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Hybrid materials based on lanthanide organic complexes: a review

Jing Feng, +1 more
- 07 Jan 2013 - 
- Vol. 42, Iss: 1, pp 387-410
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TLDR
This critical review begins with a formulation of the fundamentals of lanthanide organic complex luminescence, and presents various current designed ideas, synthetic routes, luminescent behaviors and potentials of the latest advanced organic-inorganic hybrid materials.
Abstract
A great deal of research has been carried out on lanthanide organic complex-based organic-inorganic hybrid materials in the last decade. This critical review begins with a formulation of the fundamentals of lanthanide organic complex luminescence, and presents various current designed ideas, synthetic routes, luminescence behaviors and potentials of the latest advanced (a) sol-gel materials, (b) mesoporous materials, (c) titania materials, (d) ionic liquids and ionogels, (e) polymers, and (f) bifunctional magnetic-optical composites based on lanthanide organic complexes. Finally, challenges and opportunities for further improvement of organic-inorganic hybrid luminescent materials based on lanthanide organic complexes will be discussed.

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Citations
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Fluorescence properties of microcomposites europium triethylene glycol picrate complex doped in polymer

TL;DR: In this article, a ternary europium-picratetriethylene glycol (Eu-EO3-Pic) complex was doped in poly(methyl methacrylate), PMMA and the composites were impregnated in several matrices to form thin films via spin coating technique.
Journal ArticleDOI

The anisotropic properties of a terbium-based liquid crystal complex

TL;DR: In this article, the influence of the central ion on dielectric properties of nematic lanthanidomesogens, and in particular on the magnitude and the sign of dielectoric anisotropy, was investigated.
Journal ArticleDOI

First example of PMMA-supported and highly luminous color-purity red-light metallopolymer based on a tris-β-diketonate Zn2 +-Eu3 +-complex

TL;DR: In this article, the first example of PMMA-supported and highly luminous red-light metallopolymer poly(MMA- co -2 ) based on a tris-β-diketonate Zn 2 + -Eu 3 + -complex is obtained.
Journal ArticleDOI

Effect of 1-(9-Ethyl-9H-carbazol-3-yl)-4,4,4-trifluorobutane-1,3-dione on Properties of Luminescent Europium (III) Complexes

TL;DR: In this paper, the effect of β-diketone ligands containing carbazole group on luminescent europium (III) complexes was investigated and the results showed amorphous nature, glass transition temperatures and luminescence intensity can be improved by 1-(9-ethyl-9H-carbazol-3-yl)-4,4, 4,4-4-trifluorobutane-1,3-dione, at the same time their thermal decomposition temperatures have seldom effected by it.
References
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Journal ArticleDOI

Ordered mesoporous molecular sieves synthesized by a liquid-crystal template mechanism

TL;DR: In this paper, the synthesis of mesoporous inorganic solids from calcination of aluminosilicate gels in the presence of surfactants is described, in which the silicate material forms inorganic walls between ordered surfactant micelles.
Journal ArticleDOI

A new family of mesoporous molecular sieves prepared with liquid crystal templates

TL;DR: In this paper, the synthesis, characterization, and proposed mechanism of formation of a new family of silicatelaluminosilicate mesoporous molecular sieves designated as M41S is described.
Journal Article

Photoelectrochemical cells : Materials for clean energy

Michael Grätzel
- 01 Jan 2001 - 
TL;DR: In this paper, the authors look into the historical background, and present status and development prospects for photoelectrochemical cells, based on nanocrystalline materials and conducting polymer films.
Journal ArticleDOI

A Theory of Sensitized Luminescence in Solids

TL;DR: In this article, the resonance theory of Forster, which involves only allowed transitions, is extended to include transfer by means of forbidden transitions which, it is concluded, are responsible for the transfer in all inorganic systems yet investigated.
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