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InP Nanowire Array Solar Cells Achieving 13.8% Efficiency by Exceeding the Ray Optics Limit

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TLDR
It is reported that arrays of p-i-n InP nanowires (that switch from positive to negative doping), grown to millimeter lengths, can be optimized by varying the nanowire diameter and length of the n-doped segment, which are comparable to the best planar InP photovoltaics.
Abstract
Photovoltaics based on nanowire arrays could reduce cost and materials consumption compared with planar devices but have exhibited low efficiency of light absorption and carrier collection. We fabricated a variety of millimeter-sized arrays of p-type/intrinsic/n-type (p-i-n) doped InP nanowires and found that the nanowire diameter and the length of the top n-segment were critical for cell performance. Efficiencies up to 13.8% (comparable to the record planar InP cell) were achieved by using resonant light trapping in 180-nanometer-diameter nanowires that only covered 12% of the surface. The share of sunlight converted into photocurrent (71%) was six times the limit in a simple ray optics description. Furthermore, the highest open-circuit voltage of 0.906 volt exceeds that of its planar counterpart, despite about 30 times higher surface-to-volume ratio of the nanowire cell.

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Citations
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Journal ArticleDOI

Controlling the polarity of metalorganic vapor phase epitaxy-grown GaP on Si(111) for subsequent III-V nanowire growth

TL;DR: In this article, the authors obtained vertical GaAs nanowire growth on heteroepitaxial GaP with (1×1) surface reconstruction only, in agreement with growth experiments on homoenitaxially grown GaP(111).
Journal ArticleDOI

Current injection to free-standing III-N nanowires by bipolar diffusion

TL;DR: In this paper, the authors show that with bipolar diffusion injection, injection efficiencies exceeding 80% are feasible even for unoptimized free-standing nanowire structures at current densities up to 100 cm2, with a maximum injection efficiency of approximately 95% at 0.1 cm2.
Journal ArticleDOI

Numerical analysis of InP based high efficiency radial junction nanowire solar cell

TL;DR: In this article, a high performance radial junction III-V nanowire solar cells (NWSC) was proposed, consisting of p-InP NW coated by Ta2O5 and ITO, and simulate it using Lumerical software.
Journal ArticleDOI

Measurement of strain in InGaN/GaN nanowires and nanopyramids

TL;DR: In this paper, X-ray diffraction data are presented that show that InGa1-N shells grown on GaN cores are strained along each of the facets independently, corresponding to different parts of the shell being strained along individual facet planes.
Journal ArticleDOI

Absorption of light in a single vertical nanowire and a nanowire array

TL;DR: Electromagnetic modeling of InP nanowires shows that a single nanowire can show at an absorption peak, a remarkably high absorption cross- section that is more than 50 times the geometrical cross-section, and shows analytically the coupling efficiency of incident light into the fundamental HE11 guided mode and consecutive absorption of the mode in the Nanowires.
References
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Journal ArticleDOI

A low-cost, high-efficiency solar cell based on dye-sensitized colloidal TiO2 films

TL;DR: In this article, the authors describe a photovoltaic cell, created from low-to medium-purity materials through low-cost processes, which exhibits a commercially realistic energy-conversion efficiency.
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Porphyrin-Sensitized Solar Cells with Cobalt (II/III)–Based Redox Electrolyte Exceed 12 Percent Efficiency

TL;DR: In this article, a Co(II/III)tris(bipyridyl)-based redox electrolyte was used in conjunction with a custom synthesized donor-π-bridge-acceptor zinc porphyrin dye as sensitizer (designated YD2-o-C8).
Journal Article

Porphyrin-sensitized solar cells with cobalt (II/III)-based redox electrolyte exceed 12 percent efficiency (vol 334, pg 629, 2011)

TL;DR: Mesoscopic solar cells that incorporate a Co(II/III)tris(bipyridyl)–based redox electrolyte in conjunction with a custom synthesized donor-π-bridge-acceptor zinc porphyrin dye as sensitizer are reported, enabling attainment of strikingly high photovoltages approaching 1 volt.
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Hybrid Nanorod-Polymer Solar Cells

TL;DR: It is demonstrated that semiconductor nanorods can be used to fabricate readily processed and efficient hybrid solar cells together with polymers and Tuning the band gap by altering the nanorod radius enabled us to optimize the overlap between the absorption spectrum of the cell and the solar emission spectrum.
Journal ArticleDOI

Light Trapping in Silicon Nanowire Solar Cells

TL;DR: It is demonstrated that ordered arrays of silicon nanowires increase the path length of incident solar radiation by up to a factor of 73, which is above the randomized scattering (Lambertian) limit and is superior to other light-trapping methods.
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