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Journal ArticleDOI

Ionic-liquid materials for the electrochemical challenges of the future.

TLDR
The goal in this review is to survey the recent key developments and issues within ionic-liquid research in these areas, and to generate interest in the wider community and encourage others to make use of ionic liquids in tackling scientific challenges.
Abstract
Ionic liquids are room-temperature molten salts, composed mostly of organic ions that may undergo almost unlimited structural variations. This review covers the newest aspects of ionic liquids in applications where their ion conductivity is exploited; as electrochemical solvents for metal/semiconductor electrodeposition, and as batteries and fuel cells where conventional media, organic solvents (in batteries) or water (in polymer-electrolyte-membrane fuel cells), fail. Biology and biomimetic processes in ionic liquids are also discussed. In these decidedly different materials, some enzymes show activity that is not exhibited in more traditional systems, creating huge potential for bioinspired catalysis and biofuel cells. Our goal in this review is to survey the recent key developments and issues within ionic-liquid research in these areas. As well as informing materials scientists, we hope to generate interest in the wider community and encourage others to make use of ionic liquids in tackling scientific challenges.

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Citations
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Journal ArticleDOI

Mixed Ionic Liquid Improves Electrolyte Dynamics in Supercapacitors

TL;DR: In this article, the authors explore two room-temperature ionic liquids, 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide (EmimTFSI) and 1-methyl-3methyloride-drugs tetrafluoroborate(EmimBF4), as binary mixtures on the external surfaces of onion-like carbon electrodes using quasielastic neutron scattering and classical density functional theory techniques.
Journal ArticleDOI

Devulcanization of styrene butadiene rubber by microwave energy: Effect of the presence of ionic liquid

TL;DR: In this paper, styrene butadiene rubber (SBR) was devulcanized using microwave irradiation and the effect of ionic liquid (IL), pyrrolidinium hydrogen sulfate [Pyrr][HSO4] on the performance was studied.
Journal ArticleDOI

AIE-doped poly(ionic liquid) photonic spheres: a single sphere-based customizable sensing platform for the discrimination of multi-analytes

TL;DR: In this article, a novel customizable sensing system for multi-analytes was developed based on a single AIE-doped poly(ionic liquid) photonic sphere, which can differentially interact with broader classes of analytes, thus generating response patterns with remarkable diversity.
Journal ArticleDOI

Extraordinary Supercapacitor Performance of a Multicomponent and Mixed‐Valence Oxyhydroxide

TL;DR: A novel multicomponent mixed-valence oxyhydroxide-based electrode synthesized by electrochemical polarization of a de-alloyed nanoporous NiCuMn alloy possesses an extraordinarily wide working-potential window of 1.8 V in an aqueous electrolyte, which far exceeds the theoretically stable window of water.
Journal ArticleDOI

Organic–inorganic hybrid electrolytes from ionic liquid-functionalized octasilsesquioxane for lithium metal batteries

TL;DR: In this paper, the authors report the synthesis and characterization of a new class of nonflammable solid electrolytes based on the grafting of ionic liquids onto octa-silsesquioxane.
References
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Journal ArticleDOI

Building better batteries

TL;DR: Researchers must find a sustainable way of providing the power their modern lifestyles demand to ensure the continued existence of clean energy sources.
Journal ArticleDOI

Materials for electrochemical capacitors

TL;DR: This work has shown that combination of pseudo-capacitive nanomaterials, including oxides, nitrides and polymers, with the latest generation of nanostructured lithium electrodes has brought the energy density of electrochemical capacitors closer to that of batteries.
Journal ArticleDOI

Dissolution of Cellose with Ionic Liquids

TL;DR: In this paper, the authors demonstrate that cellulose can be dissolved without activation or pretreatment in, and regenerated from, 1-butyl-3-methylimidazolium chloride and other hydrophilic ionic liquids.
Book

Ionic Liquids in Synthesis

TL;DR: The early years of Ionic liquid production were covered in this article, where a new generation of soluble supports for Supported Organic Synthesis (SPOS) was proposed. But this support was not applied to the task-specific Ionic liquids.
Book

Handbook of fuel cells : fundamentals technology and applications

TL;DR: In this article, the authors present a survey of fuel cell technologies and applications, focusing on hydrogen storage, hydrogen generation, and other energy conversion related topics, as well as their applications.
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