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Hybrid materials based on lanthanide organic complexes: a review

Jing Feng, +1 more
- 07 Jan 2013 - 
- Vol. 42, Iss: 1, pp 387-410
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TLDR
This critical review begins with a formulation of the fundamentals of lanthanide organic complex luminescence, and presents various current designed ideas, synthetic routes, luminescent behaviors and potentials of the latest advanced organic-inorganic hybrid materials.
Abstract
A great deal of research has been carried out on lanthanide organic complex-based organic-inorganic hybrid materials in the last decade. This critical review begins with a formulation of the fundamentals of lanthanide organic complex luminescence, and presents various current designed ideas, synthetic routes, luminescence behaviors and potentials of the latest advanced (a) sol-gel materials, (b) mesoporous materials, (c) titania materials, (d) ionic liquids and ionogels, (e) polymers, and (f) bifunctional magnetic-optical composites based on lanthanide organic complexes. Finally, challenges and opportunities for further improvement of organic-inorganic hybrid luminescent materials based on lanthanide organic complexes will be discussed.

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Citations
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Fluorescence sensing of fluoride ions and N, N- dimethylformamide by novel luminescent lanthanide(III) xerogels

TL;DR: In this article, two luminescent lanthanide acylamide derivatives covalently grafted to xerogels (donated as Ln-pp-xerogel, Ln=Eu, Tb) were designed and synthesized in situ via a sol-gel process.
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Electronic interactions between a quaternary pyridyl-β-diketonate and anionic clay nanosheets facilitate intense photoluminescence.

TL;DR: The fixation and spatial separation of β-diketonate in the narrow interlayer space was determined to be essential for obtaining strong emission.
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Polybenzobisimidazole-derived two-dimensional supramolecular polymer

TL;DR: In this article, a two-dimensional supramolecular polybenzobisimidazole (SP-PBBI) was obtained by liquid-phase exfoliation.
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Optical Gain in Polymer Composite Materials With P 2 O 2 :Er 3+ /Yb 3+ Codoped Nanoparticles

TL;DR: In this paper, the results of detailed numerical modeling and optimization of optical amplification in polymer nanocomposite materials, comprising highly doped phosphate nanoparticles in a polymer host, were presented.
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Excited-State Dynamics of Crossing-Controlled Energy Transfer in Europium Complexes

TL;DR: In this article , an energy-degeneracy-crossing-controlled EnT model was proposed, which can be experimentally confirmed by time-resolved two-dimensional photoluminescence measurements.
References
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Journal ArticleDOI

Ordered mesoporous molecular sieves synthesized by a liquid-crystal template mechanism

TL;DR: In this paper, the synthesis of mesoporous inorganic solids from calcination of aluminosilicate gels in the presence of surfactants is described, in which the silicate material forms inorganic walls between ordered surfactant micelles.
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A new family of mesoporous molecular sieves prepared with liquid crystal templates

TL;DR: In this paper, the synthesis, characterization, and proposed mechanism of formation of a new family of silicatelaluminosilicate mesoporous molecular sieves designated as M41S is described.
Journal Article

Photoelectrochemical cells : Materials for clean energy

Michael Grätzel
- 01 Jan 2001 - 
TL;DR: In this paper, the authors look into the historical background, and present status and development prospects for photoelectrochemical cells, based on nanocrystalline materials and conducting polymer films.
Journal ArticleDOI

A Theory of Sensitized Luminescence in Solids

TL;DR: In this article, the resonance theory of Forster, which involves only allowed transitions, is extended to include transfer by means of forbidden transitions which, it is concluded, are responsible for the transfer in all inorganic systems yet investigated.
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