Reticular synthesis and the design of new materials
Omar M. Yaghi,Michael O'Keeffe,Nathan W. Ockwig,Hee K. Chae,Hee K. Chae,Mohamed Eddaoudi,Jaheon Kim +6 more
TLDR
This work has shown that highly porous frameworks held together by strong metal–oxygen–carbon bonds and with exceptionally large surface area and capacity for gas storage have been prepared and their pore metrics systematically varied and functionalized.Abstract:
The long-standing challenge of designing and constructing new crystalline solid-state materials from molecular building blocks is just beginning to be addressed with success. A conceptual approach that requires the use of secondary building units to direct the assembly of ordered frameworks epitomizes this process: we call this approach reticular synthesis. This chemistry has yielded materials designed to have predetermined structures, compositions and properties. In particular, highly porous frameworks held together by strong metal-oxygen-carbon bonds and with exceptionally large surface area and capacity for gas storage have been prepared and their pore metrics systematically varied and functionalized.read more
Citations
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Visible-Light-Promoted Photocatalytic Hydrogen Production by Using an Amino-Functionalized Ti(IV) Metal–Organic Framework
Yu Horiuchi,Takashi Toyao,Masakazu Saito,Mochizuki Katsunori,Masatoshi Iwata,Hideyuki Higashimura,Masakazu Anpo,Masaya Matsuoka +7 more
TL;DR: In this paper, the authors describe the hydrogen production from an aqueous medium over amino-functionalized Ti(IV) metal-organic framework (Ti-MOF-NH2) under visible-light irradiation.
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The Interaction of Water with MOF-5 Simulated by Molecular Dynamics
TL;DR: In this article, the force field parameters for metal-organic framework-5 (MOF-5 or IRMOF1) are presented, and the model is validated by comparing simulated lattice parameters of pure MOF5 with X-ray diffraction results.
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In silico screening of carbon-capture materials
Li-Chiang Lin,Adam H. Berger,Richard L. Martin,Jihan Kim,Joseph A. Swisher,Joseph A. Swisher,Kuldeep Jariwala,Chris H. Rycroft,Chris H. Rycroft,Abhoyjit S. Bhown,Michael W. Deem,Maciej Haranczyk,Berend Smit,Berend Smit +13 more
TL;DR: This analysis has screened hundreds of thousands of zeolite and zeolitic imidazolate framework structures and identified many different structures that have the potential to reduce the parasitic energy of CCS by 30-40% compared with near-term technologies.
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Selective Nucleation and Growth of Metal−Organic Open Framework Thin Films on Patterned COOH/CF3-Terminated Self-Assembled Monolayers on Au(111)
TL;DR: This work demonstrates the selective growth of patterned thin films of MOF-5 and the subsequent loading with a palladium organic compound, which acts as a precursor for the deposition of palladium nanoclusters inside the cavities of the MOf-5 material.
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Copper(I) 1,2,4-triazolates and related complexes: studies of the solvothermal ligand reactions, network topologies, and photoluminescence properties.
TL;DR: Another remarkable feature of these crystalline Cu(I) triazolates is their simple, typical 3- or 4-connected network topologies.
References
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Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage
Mohamed Eddaoudi,Jaheon Kim,Nathaniel L. Rosi,David T. Vodak,Joseph Wachter,Michael O'Keeffe,Omar M. Yaghi +6 more
TL;DR: Metal-organic framework (MOF-5), a prototype of a new class of porous materials and one that is constructed from octahedral Zn-O-C clusters and benzene links, was used to demonstrate that its three-dimensional porous system can be functionalized with the organic groups and can be expanded with the long molecular struts biphenyl, tetrahydropyrene, pyrene, and terphenyl.
Journal ArticleDOI
Design and synthesis of an exceptionally stable and highly porous metal-organic framework
TL;DR: In this article, an organic dicarboxylate linker is used in a reaction that gives supertetrahedron clusters when capped with monocarboxyates.