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Journal ArticleDOI

Ionic-liquid materials for the electrochemical challenges of the future.

TLDR
The goal in this review is to survey the recent key developments and issues within ionic-liquid research in these areas, and to generate interest in the wider community and encourage others to make use of ionic liquids in tackling scientific challenges.
Abstract
Ionic liquids are room-temperature molten salts, composed mostly of organic ions that may undergo almost unlimited structural variations. This review covers the newest aspects of ionic liquids in applications where their ion conductivity is exploited; as electrochemical solvents for metal/semiconductor electrodeposition, and as batteries and fuel cells where conventional media, organic solvents (in batteries) or water (in polymer-electrolyte-membrane fuel cells), fail. Biology and biomimetic processes in ionic liquids are also discussed. In these decidedly different materials, some enzymes show activity that is not exhibited in more traditional systems, creating huge potential for bioinspired catalysis and biofuel cells. Our goal in this review is to survey the recent key developments and issues within ionic-liquid research in these areas. As well as informing materials scientists, we hope to generate interest in the wider community and encourage others to make use of ionic liquids in tackling scientific challenges.

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Citations
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Journal ArticleDOI

Dual Ionic and Organic Nature of Ionic Liquids.

TL;DR: It is revealed that the depth of the cage energy landscape characterizes the ionic nature ofILs, whereas the slope and curvature of its mimimum determine the organic nature of ILs.
Journal ArticleDOI

Boosting interfacial Li+ transport with a MOF-based ionic conductor for solid-state batteries

TL;DR: In this article, an assistant ionic conductor is introduced to improve the interfacial Li+ transport of SSBs by impregnating an ionic liquid (Li-IL) into a porous metal-organic framework (MOF) host.
Journal ArticleDOI

General Synthetic Route toward Highly Dispersed Metal Clusters Enabled by Poly(ionic liquid)s

TL;DR: In this paper, a capping agent from a polytriazolium poly(ionic liquid) (PIL) in a vesicular form in solution was proposed for crafting a broad spectrum of metal clusters (MCs) with their size controllable on a subnanometer scale.
Journal ArticleDOI

Preparation and characterization of gel polymer electrolytes using poly(ionic liquids) and high lithium salt concentration ionic liquids

TL;DR: In this paper, a novel GPE based on a polyIL, poly(diallyldimethylammonium) bis(trifluoromethanesulfonyl)imide (PDADMA TFSI) and a high lithium-concentration phosphonium ionic liquid, trimethyl(isobutyl)phosphonium bis(fluorosulfonyls)imides (P111i4FSI), is prepared.
Journal ArticleDOI

Design of functional ionic liquids using magneto- and luminescent-active anions

TL;DR: The component ions used so far include both inorganic and organic types; and various strategies, namely not only the proper choice but also the synthesis of anions to impart the functionality are presented.
References
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Journal ArticleDOI

Building better batteries

TL;DR: Researchers must find a sustainable way of providing the power their modern lifestyles demand to ensure the continued existence of clean energy sources.
Journal ArticleDOI

Materials for electrochemical capacitors

TL;DR: This work has shown that combination of pseudo-capacitive nanomaterials, including oxides, nitrides and polymers, with the latest generation of nanostructured lithium electrodes has brought the energy density of electrochemical capacitors closer to that of batteries.
Journal ArticleDOI

Dissolution of Cellose with Ionic Liquids

TL;DR: In this paper, the authors demonstrate that cellulose can be dissolved without activation or pretreatment in, and regenerated from, 1-butyl-3-methylimidazolium chloride and other hydrophilic ionic liquids.
Book

Ionic Liquids in Synthesis

TL;DR: The early years of Ionic liquid production were covered in this article, where a new generation of soluble supports for Supported Organic Synthesis (SPOS) was proposed. But this support was not applied to the task-specific Ionic liquids.
Book

Handbook of fuel cells : fundamentals technology and applications

TL;DR: In this article, the authors present a survey of fuel cell technologies and applications, focusing on hydrogen storage, hydrogen generation, and other energy conversion related topics, as well as their applications.
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