Journal ArticleDOI
Hydrogenated TiO2 Nanotube Arrays for Supercapacitors
Reads0
Chats0
TLDR
The ability to improve the capacitive properties of TiO(2) electrode materials should open up new opportunities for high-performance supercapacitors.Abstract:
We report a new and general strategy for improving the capacitive properties of TiO2 materials for supercapacitors, involving the synthesis of hydrogenated TiO2 nanotube arrays (NTAs). The hydrogenated TiO2 (denoted as H–TiO2) were obtained by calcination of anodized TiO2 NTAs in hydrogen atmosphere in a range of temperatures between 300 to 600 °C. The H–TiO2 NTAs prepared at 400 °C yields the largest specific capacitance of 3.24 mF cm–2 at a scan rate of 100 mV s–1, which is 40 times higher than the capacitance obtained from air-annealed TiO2 NTAs at the same conditions. Importantly, H–TiO2 NTAs also show remarkable rate capability with 68% areal capacitance retained when the scan rate increase from 10 to 1000 mV s–1, as well as outstanding long-term cycling stability with only 3.1% reduction of initial specific capacitance after 10 000 cycles. The prominent electrochemical capacitive properties of H–TiO2 are attributed to the enhanced carrier density and increased density of hydroxyl group on TiO2 surfa...read more
Citations
More filters
Journal ArticleDOI
Design and Mechanisms of Asymmetric Supercapacitors.
Yuanlong Shao,Maher F. El-Kady,Jingyu Sun,Yaogang Li,Qinghong Zhang,Meifang Zhu,Hongzhi Wang,Bruce Dunn,Richard B. Kaner +8 more
TL;DR: This review looks at the essential energy-storage mechanisms and performance evaluation criteria for asymmetric supercapacitors to understand the wide-ranging research conducted in this area and highlights several key scientific challenges.
Journal ArticleDOI
Supercapacitor electrode materials: nanostructures from 0 to 3 dimensions
TL;DR: In this paper, the effect of nanostructures on the properties of supercapacitors including specific capacitance, rate capability and cycle stability is discussed, which may serve as a guideline for the next generation of super-capacitor electrode design.
Journal ArticleDOI
Synthesis of Nitrogen-Doped Porous Carbon Nanofibers as an Efficient Electrode Material for Supercapacitors
Li-Feng Chen,Xu-Dong Zhang,Hai-Wei Liang,Mingguang Kong,Qing-Fang Guan,Ping Chen,Zhen-Yu Wu,Shu-Hong Yu,Shu-Hong Yu +8 more
TL;DR: This work presents a high-capacity supercapacitor material based on the nitrogen-doped porous carbon nan ofibers synthesized by carbonization of macroscopic-scale carbonaceous nanofibers coated with polypyrrole (CNFs@polypyr role) at an appropriate temperature.
Journal ArticleDOI
Oxygen vacancies enhance pseudocapacitive charge storage properties of MoO3-x.
Hyung-Seok Kim,John B. Cook,John B. Cook,Hao Lin,Jesse S. Ko,Sarah H. Tolbert,Sarah H. Tolbert,Vidvuds Ozolins,Bruce Dunn,Bruce Dunn +9 more
TL;DR: This study underscores the potential importance of incorporating oxygen vacancies into transition metal oxides as a strategy for increasing the charge storage kinetics of redox-active materials.
Journal ArticleDOI
Construction of High-Capacitance 3D CoO@Polypyrrole Nanowire Array Electrode for Aqueous Asymmetric Supercapacitor
TL;DR: A supercapacitor electrode composed of well-aligned CoO nanowire array grown on 3D nickel foam with polypyrrole (PPy) uniformly immobilized onto or firmly anchored to each nanowires surface to boost the pseudocapacitive performance.
References
More filters
Journal ArticleDOI
Materials for electrochemical capacitors
TL;DR: This work has shown that combination of pseudo-capacitive nanomaterials, including oxides, nitrides and polymers, with the latest generation of nanostructured lithium electrodes has brought the energy density of electrochemical capacitors closer to that of batteries.
Journal ArticleDOI
Increasing Solar Absorption for Photocatalysis with Black Hydrogenated Titanium Dioxide Nanocrystals
TL;DR: It is shown that disorder-engineered TiO2 nanocrystals exhibit substantial solar-driven photocatalytic activities, including the photo-oxidation of organic molecules in water and the production of hydrogen with the use of a sacrificial reagent.
Journal ArticleDOI
Electrochemical Capacitors for Energy Management
John R. Miller,Patrice Simon +1 more
TL;DR: Electrochemical capacitors enable rapid storage and efficient delivery of electrical energy in heavy-duty applications and are being enabled by electrochemical capacitor technology.
Journal ArticleDOI
Pseudocapacitive Contributions to Electrochemical Energy Storage in TiO2 (Anatase) Nanoparticles
TL;DR: In this paper, the capacitive effects of nanostructured materials for electrochemical energy storage have been investigated over a dimensional regime where both capacitive and lithium intercalation processes contribute to the total stored charge.
Journal ArticleDOI
Charge Storage Mechanism of MnO2 Electrode Used in Aqueous Electrochemical Capacitor
TL;DR: The charge storage mechanism in MnO2 electrode, used in aqueous electrolyte, was investigated by cyclic voltammetry and X-ray photoelectron spectroscopy as discussed by the authors.