Journal ArticleDOI
The Chemistry and Applications of Metal-Organic Frameworks
Hiroyasu Furukawa,Hiroyasu Furukawa,Kyle E. Cordova,Kyle E. Cordova,Michael O'Keeffe,Michael O'Keeffe,Omar M. Yaghi,Omar M. Yaghi,Omar M. Yaghi +8 more
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TLDR
Metal-organic frameworks are porous materials that have potential for applications such as gas storage and separation, as well as catalysis, and methods are being developed for making nanocrystals and supercrystals of MOFs for their incorporation into devices.Abstract:
Crystalline metal-organic frameworks (MOFs) are formed by reticular synthesis, which creates strong bonds between inorganic and organic units. Careful selection of MOF constituents can yield crystals of ultrahigh porosity and high thermal and chemical stability. These characteristics allow the interior of MOFs to be chemically altered for use in gas separation, gas storage, and catalysis, among other applications. The precision commonly exercised in their chemical modification and the ability to expand their metrics without changing the underlying topology have not been achieved with other solids. MOFs whose chemical composition and shape of building units can be multiply varied within a particular structure already exist and may lead to materials that offer a synergistic combination of properties.read more
Citations
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Journal ArticleDOI
Opportunities of Covalent Organic Frameworks for Advanced Applications
TL;DR: Recent advancements of COFs as a designer platform for a plethora of applications are emphasized together with discussions about the strategies and principles involved.
Journal ArticleDOI
The role of metal–organic frameworks in a carbon-neutral energy cycle
TL;DR: In this paper, the role of metal-organic frameworks for the capture, storage and conversion of gases such as hydrogen, methane and carbon dioxide is explored. But the authors focus on metal oxide "hubs" are linked with organic "struts" to make materials of ultrahigh porosity, which provide a basis for addressing this challenge through materials design on the molecular level.
Journal ArticleDOI
Metal-organic frameworks with precisely designed interior for carbon dioxide capture in the presence of water
Alejandro M. Fracaroli,Hiroyasu Furukawa,Mitsuharu Suzuki,Matthew Dodd,Satoshi Okajima,Felipe Gándara,Jeffrey A. Reimer,Omar M. Yaghi,Omar M. Yaghi +8 more
TL;DR: Carbon dioxide isotherms and breakthrough experiments show that IRMOF-74-III-CH2NH2 is especially efficient at taking up CO2 and removing CO2 from wet nitrogen gas streams with breakthrough time of 610 ± 10 s g(-1) and full preservation of the IR MOF structure.
Journal ArticleDOI
Elevated Performance of Thin Film Nanocomposite Membranes Enabled by Modified Hydrophilic MOFs for Nanofiltration.
Junyong Zhu,Lijuan Qin,Adam Uliana,Jingwei Hou,Jing Wang,Jing Wang,Yatao Zhang,Xin Li,Shushan Yuan,Jian Li,Miaomiao Tian,Jiuyang Lin,Bart Van der Bruggen +12 more
TL;DR: This facile, cost-effective strategy will provide a useful guideline to integrate with other modified hydrophilic MOFs to design nanofiltration for water treatment.
Journal ArticleDOI
Metal–organic framework technologies for water remediation: towards a sustainable ecosystem
TL;DR: In this paper, the authors have focused their attention on critically highlighting the latest developments achieved in the adsorptive removal of inorganic metal cations, inorganic acids, oxyanions/cations, nuclear wastes and other inorganic anions.
References
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Journal ArticleDOI
Reticular synthesis and the design of new materials
Omar M. Yaghi,Michael O'Keeffe,Nathan W. Ockwig,Hee K. Chae,Hee K. Chae,Mohamed Eddaoudi,Jaheon Kim +6 more
TL;DR: This work has shown that highly porous frameworks held together by strong metal–oxygen–carbon bonds and with exceptionally large surface area and capacity for gas storage have been prepared and their pore metrics systematically varied and functionalized.
Journal ArticleDOI
Metal–organic framework materials as catalysts
JeongYong Lee,Omar K. Farha,John M. Roberts,Karl A. Scheidt,SonBinh T. Nguyen,Joseph T. Hupp +5 more
TL;DR: A critical review of the emerging field of MOF-based catalysis is presented and examples of catalysis by homogeneous catalysts incorporated as framework struts or cavity modifiers are presented.
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Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage
Mohamed Eddaoudi,Jaheon Kim,Nathaniel L. Rosi,David T. Vodak,Joseph Wachter,Michael O'Keeffe,Omar M. Yaghi +6 more
TL;DR: Metal-organic framework (MOF-5), a prototype of a new class of porous materials and one that is constructed from octahedral Zn-O-C clusters and benzene links, was used to demonstrate that its three-dimensional porous system can be functionalized with the organic groups and can be expanded with the long molecular struts biphenyl, tetrahydropyrene, pyrene, and terphenyl.
Journal ArticleDOI
Design and synthesis of an exceptionally stable and highly porous metal-organic framework
TL;DR: In this article, an organic dicarboxylate linker is used in a reaction that gives supertetrahedron clusters when capped with monocarboxyates.