Reticular synthesis and the design of new materials
Omar M. Yaghi,Michael O'Keeffe,Nathan W. Ockwig,Hee K. Chae,Hee K. Chae,Mohamed Eddaoudi,Jaheon Kim +6 more
TLDR
This work has shown that highly porous frameworks held together by strong metal–oxygen–carbon bonds and with exceptionally large surface area and capacity for gas storage have been prepared and their pore metrics systematically varied and functionalized.Abstract:
The long-standing challenge of designing and constructing new crystalline solid-state materials from molecular building blocks is just beginning to be addressed with success. A conceptual approach that requires the use of secondary building units to direct the assembly of ordered frameworks epitomizes this process: we call this approach reticular synthesis. This chemistry has yielded materials designed to have predetermined structures, compositions and properties. In particular, highly porous frameworks held together by strong metal-oxygen-carbon bonds and with exceptionally large surface area and capacity for gas storage have been prepared and their pore metrics systematically varied and functionalized.read more
Citations
More filters
Journal ArticleDOI
Versatile functionalization of the NU-1000 platform by solvent-assisted ligand incorporation
TL;DR: Solvent-assisted ligand incorporation (SALI) was utilized to efficiently insert various carboxylate-derived functionalities into the Zr-based metal-organic framework NU-1000 as charge compensating moieties strongly bound to the ZR6 nodes.
Journal ArticleDOI
Mechanistic Studies of Two-Dimensional Covalent Organic Frameworks Rapidly Polymerized from Initially Homogenous Conditions
TL;DR: 2D boronate ester-linked COF-5 is synthesized under conditions in which the monomers are fully soluble and stoichiometric H2O provides a 4-fold increase in crystallite domain areas, representing the first rational link between reaction conditions and material quality.
Journal ArticleDOI
Twelve-Connected Net with Face-Centered Cubic Topology: A Coordination Polymer Based on [Cu12(μ4-SCH3)6]6+ Clusters and CN− Linkers
Journal ArticleDOI
Ultra-Tuning of the Rare-Earth fcu-MOF Aperture Size for Selective Molecular Exclusion of Branched Paraffins
Ayalew Hussen Assen Assen,Youssef Belmabkhout,Karim Adil,Prashant M. Bhatt,Dong-Xu Xue,Hao Jiang,Mohamed Eddaoudi +6 more
TL;DR: Using isoreticular chemistry allows the design and construction of a new rare-earth metal (RE) fcu-MOF with a suitable aperture size for practical steric adsorptive separations, and the newly constructed RE (Y(3+) and Tb(3+)) fcu (3+) analogues display unprecedented total exclusion of branched paraffins from normal parAffins.
Journal ArticleDOI
Designable Yolk–Shell Nanoparticle@MOF Petalous Heterostructures
TL;DR: In this paper, the authors demonstrate the facile encapsulation of presynthesized NPs into carboxylic acid based MOFs using NPs@metal oxide core-shell nanostructures as the self-template.
References
More filters
Journal ArticleDOI
Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage
Mohamed Eddaoudi,Jaheon Kim,Nathaniel L. Rosi,David T. Vodak,Joseph Wachter,Michael O'Keeffe,Omar M. Yaghi +6 more
TL;DR: Metal-organic framework (MOF-5), a prototype of a new class of porous materials and one that is constructed from octahedral Zn-O-C clusters and benzene links, was used to demonstrate that its three-dimensional porous system can be functionalized with the organic groups and can be expanded with the long molecular struts biphenyl, tetrahydropyrene, pyrene, and terphenyl.
Journal ArticleDOI
Design and synthesis of an exceptionally stable and highly porous metal-organic framework
TL;DR: In this article, an organic dicarboxylate linker is used in a reaction that gives supertetrahedron clusters when capped with monocarboxyates.