Reticular synthesis and the design of new materials
Omar M. Yaghi,Michael O'Keeffe,Nathan W. Ockwig,Hee K. Chae,Hee K. Chae,Mohamed Eddaoudi,Jaheon Kim +6 more
TLDR
This work has shown that highly porous frameworks held together by strong metal–oxygen–carbon bonds and with exceptionally large surface area and capacity for gas storage have been prepared and their pore metrics systematically varied and functionalized.Abstract:
The long-standing challenge of designing and constructing new crystalline solid-state materials from molecular building blocks is just beginning to be addressed with success. A conceptual approach that requires the use of secondary building units to direct the assembly of ordered frameworks epitomizes this process: we call this approach reticular synthesis. This chemistry has yielded materials designed to have predetermined structures, compositions and properties. In particular, highly porous frameworks held together by strong metal-oxygen-carbon bonds and with exceptionally large surface area and capacity for gas storage have been prepared and their pore metrics systematically varied and functionalized.read more
Citations
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Functional Hybrid Porous Coordination Polymers
TL;DR: In this article, the authors examined 62 representative hybrid PCPs in the area of gas adsorption/separation/storage, luminescence, catalysis, drug delivery, and ionic conductivity.
Journal ArticleDOI
Cubic Polyoxometalate−Organic Molecular Cage
TL;DR: The cooperative assembly of Tris functionalized three-connected building blocks and rigid 1,3,5-benzenetricarboxylate gave rise to an unprecedented cubic polyoxometalate-organic molecular cage with high thermal and hydrothermal stability.
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Ruthenium Nanoparticles inside Porous [Zn4O(bdc)3] by Hydrogenolysis of Adsorbed [Ru(cod)(cot)]: A Solid-State Reference System for Surfactant-Stabilized Ruthenium Colloids
Felicitas Schröder,Daniel Esken,Mirza Cokoja,Maurits W. E. van den Berg,Oleg I. Lebedev,Gustaaf Van Tendeloo,Bernadeta Walaszek,Gerd Buntkowsky,Hans-Heinrich Limbach,Bruno Chaudret,Roland A. Fischer +10 more
TL;DR: Solid-state (2)H NMR measurements indicated that MOF-5 was a stabilizing support with only weak interactions with the embedded particles, as deduced from the surprisingly high mobility of the surface Ru-D species in comparison to surfactant-stabilized colloidal Ru nanoparticles of similar sizes.
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Sonochemical synthesis of MOF-5
TL;DR: High quality MOF-5 crystals of 5-25 mum in size were prepared for the first time using a sonochemical method in substantially reduced synthesis time compared with conventional solvothermal synthesis.
Journal ArticleDOI
N-Heterocyclic Carbenes in Materials Chemistry.
Christene A. Smith,Mina R. Narouz,Paul A. Lummis,Ishwar Singh,Ali Nazemi,Chien-Hung Li,Cathleen M. Crudden,Cathleen M. Crudden +7 more
TL;DR: This review provides an in-depth look at recent advances in the use of NHCs for the development of functional materials.
References
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Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage
Mohamed Eddaoudi,Jaheon Kim,Nathaniel L. Rosi,David T. Vodak,Joseph Wachter,Michael O'Keeffe,Omar M. Yaghi +6 more
TL;DR: Metal-organic framework (MOF-5), a prototype of a new class of porous materials and one that is constructed from octahedral Zn-O-C clusters and benzene links, was used to demonstrate that its three-dimensional porous system can be functionalized with the organic groups and can be expanded with the long molecular struts biphenyl, tetrahydropyrene, pyrene, and terphenyl.
Journal ArticleDOI
Design and synthesis of an exceptionally stable and highly porous metal-organic framework
TL;DR: In this article, an organic dicarboxylate linker is used in a reaction that gives supertetrahedron clusters when capped with monocarboxyates.