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Journal ArticleDOI

Liquid electrolyte lithium/sulfur battery: Fundamental chemistry, problems, and solutions

Sheng S. Zhang
- 01 Jun 2013 - 
- Vol. 231, Iss: 231, pp 153-162
TLDR
Li et al. as discussed by the authors discussed the problems and solutions of liquid electrolyte Li/S battery and showed that the dissolution of lithium polysulfide (PS) is essential for the performance of a Li-S cell.
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This article is published in Journal of Power Sources.The article was published on 2013-06-01. It has received 1348 citations till now. The article focuses on the topics: Lithium–sulfur battery & Electrolyte.

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Citations
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A reduced graphene oxide/nitrogen, phosphorus doped porous carbon hybrid framework as sulfur host for high performance lithium-sulfur batteries

TL;DR: In this article, a N, P dual-doped 3D hierarchical porous hybrid carbon is successfully prepared for advanced Li-S batteries based on the combination of reduced graphene oxide (rGO) and goat hair derived biomass carbon by a simple one-pot pyrolysis process.
Journal ArticleDOI

Rechargeable metal (Li, Na, Mg, Al)-sulfur batteries: Materials and advances

TL;DR: In this paper, a review on the advances of metal-sulfur batteries from the point of view of materials, and then focus on perspectives of their future developments has been demonstrated, and the selections of suitable electrolytes, anode protection, separator modifications and prototype innovations are discussed at the same time.
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Towards Stable Lithium-Sulfur Batteries with a Low Self-Discharge Rate: Ion Diffusion Modulation and Anode Protection.

TL;DR: It is expected that lithium-sulfur batteries with ultralow self-discharge rates may be fabricated through a combination of anode passivation and polysulfide shuttle control, as well as optimization of the lithium-Sulfur cell configuration.
Journal ArticleDOI

Promising Cell Configuration for Next-Generation Energy Storage: Li2S/Graphite Battery Enabled by a Solvate Ionic Liquid Electrolyte.

TL;DR: Simple graphite-based Li-S full cells were fabricated employing electrolytes beyond the conventional carbonates, in combination with highly loaded Li2S/graphene composite cathodes (Li2S loading: 2.2 mg/cm(2), which show a stable and reversible charge-discharge behavior, along with a very high Coulombic efficiency.
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Pseudo-binary electrolyte, LiBH4-LiCl, for bulk-type all-solid-state lithium-sulfur battery.

TL;DR: The results imply that complex hydride-based solid-state electrolytes that contain Cl-ions in the crystal would be integrated into rechargeable batteries.
References
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Book

Chemistry of the elements

TL;DR: In this article, the origins of the elements, isotopes and atomic weights Chemical periodicity and the periodic table were discussed, including the following elements: Hydrogen Lithium, sodium, potassium, rubidium, caesium and francium Beryllium, magnesium, calcium, strontium, barium and radium Boron Aluminium, gallium, indium and thallium Carbon Silicon Germanium, tin and lead Nitrogen Phosphorus Arsenic, antimony and bismuth Oxygen Sulfur Selenium, tellurium
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A highly ordered nanostructured carbon–sulphur cathode for lithium–sulphur batteries

TL;DR: In this paper, the authors report the feasibility to approach such capacities by creating highly ordered interwoven composites, where conductive mesoporous carbon framework precisely constrains sulphur nanofiller growth within its channels and generates essential electrical contact to the insulating sulphur.
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Graphene-Wrapped Sulfur Particles as a Rechargeable Lithium–Sulfur Battery Cathode Material with High Capacity and Cycling Stability

TL;DR: In this article, the synthesis of a graphene-sulfur composite material by wrapping poly(ethylene glycol) (PEG) coated submicrometer sulfur particles with mildly oxidized graphene oxide sheets decorated by carbon black nanoparticles was reported.
Journal ArticleDOI

Porous Hollow Carbon@Sulfur Composites for High‐Power Lithium–Sulfur Batteries

TL;DR: C @ S nanocomposites based on mesoporous hollow carbon capsules were prepared by a template approach as mentioned in this paper, and their excellent properties as a cathode material in a lithium secondary battery of S-sequestration of elemental sulfur in the carbon capsules, a restricted polysulfide shuttling and an improved electron transport on sulfur are attributed.
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A review on electrolyte additives for lithium-ion batteries

TL;DR: In this article, a review of electrolyte additives used in Li-ion batteries is presented, which can be classified into five categories: solid electrolyte interface (SEI) forming improver, cathode protection agent, LiPF 6 salt stabilizer, safety protection agent and Li deposition improver.
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