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Hybrid materials based on lanthanide organic complexes: a review

Jing Feng, +1 more
- 07 Jan 2013 - 
- Vol. 42, Iss: 1, pp 387-410
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TLDR
This critical review begins with a formulation of the fundamentals of lanthanide organic complex luminescence, and presents various current designed ideas, synthetic routes, luminescent behaviors and potentials of the latest advanced organic-inorganic hybrid materials.
Abstract
A great deal of research has been carried out on lanthanide organic complex-based organic-inorganic hybrid materials in the last decade. This critical review begins with a formulation of the fundamentals of lanthanide organic complex luminescence, and presents various current designed ideas, synthetic routes, luminescence behaviors and potentials of the latest advanced (a) sol-gel materials, (b) mesoporous materials, (c) titania materials, (d) ionic liquids and ionogels, (e) polymers, and (f) bifunctional magnetic-optical composites based on lanthanide organic complexes. Finally, challenges and opportunities for further improvement of organic-inorganic hybrid luminescent materials based on lanthanide organic complexes will be discussed.

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Citations
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Journal ArticleDOI

Dicationic organic salts: gelators for ionic liquids.

TL;DR: Gelation tests demonstrated that organic salts used were able to harden ionic liquids and the ability of materials to respond to external stimuli such as magnetic stirring or ultrasound irradiation was analyzed.
Journal ArticleDOI

Insight into the Luminescence Behavior of Europium(III) β-Diketonate Complexes Encapsulated in Zeolite L Crystals

TL;DR: In this paper, the acidity of europium(III)-exchanged zeolite (Eu3+/ZL) and its influence on the luminescence performances of encapsulated Europium (III) β-diketonate complexes are reported.
Journal ArticleDOI

A Red-Emitting Luminescent Material Capable of Detecting Low Water Content in Organic Solvents.

TL;DR: A new red-emitting luminescent material was prepared from a gel formed by simply mixing EuCl3 ⋅6 H2 O and 4'-para-phenylcarboxyl-2,2':6',2''-terpyridine (Hcptpy) in anhydrous ethanol at room temperature.
Journal ArticleDOI

Water-soluble Tb3+ and Eu3+ complexes with ionophilic (ionically tagged) ligands as fluorescence imaging probes.

TL;DR: Use of the task-specific ionic liquid 1-methyl-3-carboxymethyl-imidazolium chloride (MAI·Cl) as the ionophilic ligand (ionically tagged) proved to be a simple, elegant, and efficient strategy to obtain highly fluorescent water-soluble Eu(3+) (EuMAI) and Tb( 3+) (Tb MAI) complexes.
Journal ArticleDOI

Complexation behavior of poly(acrylic acid) and lanthanide ions

TL;DR: In this paper, the complexation behavior of PAA and lanthanide (Ln) ions was schematically investigated and it was shown that when pH values are higher than 2.5, the PAA-Ln complex would precipitate out from the solution.
References
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Journal ArticleDOI

Ordered mesoporous molecular sieves synthesized by a liquid-crystal template mechanism

TL;DR: In this paper, the synthesis of mesoporous inorganic solids from calcination of aluminosilicate gels in the presence of surfactants is described, in which the silicate material forms inorganic walls between ordered surfactant micelles.
Journal ArticleDOI

A new family of mesoporous molecular sieves prepared with liquid crystal templates

TL;DR: In this paper, the synthesis, characterization, and proposed mechanism of formation of a new family of silicatelaluminosilicate mesoporous molecular sieves designated as M41S is described.
Journal Article

Photoelectrochemical cells : Materials for clean energy

Michael Grätzel
- 01 Jan 2001 - 
TL;DR: In this paper, the authors look into the historical background, and present status and development prospects for photoelectrochemical cells, based on nanocrystalline materials and conducting polymer films.
Journal ArticleDOI

A Theory of Sensitized Luminescence in Solids

TL;DR: In this article, the resonance theory of Forster, which involves only allowed transitions, is extended to include transfer by means of forbidden transitions which, it is concluded, are responsible for the transfer in all inorganic systems yet investigated.
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