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Journal ArticleDOI

Ionic-liquid materials for the electrochemical challenges of the future.

TLDR
The goal in this review is to survey the recent key developments and issues within ionic-liquid research in these areas, and to generate interest in the wider community and encourage others to make use of ionic liquids in tackling scientific challenges.
Abstract
Ionic liquids are room-temperature molten salts, composed mostly of organic ions that may undergo almost unlimited structural variations. This review covers the newest aspects of ionic liquids in applications where their ion conductivity is exploited; as electrochemical solvents for metal/semiconductor electrodeposition, and as batteries and fuel cells where conventional media, organic solvents (in batteries) or water (in polymer-electrolyte-membrane fuel cells), fail. Biology and biomimetic processes in ionic liquids are also discussed. In these decidedly different materials, some enzymes show activity that is not exhibited in more traditional systems, creating huge potential for bioinspired catalysis and biofuel cells. Our goal in this review is to survey the recent key developments and issues within ionic-liquid research in these areas. As well as informing materials scientists, we hope to generate interest in the wider community and encourage others to make use of ionic liquids in tackling scientific challenges.

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Citations
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Journal ArticleDOI

Aluminum–air battery based on an ionic liquid electrolyte

TL;DR: In this paper, a non-aqueous Al-air battery is presented, which utilizes 1-ethyl-3-methylimidazolium oligo-fluoro-hydrogenate (EMIm(HF)23F) room temperature ionic liquid (RTIL) for energy storage.
Journal ArticleDOI

The Synergistic Effect of Cation and Anion of an Ionic Liquid Additive for Lithium Metal Anodes

TL;DR: In this article, Li metal anodes are steadily gaining more attention, as their superior specific capacities and low redox voltage can significantly increase the energy density of rechargeable batteries far beyond those of current Li-ion batteries.
Journal ArticleDOI

Lithium bis(fluorosulfonyl)imide–PYR14TFSI ionic liquid electrolyte compatible with graphite

TL;DR: In this article, the formation of SEI in different electrolytes was the subject of study using impedance spectroscopy on symmetrical cells containing two lithium electrodes, and the 0.7m LiFSI in PYR14TFSI exhibits a good ionic conductivity along with high electrochemical stability and high thermal stability.
Journal ArticleDOI

New Class of Type III Porous Liquids: A Promising Platform for Rational Adjustment of Gas Sorption Behavior.

TL;DR: Compared to common porous solid materials, as-synthesized porous liquids exhibited pronounced hysteresis loops in the CO2 sorption isotherms even at ambient conditions (298 K, 1 bar).
Journal ArticleDOI

Application of In Operando UV/Vis Spectroscopy in Lithium–Sulfur Batteries

Manu U. M. Patel, +1 more
- 01 Aug 2014 - 
TL;DR: Recalculation of normalized reflections of UV/Vis spectra obtained in operando mode enable the formation of polysulfides and their concentrations to be followed and it is possible to distinguish differences in the mechanism ofpolysulfide shuttling between two electrolytes and to correlate differences in capacity fading.
References
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Journal ArticleDOI

Building better batteries

TL;DR: Researchers must find a sustainable way of providing the power their modern lifestyles demand to ensure the continued existence of clean energy sources.
Journal ArticleDOI

Materials for electrochemical capacitors

TL;DR: This work has shown that combination of pseudo-capacitive nanomaterials, including oxides, nitrides and polymers, with the latest generation of nanostructured lithium electrodes has brought the energy density of electrochemical capacitors closer to that of batteries.
Journal ArticleDOI

Dissolution of Cellose with Ionic Liquids

TL;DR: In this paper, the authors demonstrate that cellulose can be dissolved without activation or pretreatment in, and regenerated from, 1-butyl-3-methylimidazolium chloride and other hydrophilic ionic liquids.
Book

Ionic Liquids in Synthesis

TL;DR: The early years of Ionic liquid production were covered in this article, where a new generation of soluble supports for Supported Organic Synthesis (SPOS) was proposed. But this support was not applied to the task-specific Ionic liquids.
Book

Handbook of fuel cells : fundamentals technology and applications

TL;DR: In this article, the authors present a survey of fuel cell technologies and applications, focusing on hydrogen storage, hydrogen generation, and other energy conversion related topics, as well as their applications.
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