Journal ArticleDOI
Hybrid materials based on lanthanide organic complexes: a review
Jing Feng,Hongjie Zhang +1 more
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TLDR
This critical review begins with a formulation of the fundamentals of lanthanide organic complex luminescence, and presents various current designed ideas, synthetic routes, luminescent behaviors and potentials of the latest advanced organic-inorganic hybrid materials.Abstract:
A great deal of research has been carried out on lanthanide organic complex-based organic-inorganic hybrid materials in the last decade. This critical review begins with a formulation of the fundamentals of lanthanide organic complex luminescence, and presents various current designed ideas, synthetic routes, luminescence behaviors and potentials of the latest advanced (a) sol-gel materials, (b) mesoporous materials, (c) titania materials, (d) ionic liquids and ionogels, (e) polymers, and (f) bifunctional magnetic-optical composites based on lanthanide organic complexes. Finally, challenges and opportunities for further improvement of organic-inorganic hybrid luminescent materials based on lanthanide organic complexes will be discussed.read more
Citations
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Tuning White Light Emission in Dinuclear Phenoxo Bridged DyIII Complexes.
TL;DR: The nature of the coordinated solvent molecule plays an important role in the behavior of the thermal dependence of the Y/B (yellow/blue) emission ratio of the DyIII complexes, since for I the variation of this ratio is significant, while for the other Dy III complexes with DMF as ligand the ratio remains constant within experimental error.
Journal ArticleDOI
Novel organic–inorganic hybrid soft xerogels with lanthanide complexes through an ionic liquid linkage
Zhi-Yuan Yan,Bing Yan +1 more
TL;DR: In this paper, a series of hybrid soft materials of alumina and titania xerogels centered with lanthanide complexes are prepared via the hydrolysis and polycondensation of aluminum isopropoxide or tetrabutyl titanate.
Journal ArticleDOI
Microwave-assisted synthesis of nanoscale Eu(BTC)(H 2 O)·DMF with tunable luminescence
TL;DR: In this paper, a nanoscale europium(III) metal-organic frameworks, Eu(BTC)(H2O)·DMF, were synthesized by rapid microwave assisted method.
Journal ArticleDOI
The Role of Blue-Emissive 1,8-Naphthalimidopyridine N-Oxide in Sensitizing EuIII Photoluminescence in Dimeric Hexafluoroacetylacetonate Complexes
Journal ArticleDOI
Enhanced full color tunable luminescent lyotropic liquid crystals from P123 and ionic liquid by doping lanthanide complexes and AIEgen.
TL;DR: Here, a highly luminescent hexagonal (H1) LLC containing a red-emitting trisdipicolinate lanthanide complex from Pluronic 123 and 1-butyl-3-methylimidazolium hexafluorophosphate is fabricated to fabricate soft materials with rich luminescence properties.
References
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Ordered mesoporous molecular sieves synthesized by a liquid-crystal template mechanism
TL;DR: In this paper, the synthesis of mesoporous inorganic solids from calcination of aluminosilicate gels in the presence of surfactants is described, in which the silicate material forms inorganic walls between ordered surfactant micelles.
Journal ArticleDOI
A new family of mesoporous molecular sieves prepared with liquid crystal templates
Jeffrey S. Beck,James C. Vartuli,Wieslaw J. Roth,M. E. Leonowicz,Charles T. Kresge,Kirk D. Schmitt,Cynthia Ting-Wah Chu,David H. Olson,E. W. Sheppard,S. B. McCullen,J. B. Higgins,J.L. Schlenker +11 more
TL;DR: In this paper, the synthesis, characterization, and proposed mechanism of formation of a new family of silicatelaluminosilicate mesoporous molecular sieves designated as M41S is described.
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Photoelectrochemical cells : Materials for clean energy
TL;DR: In this paper, the authors look into the historical background, and present status and development prospects for photoelectrochemical cells, based on nanocrystalline materials and conducting polymer films.
Journal ArticleDOI
A Theory of Sensitized Luminescence in Solids
TL;DR: In this article, the resonance theory of Forster, which involves only allowed transitions, is extended to include transfer by means of forbidden transitions which, it is concluded, are responsible for the transfer in all inorganic systems yet investigated.