scispace - formally typeset
Journal ArticleDOI

Ionic-liquid materials for the electrochemical challenges of the future.

TLDR
The goal in this review is to survey the recent key developments and issues within ionic-liquid research in these areas, and to generate interest in the wider community and encourage others to make use of ionic liquids in tackling scientific challenges.
Abstract
Ionic liquids are room-temperature molten salts, composed mostly of organic ions that may undergo almost unlimited structural variations. This review covers the newest aspects of ionic liquids in applications where their ion conductivity is exploited; as electrochemical solvents for metal/semiconductor electrodeposition, and as batteries and fuel cells where conventional media, organic solvents (in batteries) or water (in polymer-electrolyte-membrane fuel cells), fail. Biology and biomimetic processes in ionic liquids are also discussed. In these decidedly different materials, some enzymes show activity that is not exhibited in more traditional systems, creating huge potential for bioinspired catalysis and biofuel cells. Our goal in this review is to survey the recent key developments and issues within ionic-liquid research in these areas. As well as informing materials scientists, we hope to generate interest in the wider community and encourage others to make use of ionic liquids in tackling scientific challenges.

read more

Citations
More filters
Journal ArticleDOI

Direct determination of ionic transference numbers in ionic liquids by electrophoretic NMR

TL;DR: The ionic transference number, i.e. the fractional contribution of an ionic species to overall conductivity, strongly depends on cation and anion structure and its values show that structurally very similar ionic liquids can have cation- or anion-dominated conductivity.
Journal ArticleDOI

Novel pyrrolidinium-based polymeric ionic liquids with cyano counter-anions: High performance membrane materials for post-combustion CO2 separation

TL;DR: In this paper, pyrrolidinium-based polymers containing different cyano-functionalized counter-anions were synthesized by straightforward anion exchange reactions and characterized.
Journal ArticleDOI

One‐Step Synthesis of Thermosensitive Nanogels Based on Highly Cross‐Linked Poly(ionic liquid)s

TL;DR: A gel for all seasons: Thermosensitive nanogels based on highly cross-linked poly(ionic liquid)s (CLPNs) were prepared in one step by the copolymerization of imidazolium-based monomers with cross-linkers in selective solvents.
Journal ArticleDOI

Supercapacitor Operating At 200 Degrees Celsius

TL;DR: Composite electrolyte/separator structures made from naturally occurring clay and room temperature ionic liquids, with graphitic carbon electrodes, show stable supercapacitor performance at 200°C with good cyclic stability.
Journal ArticleDOI

Equation of state modelling of systems with ionic liquids: Literature review and application with the Cubic Plus Association (CPA) model

TL;DR: In this article, a review of literature studies on modelling systems with ionic liquids using equation of state models is made, and the results for VLE proved to be very good in the range of pressures studied when using one temperature-independent binary interaction parameter, with percentage deviations in pressure between 8 and 13% for [C 2 mim][NTf 2 ] and around 12% for the liquid-liquid equilibria with water.
References
More filters
Journal ArticleDOI

Building better batteries

TL;DR: Researchers must find a sustainable way of providing the power their modern lifestyles demand to ensure the continued existence of clean energy sources.
Journal ArticleDOI

Materials for electrochemical capacitors

TL;DR: This work has shown that combination of pseudo-capacitive nanomaterials, including oxides, nitrides and polymers, with the latest generation of nanostructured lithium electrodes has brought the energy density of electrochemical capacitors closer to that of batteries.
Journal ArticleDOI

Dissolution of Cellose with Ionic Liquids

TL;DR: In this paper, the authors demonstrate that cellulose can be dissolved without activation or pretreatment in, and regenerated from, 1-butyl-3-methylimidazolium chloride and other hydrophilic ionic liquids.
Book

Ionic Liquids in Synthesis

TL;DR: The early years of Ionic liquid production were covered in this article, where a new generation of soluble supports for Supported Organic Synthesis (SPOS) was proposed. But this support was not applied to the task-specific Ionic liquids.
Book

Handbook of fuel cells : fundamentals technology and applications

TL;DR: In this article, the authors present a survey of fuel cell technologies and applications, focusing on hydrogen storage, hydrogen generation, and other energy conversion related topics, as well as their applications.
Related Papers (5)