Journal ArticleDOI
The Chemistry and Applications of Metal-Organic Frameworks
Hiroyasu Furukawa,Hiroyasu Furukawa,Kyle E. Cordova,Kyle E. Cordova,Michael O'Keeffe,Michael O'Keeffe,Omar M. Yaghi,Omar M. Yaghi,Omar M. Yaghi +8 more
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TLDR
Metal-organic frameworks are porous materials that have potential for applications such as gas storage and separation, as well as catalysis, and methods are being developed for making nanocrystals and supercrystals of MOFs for their incorporation into devices.Abstract:
Crystalline metal-organic frameworks (MOFs) are formed by reticular synthesis, which creates strong bonds between inorganic and organic units. Careful selection of MOF constituents can yield crystals of ultrahigh porosity and high thermal and chemical stability. These characteristics allow the interior of MOFs to be chemically altered for use in gas separation, gas storage, and catalysis, among other applications. The precision commonly exercised in their chemical modification and the ability to expand their metrics without changing the underlying topology have not been achieved with other solids. MOFs whose chemical composition and shape of building units can be multiply varied within a particular structure already exist and may lead to materials that offer a synergistic combination of properties.read more
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In Situ Fabrication of Highly Luminescent Bifunctional Amino Acid Crosslinked 2D/3D NH3C4H9COO(CH3NH3PbBr3)n Perovskite Films
Taiyang Zhang,Li-Qiang Xie,Liang Chen,Guo Nanjie,Ge Li,Zhong-Qun Tian,Bing-Wei Mao,Yixin Zhao +7 more
TL;DR: In this article, a crosslinked 2D/3D NH3C4H9COO(CH3NH3) nPbnBr3n perovskite planar films with controllable quantum confine via bifunctional amino acid crosslinkage is reported.
Journal ArticleDOI
When CuAAC 'Click Chemistry' goes heterogeneous
TL;DR: In this article, the authors present a review of various reliable heterogeneous methods, alternative to the commonly used Meldal-Sharpless method for click chemistry, including those involving flow chemistry, and that they could be applied to a variety of compounds, solving some problems faced by more conventional methods.
Journal ArticleDOI
Metal-Organic Framework Membranes: Recent Development in the Synthesis Strategies and their Application in Oil-Water Separation
Yuying Deng,Yuying Deng,Yanni Wu,Chen Guangquan,Xilai Zheng,Min Dai,Changsheng Peng,Changsheng Peng +7 more
TL;DR: In this article, the authors classified the synthesis strategies of pure MOF membranes and MOF-based mixed matrix membranes and provided theoretical basis and technical guidance for realizing the large-scale application of MOF membrane in the field of oil-water separation.
Journal ArticleDOI
Robust Metal-Triazolate Frameworks for CO2 Capture from Flue Gas.
Zhaolin Shi,Yu Tao,Jiasheng Wu,Cuizheng Zhang,Hailong He,Liuliu Long,Yong Jin Lee,Tao Li,Yue-Biao Zhang +8 more
TL;DR: The best performing MOF in this series features low regeneration energy, high CO2 capture utility under hu-mid conditions, and decent cycling performance for mimic flue gas.
Journal ArticleDOI
Engineering of Pore Geometry for Ultrahigh Capacity Methane Storage in Mesoporous Metal–Organic Frameworks
Cong-Cong Liang,Zhaolin Shi,Chun-Ting He,Jing Tan,Hu-Die Zhou,Hao-Long Zhou,Yong Jin Lee,Yue-Biao Zhang +7 more
TL;DR: It is illustrated that the fine-tuned mesoporosity is critical in further improving the deliverable capacities at ultrahigh pressure.
References
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Journal ArticleDOI
Reticular synthesis and the design of new materials
Omar M. Yaghi,Michael O'Keeffe,Nathan W. Ockwig,Hee K. Chae,Hee K. Chae,Mohamed Eddaoudi,Jaheon Kim +6 more
TL;DR: This work has shown that highly porous frameworks held together by strong metal–oxygen–carbon bonds and with exceptionally large surface area and capacity for gas storage have been prepared and their pore metrics systematically varied and functionalized.
Journal ArticleDOI
Metal–organic framework materials as catalysts
JeongYong Lee,Omar K. Farha,John M. Roberts,Karl A. Scheidt,SonBinh T. Nguyen,Joseph T. Hupp +5 more
TL;DR: A critical review of the emerging field of MOF-based catalysis is presented and examples of catalysis by homogeneous catalysts incorporated as framework struts or cavity modifiers are presented.
Journal ArticleDOI
Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage
Mohamed Eddaoudi,Jaheon Kim,Nathaniel L. Rosi,David T. Vodak,Joseph Wachter,Michael O'Keeffe,Omar M. Yaghi +6 more
TL;DR: Metal-organic framework (MOF-5), a prototype of a new class of porous materials and one that is constructed from octahedral Zn-O-C clusters and benzene links, was used to demonstrate that its three-dimensional porous system can be functionalized with the organic groups and can be expanded with the long molecular struts biphenyl, tetrahydropyrene, pyrene, and terphenyl.
Journal ArticleDOI
Design and synthesis of an exceptionally stable and highly porous metal-organic framework
TL;DR: In this article, an organic dicarboxylate linker is used in a reaction that gives supertetrahedron clusters when capped with monocarboxyates.