Reticular synthesis and the design of new materials
Omar M. Yaghi,Michael O'Keeffe,Nathan W. Ockwig,Hee K. Chae,Hee K. Chae,Mohamed Eddaoudi,Jaheon Kim +6 more
TLDR
This work has shown that highly porous frameworks held together by strong metal–oxygen–carbon bonds and with exceptionally large surface area and capacity for gas storage have been prepared and their pore metrics systematically varied and functionalized.Abstract:
The long-standing challenge of designing and constructing new crystalline solid-state materials from molecular building blocks is just beginning to be addressed with success. A conceptual approach that requires the use of secondary building units to direct the assembly of ordered frameworks epitomizes this process: we call this approach reticular synthesis. This chemistry has yielded materials designed to have predetermined structures, compositions and properties. In particular, highly porous frameworks held together by strong metal-oxygen-carbon bonds and with exceptionally large surface area and capacity for gas storage have been prepared and their pore metrics systematically varied and functionalized.read more
Citations
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Enhanced selectivity of CO2 over CH4 in sulphonate-, carboxylate- and iodo-functionalized UiO-66 frameworks
Shyam Biswas,Jian Zhang,Li Zhibao,Ying-Ya Liu,Maciej Grzywa,Lixian Sun,Lixian Sun,Dirk Volkmer,Pascal Van Der Voort +8 more
TL;DR: Three new functionalized UiO-66-X frameworks incorporating BDC-X (BDC: 1,4-benzenedicarboxylate) linkers have been synthesized by a solvothermal method using conventional electric heating.
Journal ArticleDOI
4-connected metal-organic assemblies mediated via heterochelation and bridging of single metal ions : Kagome lattice and the M6L12 octahedron
TL;DR: Single-metal-ion-based rigid molecular building blocks have been utilized to design and synthesize novel metal-organic assemblies and have permitted the assembly of two supramolecular isomers, a Kagomé lattice and an unprecedented M6L12 discrete octahedron.
Journal ArticleDOI
Hierarchically mesostructured MIL-101 metal–organic frameworks: supramolecular template-directed synthesis and accelerated adsorption kinetics for dye removal
Xiao-Xian Huang,Ling-Guang Qiu,Wang Zhang,Yupeng Yuan,Xia Jiang,Anjian Xie,Yuhua Shen,Junfa Zhu +7 more
TL;DR: Hierarchically mesostructured MIL-101 metal-organic frameworks (MOFs) were successfully synthesized under solvothermal synthesis conditions by using the cationic surfactant cetyltrimethylammonium bromide as a supramolecular template as mentioned in this paper.
Journal ArticleDOI
A Flexible Porous Coordination Polymer Functionalized by Unsaturated Metal Clusters
Journal ArticleDOI
Mechanical Gas Capture and Release in a Network Solid via Multiple Single-Crystalline Transformations
Brett D. Chandler,Gary D. Enright,Konstantin A. Udachin,Shane Pawsey,John A. Ripmeester,David T. Cramb,George K. H. Shimizu +6 more
TL;DR: An open-channel metal-organic framework that, on dehydration, shifts structure to form closed pores in the solid to represent a thermally robust and porous material that is also capable of dynamically capturing and releasing gas in a controlled manner.
References
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Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage
Mohamed Eddaoudi,Jaheon Kim,Nathaniel L. Rosi,David T. Vodak,Joseph Wachter,Michael O'Keeffe,Omar M. Yaghi +6 more
TL;DR: Metal-organic framework (MOF-5), a prototype of a new class of porous materials and one that is constructed from octahedral Zn-O-C clusters and benzene links, was used to demonstrate that its three-dimensional porous system can be functionalized with the organic groups and can be expanded with the long molecular struts biphenyl, tetrahydropyrene, pyrene, and terphenyl.
Journal ArticleDOI
Design and synthesis of an exceptionally stable and highly porous metal-organic framework
TL;DR: In this article, an organic dicarboxylate linker is used in a reaction that gives supertetrahedron clusters when capped with monocarboxyates.