set.

TL;DR: An efficient scheme for calculating the Kohn-Sham ground state of metallic systems using pseudopotentials and a plane-wave basis set is presented and the application of Pulay's DIIS method to the iterative diagonalization of large matrices will be discussed.
Journal ArticleDOI

From ultrasoft pseudopotentials to the projector augmented-wave method

TL;DR: In this paper, the formal relationship between US Vanderbilt-type pseudopotentials and Blochl's projector augmented wave (PAW) method is derived and the Hamilton operator, the forces, and the stress tensor are derived for this modified PAW functional.
Journal ArticleDOI

Efficiency of ab-initio total energy calculations for metals and semiconductors using a plane-wave basis set

TL;DR: A detailed description and comparison of algorithms for performing ab-initio quantum-mechanical calculations using pseudopotentials and a plane-wave basis set is presented in this article. But this is not a comparison of our algorithm with the one presented in this paper.
Journal ArticleDOI

Defect identification in semiconductors with positron annihilation: Experiment and theory

TL;DR: Positron annihilation spectroscopy is particularly suitable for studying vacancy-type defects in semiconductors and combining state-of-the-art experimental and theoretical methods allows for detailed identification of the defects and their chemical surroundings as mentioned in this paper.
Journal ArticleDOI

Giant spin-orbit bowing in GaAs1-xBix.

TL;DR: This is the first observation of a large relativistic correction to the host electronic band structure induced by just a few percent of isoelectronic doping in a semiconductor material, which opens up the possibility of tailoring the spin-orbit splitting in semiconductors for spintronic applications.
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