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Journal ArticleDOI

Spin routes in organic semiconductors

V. Alek Dediu, +3 more
- 01 Sep 2009 - 
- Vol. 8, Iss: 9, pp 707-716
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TLDR
The main experimental results and their connections with devices such as light-emitting diodes and electronic memory devices are summarized, and the scientific and technological issues that make organic spintronics a young but exciting field are outlined.
Abstract
Organic semiconductors are characterized by a very low spin–orbit interaction, which, together with their chemical flexibility and relatively low production costs, makes them an ideal materials system for spintronics applications. The first experiments on spin injection and transport occurred only a few years ago, and since then considerable progress has been made in improving performance as well as in understanding the mechanisms affecting spin-related phenomena. Nevertheless, several challenges remain in both device performance and fundamental understanding before organic semiconductors can compete with inorganic semiconductors or metals in the development of realistic spintronics applications. In this article we summarize the main experimental results and their connections with devices such as light-emitting diodes and electronic memory devices, and we outline the scientific and technological issues that make organic spintronics a young but exciting field.

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Citations
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Journal ArticleDOI

Supramolecular spin valves

TL;DR: An original spin-valve device is presented in which a non-magnetic molecular quantum dot is laterally coupled through supramolecular interactions to TbPc(2) single-molecule magnets (Pc=phthalocyanine), resulting in magnetoresistance ratios up to 300% at temperatures less than 1 K.
Journal ArticleDOI

Unravelling the role of the interface for spin injection into organic semiconductors

TL;DR: In this paper, the metal/organic interface is found to be key for spin injection in organic semiconductors, and the authors investigated how to optimize the injection of spin into these materials.
Journal ArticleDOI

Molecular magnetism: from chemical design to spin control in molecules, materials and devices

TL;DR: The field of molecular magnetism is rapidly evolving towards the use of magnetic molecules and molecule-based magnetic materials in physics-driven and nanotechnology-driven fields, in particular molecular spintronics, quantum technologies, metal-organic frameworks (MOFs) and 2D materials as discussed by the authors.
Journal ArticleDOI

Isotope effect in spin response of pi-conjugated polymer films and devices.

TL;DR: It is demonstrated that the HFI does indeed have a crucial role in all three spin responses and OLED films based on the D-polymers show substantially narrower magneto-electroluminescence and ODMR responses, and OSV devices based on D- polymers show a substantially larger magnetoresistance.
Journal ArticleDOI

Zethrenes, extended p-quinodimethanes, and periacenes with a singlet biradical ground state.

TL;DR: This Account discusses the chemistry and physics of three types of PHs with a significant singlet biradical character, primarily developed in this group, and finds that Clar's aromatic sextet rule, which is useful for the closed-shell PAHs, can also predict the relative biradicals character of benzenoid PH-based singletBiradicaloids.
References
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Journal ArticleDOI

Hysteretic electroluminescence in organic light-emitting diodes for spin injection

TL;DR: In this article, an organic light-emitting diodes with ferromagnetic contacts are fabricated, and their emission intensity is studied at room temperature for parallel and antiparallel magnetization configuration of anode and cathode.
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Alignment of energy levels at the Al q 3 ∕ La 0.7 Sr 0.3 Mn O 3 interface for organic spintronic devices

TL;DR: The electronic structure of the interface between tris(8-hydroxyquinolino)-aluminum and manganite was investigated by means of photoelectron spectroscopy as mentioned in this paper.
Journal ArticleDOI

EPR and charge-transport studies of polyaniline

TL;DR: In this paper, the authors studied dc and microwave (140 GHz) electrical conductivities using multifrequency electron-spin resonance in undoped and HCl-doped polyaniline.
Journal ArticleDOI

Comparing small molecules and polymer for future organic spin-valves

TL;DR: In this article, spin-paralyzed injection and transport in organic spin-valves made from both organic small molecules and polymers was reported. But the results were limited to spin-carrier injection and transfer.
Journal ArticleDOI

Correlation between microstructure and magnetotransport in organic semiconductor spin-valve structures

TL;DR: In this paper, the authors have studied magnetotransport in organic-inorganic hybrid multilayer junctions, where the organic semiconductor Alq$_3$ (tris(8-hydroxyquinoline) aluminum) formed a spacer layer between ferromagnetic (FM) Co and Fe layers.
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