scispace - formally typeset
Journal ArticleDOI

Ionic-liquid materials for the electrochemical challenges of the future.

TLDR
The goal in this review is to survey the recent key developments and issues within ionic-liquid research in these areas, and to generate interest in the wider community and encourage others to make use of ionic liquids in tackling scientific challenges.
Abstract
Ionic liquids are room-temperature molten salts, composed mostly of organic ions that may undergo almost unlimited structural variations. This review covers the newest aspects of ionic liquids in applications where their ion conductivity is exploited; as electrochemical solvents for metal/semiconductor electrodeposition, and as batteries and fuel cells where conventional media, organic solvents (in batteries) or water (in polymer-electrolyte-membrane fuel cells), fail. Biology and biomimetic processes in ionic liquids are also discussed. In these decidedly different materials, some enzymes show activity that is not exhibited in more traditional systems, creating huge potential for bioinspired catalysis and biofuel cells. Our goal in this review is to survey the recent key developments and issues within ionic-liquid research in these areas. As well as informing materials scientists, we hope to generate interest in the wider community and encourage others to make use of ionic liquids in tackling scientific challenges.

read more

Citations
More filters
Journal ArticleDOI

Structural Motifs in Cold Ternary Ion Complexes of Hydroxyl-Functionalized Ionic Liquids: Isolating the Role of Cation-Cation Interactions.

TL;DR: This work addresses the competition between intermolecular forces underlying the recent observation that ionic liquids (ILs) with a hydroxyl-functionalized cation can form domains with attractive interactions between the nominally repulsive positively charged constituents.
Journal ArticleDOI

Dye-sensitized solar cells using ionic liquids as redox mediator

TL;DR: In this article, the influence of ionic liquid on the conversion efficiency, incident photons to converted electrons (IPCE) and performance of fabricated solar cell was investigated using various ionic liquids.
Journal ArticleDOI

Fabrication and characterization of phosphoric acid doped imidazolium ionic liquid polymer composite membranes

TL;DR: In this article, composite membranes based on polymers of sulfonated poly (ether ether) ketone (SPEEK) or polyvinylidenefluoride (PVDF) composite membranes were fabricated using the approach of immersing the membranes into pure phosphoric acid at room temperature.
Journal ArticleDOI

Electrochemical properties of a poly(ethylene carbonate)-LiTFSI electrolyte containing a pyrrolidinium-based ionic liquid

TL;DR: In this article, a novel polymer electrolyte membrane comprising poly(ethylene carbonate) (PEC), lithium bis(trifluoromethanesulfonyl)imide (LiTFSI) salt, and N-n-butyl-N-methylpyrrolidinium (Pyr14TFSI), was prepared by a solvent-free procedure, combining annealing and hot-pressing.
References
More filters
Journal ArticleDOI

Building better batteries

TL;DR: Researchers must find a sustainable way of providing the power their modern lifestyles demand to ensure the continued existence of clean energy sources.
Journal ArticleDOI

Materials for electrochemical capacitors

TL;DR: This work has shown that combination of pseudo-capacitive nanomaterials, including oxides, nitrides and polymers, with the latest generation of nanostructured lithium electrodes has brought the energy density of electrochemical capacitors closer to that of batteries.
Journal ArticleDOI

Dissolution of Cellose with Ionic Liquids

TL;DR: In this paper, the authors demonstrate that cellulose can be dissolved without activation or pretreatment in, and regenerated from, 1-butyl-3-methylimidazolium chloride and other hydrophilic ionic liquids.
Book

Ionic Liquids in Synthesis

TL;DR: The early years of Ionic liquid production were covered in this article, where a new generation of soluble supports for Supported Organic Synthesis (SPOS) was proposed. But this support was not applied to the task-specific Ionic liquids.
Book

Handbook of fuel cells : fundamentals technology and applications

TL;DR: In this article, the authors present a survey of fuel cell technologies and applications, focusing on hydrogen storage, hydrogen generation, and other energy conversion related topics, as well as their applications.
Related Papers (5)