Reticular synthesis and the design of new materials
Omar M. Yaghi,Michael O'Keeffe,Nathan W. Ockwig,Hee K. Chae,Hee K. Chae,Mohamed Eddaoudi,Jaheon Kim +6 more
TLDR
This work has shown that highly porous frameworks held together by strong metal–oxygen–carbon bonds and with exceptionally large surface area and capacity for gas storage have been prepared and their pore metrics systematically varied and functionalized.Abstract:
The long-standing challenge of designing and constructing new crystalline solid-state materials from molecular building blocks is just beginning to be addressed with success. A conceptual approach that requires the use of secondary building units to direct the assembly of ordered frameworks epitomizes this process: we call this approach reticular synthesis. This chemistry has yielded materials designed to have predetermined structures, compositions and properties. In particular, highly porous frameworks held together by strong metal-oxygen-carbon bonds and with exceptionally large surface area and capacity for gas storage have been prepared and their pore metrics systematically varied and functionalized.read more
Citations
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Hierarchically Nanostructured Coordination Polymer: Facile and Rapid Fabrication and Tunable Morphologies
Kai Liu,Hongpeng You,Guang Jia,Yuhua Zheng,Yeju Huang,Yanhua Song,Mei Yang,Lihui Zhang,Hongjie Zhang +8 more
TL;DR: In this article, hierarchical nanostructured coordination polymer Ce(1,3,5-BTC)(H2O)6 architectures with tunable morphologies were successfully prepared on a large scale via a simple and rapid solution phase method at room temperature.
Journal ArticleDOI
A Covalent Organic Framework with 4 nm open pores.
TL;DR: The synthesis and characterization of a new mesoporous Covalent Organic Framework BTP-COF is described, the latter having fully accessible pores with an open diameter of 4.0 nm.
Journal ArticleDOI
Energy-based descriptors to rapidly predict hydrogen storage in metal–organic frameworks
Benjamin J. Bucior,N. Scott Bobbitt,Timur Islamoglu,Subhadip Goswami,Arun Gopalan,Taner Yildirim,Omar K. Farha,Neda Bagheri,Randall Q. Snurr +8 more
TL;DR: In this article, a data-driven approach was developed to accelerate materials screening and learn structure-property relationships, and new descriptors for gas adsorption in metal-organic frameworks (MOFs) derived from the energetics of MOF-guest interactions.
Journal ArticleDOI
Hydrothermal synthesis and crystal structure of a new three-dimensional aluminum-organic framework MIL-69 with 2,6-naphthalenedicarboxylate (ndc), Al(OH)(ndc)·H2O
Thierry Loiseau,Caroline Mellot-Draznieks,Hervé Muguerra,Gérard Férey,Mohamed Haouas,Francis Taulelle +5 more
TL;DR: Loiseau et al. as discussed by the authors used 2,6-naphthalenedicarboxylic acid as a rigid ligand to synthesize a new three-dimensional aluminum-organic framework, MIL-69 or Al(OH)2 octahedra corner-linked through the μ2-hydroxyl groups.
References
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Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage
Mohamed Eddaoudi,Jaheon Kim,Nathaniel L. Rosi,David T. Vodak,Joseph Wachter,Michael O'Keeffe,Omar M. Yaghi +6 more
TL;DR: Metal-organic framework (MOF-5), a prototype of a new class of porous materials and one that is constructed from octahedral Zn-O-C clusters and benzene links, was used to demonstrate that its three-dimensional porous system can be functionalized with the organic groups and can be expanded with the long molecular struts biphenyl, tetrahydropyrene, pyrene, and terphenyl.
Journal ArticleDOI
Design and synthesis of an exceptionally stable and highly porous metal-organic framework
TL;DR: In this article, an organic dicarboxylate linker is used in a reaction that gives supertetrahedron clusters when capped with monocarboxyates.