Abstract Submitted
for the MAR17 Meeting of
The American Physical Society
Roll-to-Roll printed large-area all-polymer solar cells with 5%
efficiency based on a low crystallinity conjugated polymer blend
1
XIAO-
DAN GU, Univ of Southern Mississippi, YAN ZHOU, KEVIN GU, TADANORI
KUROSAWA, Stanford University, HONGPING YAN, CHENG WANG, MICHEAL
TONEY, Stanford synchrotron radiation lightsource, ZHENAN BAO, Stanford Uni-
versity — The challenge of continuous printing in high efficiency large-area organic
solar cells is a key limiting factor for their widespread adoption. We present a
materials design concept for achieving large-area, solution coated all-polymer bulk
heterojunction (BHJ) solar cells with stable phase separation morphology between
the donor and acceptor. The key concept lies in inhibiting strong crystallization of
donor and acceptor polymers, thus forming intermixed, low crystallinity and mostly
amorphous blends. Based on experiments using donors and acceptors with different
degree of crystallinity, our results showed that microphase separated donor and ac-
ceptor domain sizes are inversely proportional to the crystallinity of the conjugated
polymers. This methodology of using low crystallinity donors and acceptors has the
added benefit of forming a consistent and robust morphology that is insensitive to
different processing conditions, allowing one to easily scale up the printing process
from a small scale solution shearing coater to a large-scale continuous roll-to-roll
(R2R) printer. We were able to continuously roll-to-roll slot die print large area
all-polymer solar cells with power conversion efficiencies of 5%, with combined cell
area up to 10 cm2. This is among the highest efficiencies realized with R2R coated
active layer organic materials on flexible substrate.
1
DOE BRIDGE sunshot program. Office of Naval Research
Xiaodan Gu
Univ of Southern Mississippi
Date submitted: 11 Nov 2016 Electronic form version 1.4