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Journal ArticleDOI

Hybrid materials based on lanthanide organic complexes: a review

Jing Feng, +1 more
- 07 Jan 2013 - 
- Vol. 42, Iss: 1, pp 387-410
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TLDR
This critical review begins with a formulation of the fundamentals of lanthanide organic complex luminescence, and presents various current designed ideas, synthetic routes, luminescent behaviors and potentials of the latest advanced organic-inorganic hybrid materials.
Abstract
A great deal of research has been carried out on lanthanide organic complex-based organic-inorganic hybrid materials in the last decade. This critical review begins with a formulation of the fundamentals of lanthanide organic complex luminescence, and presents various current designed ideas, synthetic routes, luminescence behaviors and potentials of the latest advanced (a) sol-gel materials, (b) mesoporous materials, (c) titania materials, (d) ionic liquids and ionogels, (e) polymers, and (f) bifunctional magnetic-optical composites based on lanthanide organic complexes. Finally, challenges and opportunities for further improvement of organic-inorganic hybrid luminescent materials based on lanthanide organic complexes will be discussed.

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Citations
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Water‐Soluble Luminescent Hybrid Composites Consisting of Oligosilsesquioxanes and Lanthanide Complexes and their Sensing Ability for Cu2+

TL;DR: The novel water-soluble luminescent hybrid composites exhibit high thermal and photostability, and the emitted colors of the resulting hybrid composite can be finely tuned by changing the Eu(dpa)3 /Tb(3+) ratio.
Journal ArticleDOI

Dual color emitting Eu doped strontium orthosilicate phosphors synthesized by bio-template assisted ultrasound for solid state lightning and display applications.

TL;DR: The results elucidated a rapid, environmentally benign, cost-effective and convenient method for Sr2SiO4:Eu3+ synthesis and for the possible applications such as solid state lighting and display devices.
Journal ArticleDOI

Photoluminescence and cathode-luminescence of Eu3+-doped NaLnTiO4 (Ln = Gd and Y) phosphors

TL;DR: In this paper, Eu3+-activated layered perovskite ionic conductors NaYTiO4 and NaGdTiOO4 were successfully synthesized by a modified sol-gel method for applications in field emission displays (FEDs) and ultraviolet-based light-emitting diodes (LEDs).
Journal ArticleDOI

Eu3+-Based Bridged Silsesquioxanes for Transparent Luminescent Solar Concentrators

TL;DR: The sol-gel preparation of a bridged silsesquioxane containing europium(III) salts and 2-thenoyltrifluoroacetone has been achieved from a new ethane tetracarboxamide-based organosilane, and the optimized device displays an optical conversion efficiency of 12.3% in the absorbing spectral region of the active layer.
Journal ArticleDOI

Self-assembly of stable luminescent lanthanide supramolecular M4L6 cages with sensing properties toward nitroaromatics.

TL;DR: The first example of concentration-triggered helicate-to-tetrahedron transformation in supramolecular lanthanide edifices is reported, along with their highly efficient and selective luminescence sensing properties toward PA at the ppb level.
References
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TL;DR: In this paper, the synthesis of mesoporous inorganic solids from calcination of aluminosilicate gels in the presence of surfactants is described, in which the silicate material forms inorganic walls between ordered surfactant micelles.
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A new family of mesoporous molecular sieves prepared with liquid crystal templates

TL;DR: In this paper, the synthesis, characterization, and proposed mechanism of formation of a new family of silicatelaluminosilicate mesoporous molecular sieves designated as M41S is described.
Journal Article

Photoelectrochemical cells : Materials for clean energy

Michael Grätzel
- 01 Jan 2001 - 
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Journal ArticleDOI

A Theory of Sensitized Luminescence in Solids

TL;DR: In this article, the resonance theory of Forster, which involves only allowed transitions, is extended to include transfer by means of forbidden transitions which, it is concluded, are responsible for the transfer in all inorganic systems yet investigated.
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