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Superconductivity in the Z 2 kagome metal KV 3 Sb 5

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TLDR
In this paper, the authors reported the observation of bulk superconductivity in single crystals of the two-dimensional kagome metal (KV, Rb, Cs) with magnetic susceptibility, resistivity, and heat capacity measurements.
Abstract
Here we report the observation of bulk superconductivity in single crystals of the two-dimensional kagome metal ${\mathrm{KV}}_{3}{\mathrm{Sb}}_{5}$. Magnetic susceptibility, resistivity, and heat capacity measurements reveal superconductivity below ${T}_{c}=0.93\phantom{\rule{0.28em}{0ex}}\mathrm{K}$, and density functional theory (DFT) calculations further characterize the normal state as a ${\mathbb{Z}}_{2}$ topological metal. Our results demonstrate that the recent observation of superconductivity within the related kagome metal ${\mathrm{CsV}}_{3}{\mathrm{Sb}}_{5}$ is likely a common feature across the $A{\mathrm{V}}_{3}{\mathrm{Sb}}_{5}$ ($A$: K, Rb, Cs) family of compounds and establishes them as a rich arena for studying the interplay between bulk superconductivity, topological surface states, and likely electronic density wave order in an exfoliable kagome lattice.

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Journal ArticleDOI

Rotation symmetry breaking in the normal state of a kagome superconductor KV3Sb5

- 20 Jan 2022 - 
TL;DR: In this article , the authors used spectroscopic-imaging scanning tunneling microscopy to reveal a pronounced intensity anisotropy between different 2a0 charge density wave (CDW) directions in KV3Sb5.
Journal ArticleDOI

Electronic correlations in the normal state of the kagome superconductor KV 3 Sb 5

TL;DR: In this paper, the authors investigated the correlated electronic structure and magnetic properties of the kagome-lattice materials in the normal state and showed that these materials are good metals with weak local correlations.
Journal ArticleDOI

Discovery of unconventional chiral charge order in kagome superconductor KV3Sb5.

TL;DR: In this article, the authors used high-resolution scanning tunnelling microscopy (STM) to discover an unconventional charge order in a kagome material KV3Sb5, with both a topological band structure and a superconducting ground state.
Journal ArticleDOI

Anisotropic superconducting properties of Kagome metal CsV3Sb5

TL;DR: In this article, the superconducting and mixed state properties of high-quality CsV3Sb5 single crystals with Tc ~ 35 K were systematically measured and it was found that the upper critical field Hc2(T) exhibits a large anisotropic ratio of Hc 2^(ab)/Hc2^(c) ~ 9 at zero temperature and fitting its temperature dependence requires a minimum two-band effective model.
References
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Journal ArticleDOI

Generalized Gradient Approximation Made Simple

TL;DR: A simple derivation of a simple GGA is presented, in which all parameters (other than those in LSD) are fundamental constants, and only general features of the detailed construction underlying the Perdew-Wang 1991 (PW91) GGA are invoked.
Journal ArticleDOI

Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set.

TL;DR: An efficient scheme for calculating the Kohn-Sham ground state of metallic systems using pseudopotentials and a plane-wave basis set is presented and the application of Pulay's DIIS method to the iterative diagonalization of large matrices will be discussed.
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Projector augmented-wave method

TL;DR: An approach for electronic structure calculations is described that generalizes both the pseudopotential method and the linear augmented-plane-wave (LAPW) method in a natural way and can be used to treat first-row and transition-metal elements with affordable effort and provides access to the full wave function.
Journal ArticleDOI

From ultrasoft pseudopotentials to the projector augmented-wave method

TL;DR: In this paper, the formal relationship between US Vanderbilt-type pseudopotentials and Blochl's projector augmented wave (PAW) method is derived and the Hamilton operator, the forces, and the stress tensor are derived for this modified PAW functional.
Journal ArticleDOI

Efficiency of ab-initio total energy calculations for metals and semiconductors using a plane-wave basis set

TL;DR: A detailed description and comparison of algorithms for performing ab-initio quantum-mechanical calculations using pseudopotentials and a plane-wave basis set is presented in this article. But this is not a comparison of our algorithm with the one presented in this paper.
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