Journal ArticleDOI
Hybrid materials based on lanthanide organic complexes: a review
Jing Feng,Hongjie Zhang +1 more
Reads0
Chats0
TLDR
This critical review begins with a formulation of the fundamentals of lanthanide organic complex luminescence, and presents various current designed ideas, synthetic routes, luminescent behaviors and potentials of the latest advanced organic-inorganic hybrid materials.Abstract:
A great deal of research has been carried out on lanthanide organic complex-based organic-inorganic hybrid materials in the last decade. This critical review begins with a formulation of the fundamentals of lanthanide organic complex luminescence, and presents various current designed ideas, synthetic routes, luminescence behaviors and potentials of the latest advanced (a) sol-gel materials, (b) mesoporous materials, (c) titania materials, (d) ionic liquids and ionogels, (e) polymers, and (f) bifunctional magnetic-optical composites based on lanthanide organic complexes. Finally, challenges and opportunities for further improvement of organic-inorganic hybrid luminescent materials based on lanthanide organic complexes will be discussed.read more
Citations
More filters
Journal ArticleDOI
Molecular imaging of biothiols and in vitro diagnostics based on an organic chromophore bearing a terbium hybrid probe
TL;DR: Evaluation of luminescence changes in cell culture demonstrated that this terbium-based luminescent hybrid inorganic/organic probe is cell membrane permeable and selectively lights up in the presence of cysteine and glutathione in human embryonic kidney cells and human lung adenocarcinoma cells.
Journal ArticleDOI
Modelling the luminescence of extended solids: an example of a highly luminescent MCM-41 impregnated with a Eu3+ β-diketonate complex
Mário R. Felício,Teresa G. Nunes,Patrícia A. A. M. Vaz,Alexandre M. P. Botas,Paulo J. A. Ribeiro-Claro,Rute A. S. Ferreira,Ricardo O. Freire,Pedro D. Vaz,Luís D. Carlos,Carla Nunes,Mariela M. Nolasco +10 more
TL;DR: In this paper, a regular MCM-41 type mesostructured silica was used as a support for the incorporation of tris(β-diketonate) complex Eu(tta)3ephen yielding the hybrid MCM/Eu material.
Journal ArticleDOI
Advanced Functional Luminescent Metallomesogens: The Key Role of the Metal Center.
TL;DR: In this article, the role of the molecular geometry induced by the metal center in metallomesogens to achieve the self-assembly required in the liquid-crystalline mesophase is investigated.
Journal ArticleDOI
Structural Variation and Switchable Nonlinear Optical Behavior of Metal–Organic Frameworks
TL;DR: In this article, two europium metal-organic frameworks (MOFs) based on the same ligand, named as ZJU-23-Eu and ZJUE-24Eu, are selectively synthesized by fine-tuning solvent contents to tailor the coordination modes.
Journal ArticleDOI
Europium (III) Organic Complexes in Porous Boron Nitride Microfibers: Efficient Hybrid Luminescent Material.
Jing Lin,Congcong Feng,Xin He,Weijia Wang,Yi Fang,Zhenya Liu,Jie Li,Chengchun Tang,Yang Huang +8 more
TL;DR: The design and synthesis of a novel kind of organic-inorganic hybrid material via the incorporation of europium (III) β-diketonate complexes into one-dimensional (1D) porous boron nitride (BN) microfibers and the remarkable increase of red emission is reported.
References
More filters
Journal ArticleDOI
Ordered mesoporous molecular sieves synthesized by a liquid-crystal template mechanism
TL;DR: In this paper, the synthesis of mesoporous inorganic solids from calcination of aluminosilicate gels in the presence of surfactants is described, in which the silicate material forms inorganic walls between ordered surfactant micelles.
Journal ArticleDOI
A new family of mesoporous molecular sieves prepared with liquid crystal templates
Jeffrey S. Beck,James C. Vartuli,Wieslaw J. Roth,M. E. Leonowicz,Charles T. Kresge,Kirk D. Schmitt,Cynthia Ting-Wah Chu,David H. Olson,E. W. Sheppard,S. B. McCullen,J. B. Higgins,J.L. Schlenker +11 more
TL;DR: In this paper, the synthesis, characterization, and proposed mechanism of formation of a new family of silicatelaluminosilicate mesoporous molecular sieves designated as M41S is described.
Journal Article
Photoelectrochemical cells : Materials for clean energy
TL;DR: In this paper, the authors look into the historical background, and present status and development prospects for photoelectrochemical cells, based on nanocrystalline materials and conducting polymer films.
Journal ArticleDOI
A Theory of Sensitized Luminescence in Solids
TL;DR: In this article, the resonance theory of Forster, which involves only allowed transitions, is extended to include transfer by means of forbidden transitions which, it is concluded, are responsible for the transfer in all inorganic systems yet investigated.